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Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts

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  • Tran, Quoc Khanh
  • Ly, Hoang Vu
  • Kwon, Byeongwan
  • Kim, Seung-Soo
  • Kim, Jinsoo

Abstract

In this study, Ni/γ-Al2O3 and Fe/activated carbon (AC) catalysts were prepared by an incipient impregnation method and then utilized for hydrodeoxygenation (HDO) of guaiacol (GUA). The AC used in the process was derived from bamboo through steam activation. The effects of the calcination temperature, metal loading, and phosphorus addition on the HDO of GUA were systematically investigated. At 300 °C and atmospheric pressure, 91.52% of GUA was successfully transformed into cresol and 1,2-dimethoxybenzene in liquid phase using 10 wt% of the Fe/AC catalyst, which was calcined at 550 °C. Under the same reaction conditions, utilizing 10 wt% of the Ni/γ-Al2O3 catalyst, which was calcined at 450 °C, resulted in 96.88% GUA conversion, producing 13.03% of cresol, 58.98% of 1,2-dimethoxybenzene, and 27.99% of 3-methyl guaiacol. Additionally, the reaction pathways of the GUA HDO were proposed based on the obtained product distributions.

Suggested Citation

  • Tran, Quoc Khanh & Ly, Hoang Vu & Kwon, Byeongwan & Kim, Seung-Soo & Kim, Jinsoo, 2021. "Catalytic hydrodeoxygenation of guaiacol as a model compound of woody bio-oil over Fe/AC and Ni/γ-Al2O3 catalysts," Renewable Energy, Elsevier, vol. 173(C), pages 886-895.
    • Handle: RePEc:eee:renene:v:173:y:2021:i:c:p:886-895
    DOI: 10.1016/j.renene.2021.03.138
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    References listed on IDEAS

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    1. Fan, Xu-dong & Wu, Yu-jian & Tu, Ren & Sun, Yan & Jiang, En-chen & Xu, Xi-wei, 2020. "Hydrodeoxygenation of guaiacol via rice husk char supported Ni based catalysts: The influence of char supports," Renewable Energy, Elsevier, vol. 157(C), pages 1035-1045.
    2. Xu, Xiwei & Jiang, Enchen & Du, Yanhong & Li, Bosong, 2016. "BTX from the gas-phase hydrodeoxygenation and transmethylation of guaiacol at room pressure," Renewable Energy, Elsevier, vol. 96(PA), pages 458-468.
    3. Park, Seyoung & Jae, Jungho & Farooq, Abid & Kwon, Eilhann E. & Park, Eun Duck & Ha, Jeong-Myeong & Jung, Sang-Chul & Park, Young-Kwon, 2019. "Continuous pyrolysis of organosolv lignin and application of biochar on gasification of high density polyethylene," Applied Energy, Elsevier, vol. 255(C).
    4. Li, Zhiyu & Jiang, Enchen & Xu, Xiwei & Sun, Yan & Tu, Ren, 2020. "Hydrodeoxygenation of phenols, acids, and ketones as model bio-oil for hydrocarbon fuel over Ni-based catalysts modified by Al, La and Ga," Renewable Energy, Elsevier, vol. 146(C), pages 1991-2007.
    5. Ly, Hoang Vu & Choi, Jae Hyung & Woo, Hee Chul & Kim, Seung-Soo & Kim, Jinsoo, 2019. "Upgrading bio-oil by catalytic fast pyrolysis of acid-washed Saccharina japonica alga in a fluidized-bed reactor," Renewable Energy, Elsevier, vol. 133(C), pages 11-22.
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    1. Tai, Lingyu & Hamidi, Roya & de Caprariis, Benedetta & Damizia, Martina & Paglia, Laura & Scarsella, Marco & Karimzadeh, Ramin & De Filippis, Paolo, 2022. "Guaiacol hydrotreating with in-situ generated hydrogen over ni/modified zeolite supports," Renewable Energy, Elsevier, vol. 182(C), pages 647-658.

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