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Catalytic deoxygenation of liquid biomass for hydrocarbon fuels

Author

Listed:
  • Kwon, Kyung C.
  • Mayfield, Howard
  • Marolla, Ted
  • Nichols, Bob
  • Mashburn, Mike

Abstract

Liquid biomass such as methyl laurate and canola oil is deoxygenated with hydrogen and NiMo/γ-Al2O3 catalyst. Oxygen from methyl laurate and canola oil is removed at 18.25–85.13 bar initial cold hydrogen pressure and 300–400 °C, using a 316 stainless steel batch reactor. Removal of oxygen from liquid methyl laurate and canola oil is evaluated with a GC/MS analyzer for liquid reaction products and another GC for gaseous reaction products. The range of reaction duration of liquid biomass in the batch reactor is 30–60 min under the deoxygenation conditions. Conversion of liquid biomass into gaseous products is evaluated with analysis data of gas products and a mass balance in terms of hydrogen.

Suggested Citation

  • Kwon, Kyung C. & Mayfield, Howard & Marolla, Ted & Nichols, Bob & Mashburn, Mike, 2011. "Catalytic deoxygenation of liquid biomass for hydrocarbon fuels," Renewable Energy, Elsevier, vol. 36(3), pages 907-915.
    • Handle: RePEc:eee:renene:v:36:y:2011:i:3:p:907-915
    DOI: 10.1016/j.renene.2010.09.004
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    Cited by:

    1. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    2. del Río, Juan I. & Pérez, William & Cardeño, Fernando & Marín, James & Rios, Luis A., 2021. "Pre-hydrogenation stage as a strategy to improve the continuous production of a diesel-like biofuel from palm oil," Renewable Energy, Elsevier, vol. 168(C), pages 505-515.
    3. Jeon, Kyung-Won & Shim, Jae-Oh & Jang, Won-Jun & Lee, Da-We & Na, Hyun-Suk & Kim, Hak-Min & Lee, Yeol-Lim & Yoo, Seong-Yeun & Roh, Hyun-Seog & Jeon, Byong-Hun & Bae, Jong Wook & Ko, Chang Hyun, 2019. "Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce0.6Zr0.4O2 deoxygenation catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 131(C), pages 144-151.
    4. Gollakota, Anjani R.K. & Reddy, Madhurima & Subramanyam, Malladi D. & Kishore, Nanda, 2016. "A review on the upgradation techniques of pyrolysis oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1543-1568.
    5. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    6. Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.

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