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Hydrodeoxygenation of lignin biophenolics to cyclohexanes over sub-nanometric Ru multifunctional catalyst

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  • Gao, Xueying
  • Li, Helong
  • Wang, Shuizhong
  • Liu, Zhenzhen
  • Ma, Jian-feng
  • Liu, Xing-e
  • Song, Guoyong

Abstract

Hydrodeoxygenation of lignin-derived phenolics into cyclohexanes is recognized as an attractive philosophy for producing high energy density fuels in a sustainable manner. Here, we report a catalyst made of low-loading, sub-nanoscaled Ru species and multifarious acidic centers on amorphous-silica-alumina, which shows excellent activity, selectivity, and stability in hydrodeoxygenation of 4-propylguaiacol to propylcyclohexane. Catalytic performance exhibits a linear relationship to the total acidities of this family catalysts, demonstrating a synergistic interaction between the metallic and acidic components. The superior performance of this catalyst allows the conversion of various lignin-derived monophenols, dimers, more significantly, a biophenolic stream from miscanthus lignin into cyclohexanes with high efficiency and yield. This work highlights the importance of the sub-nanometric size of Ru species in the advancement of efficient and affordable approaches towards lignin-based fuel production.

Suggested Citation

  • Gao, Xueying & Li, Helong & Wang, Shuizhong & Liu, Zhenzhen & Ma, Jian-feng & Liu, Xing-e & Song, Guoyong, 2022. "Hydrodeoxygenation of lignin biophenolics to cyclohexanes over sub-nanometric Ru multifunctional catalyst," Renewable Energy, Elsevier, vol. 201(P1), pages 724-733.
    • Handle: RePEc:eee:renene:v:201:y:2022:i:p1:p:724-733
    DOI: 10.1016/j.renene.2022.10.090
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