IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v188y2022icp195-210.html
   My bibliography  Save this article

Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons

Author

Listed:
  • Lv, Wei
  • Hu, Xiaohong
  • Zhu, Yuting
  • Xu, Ying
  • Liu, Shijun
  • Chen, Peili
  • Wang, Chenguang
  • Ma, Longlong

Abstract

Herein, the catalysts of ruthenium and molybdenum oxide nanoparticles supported on activated carbon (AC) were synthesized by precursor stepwise impregnation and employed for the hydrodeoxygenation (HDO) of lignin oil. The XRD, TEM, XPS and NH3-TPD-MS result of RuMoOx/AC catalysts confirm that the method of loading molybdenum precursor before ruthenium precursor is advantageous for the MoOx and Ru nanoparticles high dispersion and the reduction of MoOx species enhance the amount of acidity of catalyst. Meanwhile, the reduction temperature of RuMoOx/AC-1-T catalysts could effectively regulate the MoOx species that determine the activity and product distribution of HDO. The conversion of aromatic monomers/dimers were up to 96% with high selectivity of hydrocarbon over RuMoOx/AC-1-350 catalyst at 160 °C and 30 bar H2. Which is attributed to the MoO3 and Ru species possess the excellent activity of benzene ring deep hydrogenation, ether bond breaking and acid dehydration. The RuMoOx/AC-1-350 catalyst effectively converted lignin oil (from the depolymerization of cornstalk hydrolysis residue) into hydrocarbons (56.9 wt%) and cyclohexanol/ethers (18.7 wt%) under 280 °C and 3 bar H2. The durability of the RuMoOx/AC-1-350 catalyst for HDO of lignin oil was also investigated and showed that the RuMoOx/AC-1-350 catalyst had good stability, regenerability and repeatability.

