IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v173y2021icp886-895.html
   My bibliography  Save this article

Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts

Author

Listed:
  • Tran, Quoc Khanh
  • Ly, Hoang Vu
  • Kwon, Byeongwan
  • Kim, Seung-Soo
  • Kim, Jinsoo

Abstract

In this study, Ni/γ-Al2O3 and Fe/activated carbon (AC) catalysts were prepared by an incipient impregnation method and then utilized for hydrodeoxygenation (HDO) of guaiacol (GUA). The AC used in the process was derived from bamboo through steam activation. The effects of the calcination temperature, metal loading, and phosphorus addition on the HDO of GUA were systematically investigated. At 300 °C and atmospheric pressure, 91.52% of GUA was successfully transformed into cresol and 1,2-dimethoxybenzene in liquid phase using 10 wt% of the Fe/AC catalyst, which was calcined at 550 °C. Under the same reaction conditions, utilizing 10 wt% of the Ni/γ-Al2O3 catalyst, which was calcined at 450 °C, resulted in 96.88% GUA conversion, producing 13.03% of cresol, 58.98% of 1,2-dimethoxybenzene, and 27.99% of 3-methyl guaiacol. Additionally, the reaction pathways of the GUA HDO were proposed based on the obtained product distributions.

Suggested Citation

  • Tran, Quoc Khanh & Ly, Hoang Vu & Kwon, Byeongwan & Kim, Seung-Soo & Kim, Jinsoo, 2021. "Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts," Renewable Energy, Elsevier, vol. 173(C), pages 886-895.
    • Handle: RePEc:eee:renene:v:173:y:2021:i:c:p:886-895
    DOI: 10.1016/j.renene.2021.03.138
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121005024
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.03.138?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fan, Xu-dong & Wu, Yu-jian & Tu, Ren & Sun, Yan & Jiang, En-chen & Xu, Xi-wei, 2020. "Hydrodeoxygenation of guaiacol via rice husk char supported Ni based catalysts: The influence of char supports," Renewable Energy, Elsevier, vol. 157(C), pages 1035-1045.
    2. Xu, Xiwei & Jiang, Enchen & Du, Yanhong & Li, Bosong, 2016. "BTX from the gas-phase hydrodeoxygenation and transmethylation of guaiacol at room pressure," Renewable Energy, Elsevier, vol. 96(PA), pages 458-468.
    3. Li, Zhiyu & Jiang, Enchen & Xu, Xiwei & Sun, Yan & Tu, Ren, 2020. "Hydrodeoxygenation of phenols, acids, and ketones as model bio-oil for hydrocarbon fuel over Ni-based catalysts modified by Al, La and Ga," Renewable Energy, Elsevier, vol. 146(C), pages 1991-2007.
    4. Ly, Hoang Vu & Choi, Jae Hyung & Woo, Hee Chul & Kim, Seung-Soo & Kim, Jinsoo, 2019. "Upgrading bio-oil by catalytic fast pyrolysis of acid-washed Saccharina japonica alga in a fluidized-bed reactor," Renewable Energy, Elsevier, vol. 133(C), pages 11-22.
    5. Park, Seyoung & Jae, Jungho & Farooq, Abid & Kwon, Eilhann E. & Park, Eun Duck & Ha, Jeong-Myeong & Jung, Sang-Chul & Park, Young-Kwon, 2019. "Continuous pyrolysis of organosolv lignin and application of biochar on gasification of high density polyethylene," Applied Energy, Elsevier, vol. 255(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tai, Lingyu & Hamidi, Roya & de Caprariis, Benedetta & Damizia, Martina & Paglia, Laura & Scarsella, Marco & Karimzadeh, Ramin & De Filippis, Paolo, 2022. "Guaiacol hydrotreating with in-situ generated hydrogen over ni/modified zeolite supports," Renewable Energy, Elsevier, vol. 182(C), pages 647-658.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lv, Wei & Hu, Xiaohong & Zhu, Yuting & Xu, Ying & Liu, Shijun & Chen, Peili & Wang, Chenguang & Ma, Longlong, 2022. "Molybdenum oxide decorated Ru catalyst for enhancement of lignin oil hydrodeoxygenation to hydrocarbons," Renewable Energy, Elsevier, vol. 188(C), pages 195-210.
    2. Fan, Xudong & Wu, Yujian & Sun, Yan & Tu, Ren & Ren, Zhipeng & Liang, Kaili & Jiang, Enchen & Ren, Yongzhi & Xu, Xiwei, 2022. "Functional groups anchoring-induced Ni/MoOx-Ov interface on rice husk char for hydrodeoxygenation of bio-guaiacol to BTX at ambient-pressure," Renewable Energy, Elsevier, vol. 200(C), pages 579-591.
