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Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism

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  • Hermida, Lilis
  • Abdullah, Ahmad Zuhairi
  • Mohamed, Abdul Rahman

Abstract

Deoxygenation process of fatty acid as a renewable resource to produce diesel-like hydrocarbons is one of the alternatives to address drastic shortage of crude oil-based fuels in the near future. Catalytic deoxygenation process of fatty acid is getting attention from both academia and industry. Researchers have tried different techniques in the fatty acid deoxygenation to enhance the production of diesel-like hydrocarbons. This review paper elucidates the influence of tmain operating conditions towards achieving optimum yield and selectivity of desired products. The reaction pathways, the reaction kinetics as well as recent progress in deoxygenation of fatty acid for production of diesel-like hydrocarbons are also reviewed.

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  • Hermida, Lilis & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2015. "Deoxygenation of fatty acid to produce diesel-like hydrocarbons: A review of process conditions, reaction kinetics and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1223-1233.
    • Handle: RePEc:eee:rensus:v:42:y:2015:i:c:p:1223-1233
    DOI: 10.1016/j.rser.2014.10.099
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    10. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Yasir, Madiha, 2017. "Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1072-1088.
    11. Hancsók, Jenő & Visnyei, Olivér & Holló, András & Leveles, László & Thernesz, Artur & Varga, Géza & Valyon, József, 2019. "Alternative diesel fuels with high hydrogen content in their molecular structures," Renewable Energy, Elsevier, vol. 142(C), pages 239-248.
    12. Zamani, Ali Salehi & Saidi, Majid & Najafabadi, Ali Taheri, 2023. "Selective production of diesel-like alkanes via Neem seed oil hydrodeoxygenation over Ni/MgSiO3 catalyst," Renewable Energy, Elsevier, vol. 209(C), pages 462-470.
    13. Yoosuk, Boonyawan & Sanggam, Paphawee & Wiengket, Sakdipat & Prasassarakich, Pattarapan, 2019. "Hydrodeoxygenation of oleic acid and palmitic acid to hydrocarbon-like biofuel over unsupported Ni-Mo and Co-Mo sulfide catalysts," Renewable Energy, Elsevier, vol. 139(C), pages 1391-1399.
    14. Araújo, Aruzza Mabel de Morais & Lima, Regineide de Oliveira & Gondim, Amanda Duarte & Diniz, Juraci & Souza, Luiz Di & Araujo, Antonio Souza de, 2017. "Thermal and catalytic pyrolysis of sunflower oil using AlMCM-41," Renewable Energy, Elsevier, vol. 101(C), pages 900-906.
    15. Thongkumkoon, Skonrach & Kiatkittipong, Worapon & Hartley, Unalome Wetwatana & Laosiripojana, Navadol & Daorattanachai, Pornlada, 2019. "Catalytic activity of trimetallic sulfided Re-Ni-Mo/γ-Al2O3 toward deoxygenation of palm feedstocks," Renewable Energy, Elsevier, vol. 140(C), pages 111-123.

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