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Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack

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  • Chen, Dongfang
  • Pei, Pucheng
  • Ren, Peng
  • Song, Xin
  • Wang, He
  • Zhang, Lu
  • Wang, Mingkai

Abstract

Buckets effect remains one of the most important factors limiting the fuel cell stack performance and lifetime. An experiment on a 16-cell stack with decreasing hydrogen concentration is conducted to investigate the effect of anode nitrogen concentration on stack performance and voltage consistency. The mean voltage decay rate of the stack is only 6% at the current density of 1.0 A cm−2, but the decay rate of the single cell with minimum voltage reaches up to 18%. The voltage standard deviation of the fuel cell stack increases by about 8 mV with the decrease in hydrogen concentration from 100% to 85%. Results show that the local voltage standard deviation is as high as 30 mV at 85% hydrogen concentration when the 16 cells are divided into four groups. The influence of local voltage consistency on the overall voltage consistency is further studied. The local voltage consistency can be served as a reliable indicator of anode purge strategy. Moreover, the uneven gas distribution amongst the cells in the stack can be analyzed and effectively detected, according to the local voltage consistency analysis with the experiment of anode nitrogen doping.

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  • Chen, Dongfang & Pei, Pucheng & Ren, Peng & Song, Xin & Wang, He & Zhang, Lu & Wang, Mingkai, 2022. "Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 258(C).
    • Handle: RePEc:eee:energy:v:258:y:2022:i:c:s0360544222017534
    DOI: 10.1016/j.energy.2022.124850
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    Cited by:

    1. Meng, Huanru & Yu, Xianxian & Luo, Xiaobing & Tu, Zhengkai, 2024. "Modelling and operation characteristics of air-cooled PEMFC with metallic bipolar plate used in unmanned aerial vehicle," Energy, Elsevier, vol. 300(C).
    2. Ruifeng Guo & Dongfang Chen & Yuehua Li & Wenlong Wu & Song Hu & Xiaoming Xu, 2023. "Anode Nitrogen Concentration Estimation Based on Voltage Variation Characteristics for Proton Exchange Membrane Fuel Cell Stacks," Energies, MDPI, vol. 16(5), pages 1-16, February.
    3. Pei, Pucheng & Meng, Yining & Chen, Dongfang & Ren, Peng & Wang, Mingkai & Wang, Xizhong, 2023. "Lifetime prediction method of proton exchange membrane fuel cells based on current degradation law," Energy, Elsevier, vol. 265(C).
    4. Yu, Xianxian & Cai, Shanshan & Luo, Xiaobing & Tu, Zhengkai, 2024. "Barrel effect in an air-cooled proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 286(C).
    5. Cabello González, G.M. & Toharias, Baltasar & Iranzo, Alfredo & Suárez, Christian & Rosa, Felipe, 2023. "Voltage distribution analysis and non-uniformity assessment in a 100 cm2 PEM fuel cell stack," Energy, Elsevier, vol. 282(C).
    6. Zhao, Lei & Yuan, Hao & Xie, Jiaping & Jiang, Shangfeng & Wei, Xuezhe & Tang, Wei & Ming, Pingwen & Dai, Haifeng, 2023. "Inconsistency evaluation of vehicle-oriented fuel cell stacks based on electrochemical impedance under dynamic operating conditions," Energy, Elsevier, vol. 265(C).
    7. Yin, Ren-Jie & Zeng, Wen-Chao & Bai, Fan & Chen, Li & Tao, Wen-Quan, 2024. "Study on the effects of manifold structure on the gas flow distribution uniformity of anode of PEMFC stack with 140-cell," Renewable Energy, Elsevier, vol. 221(C).

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