    3. Apip Amrullah & Obie Farobie & Asep Bayu & Novi Syaftika & Edy Hartulistiyoso & Navid R. Moheimani & Surachai Karnjanakom & Yukihiko Matsumura, 2022. "Slow Pyrolysis of Ulva lactuca (Chlorophyta) for Sustainable Production of Bio-Oil and Biochar," Sustainability, MDPI, vol. 14(6), pages 1-14, March.
    4. Xu, Xiwei & Jiang, Enchen & Li, Zhiyu & Zhu, Xiongfa & Sun, Yan & Tu, Ren, 2019. "Alkene and benzene derivate obtained from catalytic reforming of acetone-butanol-ethanol (ABE) from carbohydrates fermentation broth," Renewable Energy, Elsevier, vol. 135(C), pages 1213-1223.
    5. Guan, Weixiang & Chen, Xiao & Zhang, Jie & Hu, Haoquan & Liang, Changhai, 2020. "Catalytic transfer hydrogenolysis of lignin α-O-4 model compound 4-(benzyloxy)phenol and lignin over Pt/HNbWO6/CNTs catalyst," Renewable Energy, Elsevier, vol. 156(C), pages 249-259.
    6. Chen, Chao & Liang, Rui & Ge, Yadong & Li, Jian & Yan, Beibei & Cheng, Zhanjun & Tao, Junyu & Wang, Zhenyu & Li, Meng & Chen, Guanyi, 2022. "Fast characterization of biomass pyrolysis oil via combination of ATR-FTIR and machine learning models," Renewable Energy, Elsevier, vol. 194(C), pages 220-231.
    7. Bakhtyari, Ali & Rahimpour, Mohammad Reza & Raeissi, Sona, 2020. "Cobalt-molybdenum catalysts for the hydrodeoxygenation of cyclohexanone," Renewable Energy, Elsevier, vol. 150(C), pages 443-455.
    8. Ly, Hoang Vu & Park, Jeong Woo & Kim, Seung-Soo & Hwang, Hyun Tae & Kim, Jinsoo & Woo, Hee Chul, 2020. "Catalytic pyrolysis of bamboo in a bubbling fluidized-bed reactor with two different catalysts: HZSM-5 and red mud for upgrading bio-oil," Renewable Energy, Elsevier, vol. 149(C), pages 1434-1445.
    9. Tai, Lingyu & Hamidi, Roya & de Caprariis, Benedetta & Damizia, Martina & Paglia, Laura & Scarsella, Marco & Karimzadeh, Ramin & De Filippis, Paolo, 2022. "Guaiacol hydrotreating with in-situ generated hydrogen over ni/modified zeolite supports," Renewable Energy, Elsevier, vol. 182(C), pages 647-658.
    10. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    11. Fan, Xu-dong & Wu, Yu-jian & Li, Zhi-yu & Sun, Yan & Tu, Ren & Zhong, Pei-Dong & Jiang, En-chen & Xu, Xi-wei, 2020. "Benzene, toluene and xylene (BTX) from in-situ gas phase hydrodeoxygenation of guaiacol with liquid hydrogen donor over bifunctional non-noble-metal zeolite catalysts," Renewable Energy, Elsevier, vol. 152(C), pages 1391-1402.
    12. Park, Jeong-Woo & Heo, Juheon & Ly, Hoang Vu & Kim, Jinsoo & Lim, Hankwon & Kim, Seung-Soo, 2019. "Fast pyrolysis of acid-washed oil palm empty fruit bunch for bio-oil production in a bubbling fluidized-bed reactor," Energy, Elsevier, vol. 179(C), pages 517-527.
    13. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    14. Li, Zhiyu & Jiang, Enchen & Xu, Xiwei & Sun, Yan & Tu, Ren, 2020. "Hydrodeoxygenation of phenols, acids, and ketones as model bio-oil for hydrocarbon fuel over Ni-based catalysts modified by Al, La and Ga," Renewable Energy, Elsevier, vol. 146(C), pages 1991-2007.
    15. Wang, Chi-Hwa & Ok, Yong Sik & You, Siming & Wang, Xiaonan, 2020. "The research and development of waste-to-hydrogen technologies and systems," Applied Energy, Elsevier, vol. 268(C).
    16. Wu, Yujian & Xu, Xiwei & Sun, Yan & Jiang, Enchen & Fan, Xudong & Tu, Ren & Wang, Jiamin, 2020. "Gas-phase hydrodeoxygenation of guaiacol over Ni-based HUSY zeolite catalysts under atmospheric H2 pressure," Renewable Energy, Elsevier, vol. 152(C), pages 1380-1390.
    17. Kuang, Yongqi & Li, Hao, 2021. "Targeted engineering of metal@hollow carbon spheres as nanoreactors for biomass hydrodeoxygenation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:173:y:2021:i:c:p:886-895. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.