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Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts

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  • Yoosuk, Boonyawan
  • Sanggam, Paphawee
  • Wiengket, Sakdipat
  • Prasassarakich, Pattarapan

Abstract

Second generation biodiesel, so-called bio-hydrogenated diesel (BHD), can be produced from hydrotreatment of vegetable oils. The hydrogenation (HDO) of oleic acid and palmitic acid as model compounds of palm oil over unsupported Ni-Mo and Co-Mo sulfide catalysts was performed in a Parr reactor to produce BHD. The effects of reaction parameters: temperature, hydrogen pressure and the atomic ratio of catalysts (Ni/(Ni + Mo) or Co/(Co + Mo)) on the conversion and product yields (mainly n-C15, n-C16, n-C17 and n-C18 hydrocarbons) were evaluated. The results show that the high pressure favored HDO pathway, while high temperature strongly affected the decarboxylation and decarbonylation pathways. At optimal conditions for oleic acid HDO, the efficient catalyst was NiMoS2 catalyst (Ni/(Ni + Mo) = 0.2) which gave high oleic acid conversion (100%), n-C18 selectivity (78.8%) and n-C18 yield (70.3%) whereas, for palmitic acid HDO, NiMoS2 catalyst (Ni/(Ni + Mo) = 0.2) also gave high palmitic acid conversion (95.2%), n-C16 selectivity (78.5%) and n-C16 yield (65.6%).

Suggested Citation

  • Yoosuk, Boonyawan & Sanggam, Paphawee & Wiengket, Sakdipat & Prasassarakich, Pattarapan, 2019. "Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 139(C), pages 1391-1399.
    • Handle: RePEc:eee:renene:v:139:y:2019:i:c:p:1391-1399
    DOI: 10.1016/j.renene.2019.03.030
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    References listed on IDEAS

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    1. Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    2. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Yasir, Madiha, 2017. "Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1072-1088.
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