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Chemoselective decarboxylation of higher aliphatic esters to diesel-range alkanes over the NiCu/Al2O3 bifunctional catalyst under mild reaction conditions

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  • Cao, Xincheng
  • Long, Feng
  • Wang, Fei
  • Zhao, Jiaping
  • Xu, Junming
  • Jiang, Jianchun

Abstract

An efficient and highly selective decarboxylation catalyst has been developed for the production of diesel-range alkanes from the conversion of higher aliphatic esters under mild reaction conditions. Using methyl stearate as a model substrate, the NiCu/Al2O3 bifunctional catalysts derived from layer double hydroxide (LDHs) precursors showed excellent catalytic performance with 100% conversion and 97.5% selectivity to heptadecane at 260 °C and 3.0 MPa H2. On the other hand, the catalytic performance of NiCu/Al2O3 catalyst was also tested in the conversion of soybean and waste cooking oils under the mild conditions. The results showed that a high yields of diesel-range alkanes (>80 wt%) were obtained from the conversion of soybean oil and waste cooking oil, respectively.

Suggested Citation

  • Cao, Xincheng & Long, Feng & Wang, Fei & Zhao, Jiaping & Xu, Junming & Jiang, Jianchun, 2021. "Chemoselective decarboxylation of higher aliphatic esters to diesel-range alkanes over the NiCu/Al2O3 bifunctional catalyst under mild reaction conditions," Renewable Energy, Elsevier, vol. 180(C), pages 1-13.
    • Handle: RePEc:eee:renene:v:180:y:2021:i:c:p:1-13
    DOI: 10.1016/j.renene.2021.08.004
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    1. Yoosuk, Boonyawan & Sanggam, Paphawee & Wiengket, Sakdipat & Prasassarakich, Pattarapan, 2019. "Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 139(C), pages 1391-1399.
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    1. Cai, Bo & Kang, Rui & Guo, Dayi & Feng, Junfeng & Ma, Tianyi & Pan, Hui, 2022. "An eco-friendly acidic catalyst phosphorus-doped graphitic carbon nitride for efficient conversion of fructose to 5-Hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1629-1638.
    2. Wang, Fei & Pace, Robert & Ji, Yaying & Jiang, Jianchun & Jiang, Xiaoxiang & Krystianiak, Anna & Heintz, Olivier & Caboche, Gilles & Santillan-Jimenez, Eduardo & Crocker, Mark, 2022. "Effect of Pd promotion and catalyst support on the Ni-catalyzed deoxygenation of tristearin to fuel-like hydrocarbons," Renewable Energy, Elsevier, vol. 195(C), pages 1468-1479.
    3. Li, Xingyong & Wu, Yankun & Wang, Qi & Li, Shuirong & Ye, Yueyuan & Wang, Dechao & Zheng, Zhifeng, 2022. "Effect of preparation method of NiMo/γ-Al2O3 on the FAME hydrotreatment to produce C15–C18 alkanes," Renewable Energy, Elsevier, vol. 193(C), pages 1-12.
    4. Wang, Fei & Xu, Hui & Yu, Songyin & Zhu, Hao & Du, Yuchan & Zhang, Zeng & You, Chaoqun & Jiang, Xiaoxiang & Jiang, Jianchun, 2022. "Fe-promoted Ni catalyst with extremely high loading and oxygen vacancy for lipid deoxygenation into green diesel," Renewable Energy, Elsevier, vol. 197(C), pages 40-49.

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