Suggested Citation

  • Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.
    • Handle: RePEc:eee:renene:v:188:y:2022:i:c:p:195-210
    DOI: 10.1016/j.renene.2021.12.148
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121018760
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.12.148?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yoosuk, Boonyawan & Sanggam, Paphawee & Wiengket, Sakdipat & Prasassarakich, Pattarapan, 2019. "Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 139(C), pages 1391-1399.
    2. Fan, Xu-dong & Wu, Yu-jian & Tu, Ren & Sun, Yan & Jiang, En-chen & Xu, Xi-wei, 2020. "Hydrodeoxygenation of guaiacol via rice husk char supported Ni based catalysts: The influence of char supports," Renewable Energy, Elsevier, vol. 157(C), pages 1035-1045.
    3. Dimitriadis, Athanasios & Chrysikou, Loukia P. & Meletidis, George & Terzis, George & Auersvald, Miloš & Kubička, David & Bezergianni, Stella, 2021. "Bio-based refinery intermediate production via hydrodeoxygenation of fast pyrolysis bio-oil," Renewable Energy, Elsevier, vol. 168(C), pages 593-605.
    4. Kwon, Kyung C. & Mayfield, Howard & Marolla, Ted & Nichols, Bob & Mashburn, Mike, 2011. "Catalytic deoxygenation of liquid biomass for hydrocarbon fuels," Renewable Energy, Elsevier, vol. 36(3), pages 907-915.
    5. Li, Zhiyu & Jiang, Enchen & Xu, Xiwei & Sun, Yan & Tu, Ren, 2020. "Hydrodeoxygenation of phenols, acids, and ketones as model bio-oil for hydrocarbon fuel over Ni-based catalysts modified by Al, La and Ga," Renewable Energy, Elsevier, vol. 146(C), pages 1991-2007.
    6. Qineng Xia & Zongjia Chen & Yi Shao & Xueqing Gong & Haifeng Wang & Xiaohui Liu & Stewart F. Parker & Xue Han & Sihai Yang & Yanqin Wang, 2016. "Direct hydrodeoxygenation of raw woody biomass into liquid alkanes," Nature Communications, Nature, vol. 7(1), pages 1-10, September.
    7. Yi Shao & Qineng Xia & Lin Dong & Xiaohui Liu & Xue Han & Stewart F. Parker & Yongqiang Cheng & Luke L. Daemen & Anibal J. Ramirez-Cuesta & Sihai Yang & Yanqin Wang, 2017. "Selective production of arenes via direct lignin upgrading over a niobium-based catalyst," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    8. Chen, Shuang & Miao, Caixia & Luo, Yan & Zhou, Guilin & Xiong, Kun & Jiao, Zhaojie & Zhang, Xianming, 2018. "Study of catalytic hydrodeoxygenation performance of Ni catalysts: Effects of prepared method," Renewable Energy, Elsevier, vol. 115(C), pages 1109-1117.
    9. Resende, K.A. & Noronha, F.B. & Hori, C.E., 2020. "Hydrodeoxygenation of phenol over metal supported niobia catalysts," Renewable Energy, Elsevier, vol. 149(C), pages 198-207.
    10. Kumar, Adarsh & Kumar, Avnish & Biswas, Bijoy & Kumar, Jitendra & Yenumala, Sudhakara Reddy & Bhaskar, Thallada, 2020. "Hydrodeoxygenation of m-Cresol over Ru based catalysts: Influence of catalyst support on m-Cresol conversion and methylcyclohexane selectivity," Renewable Energy, Elsevier, vol. 151(C), pages 687-697.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gao, Xueying & Li, Helong & Wang, Shuizhong & Liu, Zhenzhen & Ma, Jian-feng & Liu, Xing-e & Song, Guoyong, 2022. "Hydrodeoxygenation of lignin biophenolics to cyclohexanes over sub-nanometric Ru multifunctional catalyst," Renewable Energy, Elsevier, vol. 201(P1), pages 724-733.
    2. Rodiansono, & Syahruji, & Dewi, Heny Puspita & Azzahra, Atina Sabila & Sembiring, Kiky Corneliasari & Adilina, Indri Badria & Afandi, Ahmad, 2024. "Pivotal MoOx-decorated Ru/C with a monomeric structure boosts the room temperature and low-pressure hydrogenation of levulinic acid to γ−valerolactone," Renewable Energy, Elsevier, vol. 229(C).
    3. Shu, Riyang & Jiang, Hao & Xie, Long & Liu, Xiaozhou & Yin, Tao & Tian, Zhipeng & Wang, Chao & Chen, Ying, 2023. "Efficient hydrodeoxygenation of lignin-derived phenolic compounds by using Ru-based biochar catalyst coupled with silicotungstic acid," Renewable Energy, Elsevier, vol. 202(C), pages 1160-1168.
    4. Zhu, Yingbo & Ma, Yulong & Sun, Yonggang & Wang, Liqiong & Ding, Jie & Zhong, Yudan & Zhang, Juan & Wang, Lei & Li, Yuanyuan, 2023. "In-situ construction of N-doped hollow carbon polyhedral cage anchored Co-Ni dual binding sites as nanoreactor for efficient real lignin oil hydrodeoxygenation," Renewable Energy, Elsevier, vol. 217(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tai, Lingyu & Hamidi, Roya & de Caprariis, Benedetta & Damizia, Martina & Paglia, Laura & Scarsella, Marco & Karimzadeh, Ramin & De Filippis, Paolo, 2022. "Guaiacol hydrotreating with in-situ generated hydrogen over ni/modified zeolite supports," Renewable Energy, Elsevier, vol. 182(C), pages 647-658.
