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Efficient hydrodeoxygenation of lignin-derived phenolic compounds by using Ru-based biochar catalyst coupled with silicotungstic acid

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  • Shu, Riyang
  • Jiang, Hao
  • Xie, Long
  • Liu, Xiaozhou
  • Yin, Tao
  • Tian, Zhipeng
  • Wang, Chao
  • Chen, Ying

Abstract

Hydrodeoxygenation (HDO) is an effective technology for the conversion of bio-oil to high quality liquid fuels, in which an active and stable catalyst is crucial to gain a high reaction efficiency. In this work, a novel bifunctional catalyst of different Ru-based biochar catalyst coupled with silicotungstic acid (HSiW) was proposed to conduct the HDO of lignin-derived phenolic compounds under mild reaction condition. Ru/C-bamboo catalyst exhibited a better HDO performance than other Ru-based biochar catalysts and commercial Ru/C catalyst. Catalyst characterizations showed that Ru/C-bamboo catalyst possessed a rich mesoporous structure of 0.06 cm3/g mesopore volume and 0.07 cm3/g micropore volume, with a large specific surface area of 209 m2/g. A high metal dispersion and a good hydrogen adsorption ability were achieved in Ru/C-bamboo catalyst. And Guaiacol can be completely converted to cyclohexane with 87.7% selectivity at the temperature of 140 °C. Other typical phenolic compounds were also transformed into corresponding cycloalkanes with high yields above 90% in most cases. Besides, the lignin-oil also had a great improvement on the stability and the heat value after upgradation, with an increase of hydrocarbon content from 9.7% to 31.9%. This result indicated the potential of the bifunctional catalyst in the field of lignin-oil valorization.

Suggested Citation

  • Shu, Riyang & Jiang, Hao & Xie, Long & Liu, Xiaozhou & Yin, Tao & Tian, Zhipeng & Wang, Chao & Chen, Ying, 2023. "Efficient hydrodeoxygenation of lignin-derived phenolic compounds by using Ru-based biochar catalyst coupled with silicotungstic acid," Renewable Energy, Elsevier, vol. 202(C), pages 1160-1168.
    • Handle: RePEc:eee:renene:v:202:y:2023:i:c:p:1160-1168
    DOI: 10.1016/j.renene.2022.11.092
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    References listed on IDEAS

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    1. Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.
    2. Chen, Guanyi & Liu, Juping & Li, Xiangping & Zhang, Jianguang & Yin, Han & Su, Zhenping, 2020. "Investigation on catalytic hydrodeoxygenation of eugenol blend with light fraction in bio-oil over Ni-based catalysts," Renewable Energy, Elsevier, vol. 157(C), pages 456-465.
    3. Oh, Shinyoung & Lee, Jae Hoon & Choi, Joon Weon, 2020. "Hydrodeoxygenation of crude bio-oil with various metal catalysts in a continuous-flow reactor and evaluation of emulsion properties of upgraded bio-oil with petroleum fuel," Renewable Energy, Elsevier, vol. 160(C), pages 1160-1167.
    4. Chaihad, Nichaboon & Karnjanakom, Surachai & Kurnia, Irwan & Yoshida, Akihiro & Abudula, Abuliti & Reubroycharoen, Prasert & Guan, Guoqing, 2019. "Catalytic upgrading of bio-oils over high alumina zeolites," Renewable Energy, Elsevier, vol. 136(C), pages 1304-1310.
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