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Bio-based refinery intermediate production via hydrodeoxygenation of fast pyrolysis bio-oil

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  • Dimitriadis, Athanasios
  • Chrysikou, Loukia P.
  • Meletidis, George
  • Terzis, George
  • Auersvald, Miloš
  • Kubička, David
  • Bezergianni, Stella

Abstract

Pyrolysis bio-oil is unsuitable as transportation fuel due to its chemical composition and high oxygen (>30 wt%) and water (>20 wt%) content rendering the upgrading essential prior any downstream use. The current work investigates the upgrading of a flash pyrolysis bio-oil via mild hydrotreatment (HDT), targeting to a potential intermediate refinery feed. Various operating parameters of HDT were tested, including three temperatures (573, 603 and 633 K), two pressures (4 and 7 MPa) and two H2/bio-oil ratios (506 and 843 NL/L). According to the results, during HDT of bio-oil, massive plugging by coke formed in the reactor. The unsaturated oxygenates in bio-oil are regarded as the predominant coke precursors since they can interact with the catalytic surface. From all the examined conditions, it was found that the longest catalyst life, (5 days on stream), was achieved at 7 MPa pressure, 843 NL/L H2/bio-oil ratio and 603 K temperature. Furthermore, several properties of the initial bio-oil were improved, such as viscosity (156 → 4.9 cSt), carboxylic acids (78 → 0.2 mgKOH/g), density (1.024 → 0.9162 g/ml), and oxygen content (37 → 4 wt%). Conclusively, mild HDT constitutes a promising technological pathway for bio-oil upgrading towards a reliable intermediate refinery feed.

Suggested Citation

  • Dimitriadis, Athanasios & Chrysikou, Loukia P. & Meletidis, George & Terzis, George & Auersvald, Miloš & Kubička, David & Bezergianni, Stella, 2021. "Bio-based refinery intermediate production via hydrodeoxygenation of fast pyrolysis bio-oil," Renewable Energy, Elsevier, vol. 168(C), pages 593-605.
    • Handle: RePEc:eee:renene:v:168:y:2021:i:c:p:593-605
    DOI: 10.1016/j.renene.2020.12.047
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    1. Mohammad, Masita & Kandaramath Hari, Thushara & Yaakob, Zahira & Chandra Sharma, Yogesh & Sopian, Kamaruzzaman, 2013. "Overview on the production of paraffin based-biofuels via catalytic hydrodeoxygenation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 121-132.
    2. Yang, Zixu & Kumar, Ajay & Huhnke, Raymond L., 2015. "Review of recent developments to improve storage and transportation stability of bio-oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 859-870.
    3. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    4. Bezergianni, Stella & Dimitriadis, Athanasios, 2013. "Comparison between different types of renewable diesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 110-116.
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    2. Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.
    3. Santos, Bruna Stella De Freitas & Palacios-Bereche, Milagros Cecilia & Gallego, Antonio Garrido & Nebra, Silvia Azucena & Palacios-Bereche, Reynaldo, 2024. "Energy assessment and heat integration of biofuel production from bio-oil produced through fast pyrolysis of sugarcane straw, and its upgrading via hydrotreatment," Renewable Energy, Elsevier, vol. 232(C).
    4. Nguyen, Quynh Van & Choi, Yeon Seok & Jeong, Yeon Woo & Han, So Young & Choi, Sang Kyu, 2024. "Catalytic co-pyrolysis of coffee-grounds and waste polystyrene foam by calcium oxide in bubbling fluidized bed reactor," Renewable Energy, Elsevier, vol. 224(C).

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