    2. Zhang, Qiongyin & Xiao, Jun & Hao, Jingwen, 2023. "Cumulative exergy analysis of lignocellulosic biomass to bio-jet fuel through aqueous-phase conversion with different lignin conversion pathways," Energy, Elsevier, vol. 265(C).
    3. Gollakota, Anjani R.K. & Shu, Chi-Min & Sarangi, Prakash Kumar & Shadangi, Krushna Prasad & Rakshit, Sudip & Kennedy, John F. & Gupta, Vijai Kumar & Sharma, Minaxi, 2023. "Catalytic hydrodeoxygenation of bio-oil and model compounds - Choice of catalysts, and mechanisms," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    4. Tran, Quoc Khanh & Ly, Hoang Vu & Kwon, Byeongwan & Kim, Seung-Soo & Kim, Jinsoo, 2021. "Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts," Renewable Energy, Elsevier, vol. 173(C), pages 886-895.
    5. Zhang, Chengzhi & Zhang, Xing & Wu, Jingfeng & Zhu, Lingjun & Wang, Shurong, 2022. "Hydrodeoxygenation of lignin-derived phenolics to cycloalkanes over Ni–Co alloy coupled with oxophilic NbOx," Applied Energy, Elsevier, vol. 328(C).
    6. Xiaoqin Si & Rui Lu & Zhitong Zhao & Xiaofeng Yang & Feng Wang & Huifang Jiang & Xiaolin Luo & Aiqin Wang & Zhaochi Feng & Jie Xu & Fang Lu, 2022. "Catalytic production of low-carbon footprint sustainable natural gas," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    7. Zihao Zhang & Qiang Li & Xiangkun Wu & Claire Bourmaud & Dionisios G. Vlachos & Jeremy Luterbacher & Andras Bodi & Patrick Hemberger, 2024. "A solution for 4-propylguaiacol hydrodeoxygenation without ring saturation," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    8. Fan, Xudong & Wu, Yujian & Sun, Yan & Tu, Ren & Ren, Zhipeng & Liang, Kaili & Jiang, Enchen & Ren, Yongzhi & Xu, Xiwei, 2022. "Functional groups anchoring-induced Ni/MoOx-Ov interface on rice husk char for hydrodeoxygenation of bio-guaiacol to BTX at ambient-pressure," Renewable Energy, Elsevier, vol. 200(C), pages 579-591.
    9. Guan, Weixiang & Chen, Xiao & Zhang, Jie & Hu, Haoquan & Liang, Changhai, 2020. "Catalytic transfer hydrogenolysis of lignin α-O-4 model compound 4-(benzyloxy)phenol and lignin over Pt/HNbWO6/CNTs catalyst," Renewable Energy, Elsevier, vol. 156(C), pages 249-259.
    10. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    11. Li, Sen & Guo, Longhui & He, Xinyu & Qiao, Congzhen & Tian, Yajie, 2022. "Synthesis of uniform Ni nanoparticles encapsulated in ZSM–5 for selective hydrodeoxygenation of phenolics," Renewable Energy, Elsevier, vol. 194(C), pages 89-99.
    12. Zhiyou Zong & Scott Mazurkewich & Caroline S. Pereira & Haohao Fu & Wensheng Cai & Xueguang Shao & Munir S. Skaf & Johan Larsbrink & Leila Lo Leggio, 2022. "Mechanism and biomass association of glucuronoyl esterase: an α/β hydrolase with potential in biomass conversion," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Jianghao Zhang & Wenda Hu & Binbin Qian & Houqian Li & Berlin Sudduth & Mark Engelhard & Lian Zhang & Jianzhi Hu & Junming Sun & Changbin Zhang & Hong He & Yong Wang, 2023. "Tuning hydrogenation chemistry of Pd-based heterogeneous catalysts by introducing homogeneous-like ligands," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    14. Miao, Caixia & Zhou, Guilin & Chen, Shuang & Xie, Hongmei & Zhang, Xianming, 2020. "Synergistic effects between Cu and Ni species in NiCu/γ-Al2O3 catalysts for hydrodeoxygenation of methyl laurate," Renewable Energy, Elsevier, vol. 153(C), pages 1439-1454.
    15. Radhakrishnan, Rokesh & Patra, Pradipta & Das, Manali & Ghosh, Amit, 2021. "Recent advancements in the ionic liquid mediated lignin valorization for the production of renewable materials and value-added chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    16. Cao, Xincheng & Long, Feng & Wang, Fei & Zhao, Jiaping & Xu, Junming & Jiang, Jianchun, 2021. "Chemoselective decarboxylation of higher aliphatic esters to diesel-range alkanes over the NiCu/Al2O3 bifunctional catalyst under mild reaction conditions," Renewable Energy, Elsevier, vol. 180(C), pages 1-13.
    17. Burimsitthigul, Thikhamporn & Yoosuk, Boonyawan & Ngamcharussrivichai, Chawalit & Prasassarakich, Pattarapan, 2021. "Hydrocarbon biofuel from hydrotreating of palm oil over unsupported Ni–Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 163(C), pages 1648-1659.
    18. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.
    19. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    20. Kakku, Sivasankar & Naidu, Sowkhya & Chakinala, Anand G. & Joshi, Jyeshtharaj & Thota, Chiranjeevi & Maity, Pintu & Sharma, Abhishek, 2024. "Co-processing of organic fraction from groundnut shell biocrude with VGO in FCC unit to produce petrochemical products," Renewable Energy, Elsevier, vol. 224(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:188:y:2022:i:c:p:195-210. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.