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Low temperature durability and consistency analysis of proton exchange membrane fuel cell stack based on comprehensive characterizations

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  • Zhong, Di
  • Lin, Rui
  • Jiang, Zhenghua
  • Zhu, Yike
  • Liu, Dengchen
  • Cai, Xin
  • Chen, Liang

Abstract

The cold start is one of the key research fields in proton exchange membrane fuel cell investigation. In this work, a low temperature durability and consistency analysis is performed on a 5-cells stack. After 20 times freezing and thaw cycles, coefficient of variation of individual cell voltage increase significantly. Through the polarization curve test, it is found that the output performance degradation of each individual cell is inconsistent. The No.1 cell which is the nearest from the gas inlets has the maximum performance degradation. Through electrochemical impedance spectroscopy, cyclic voltammetry, scanning electron microscope, segmented current density test and synchrotron radiation X-ray scan 3D image reconstruction, the cracks on the interface of membrane and catalyst layer are observed in situ successfully for the first time. Under the condition in this work, the water content of No.1 cell is the most, and a lot amount of water is frozen at the air inlet area. Due to the frost heave stress, the structure of membrane electrode assembly is damaged. This causes the loss and the agglomeration of catalyst, and even the delamination of catalyst layer. The above structure changes cause a decrease in catalyst activity and an increase in cell resistance, and eventually lead to the inconsistent degradation in output performance. The characterization results in this work are helpful for the optimization and application of membrane electrodes assembly and stacks for vehicle fuel cells.

Suggested Citation

  • Zhong, Di & Lin, Rui & Jiang, Zhenghua & Zhu, Yike & Liu, Dengchen & Cai, Xin & Chen, Liang, 2020. "Low temperature durability and consistency analysis of proton exchange membrane fuel cell stack based on comprehensive characterizations," Applied Energy, Elsevier, vol. 264(C).
    • Handle: RePEc:eee:appene:v:264:y:2020:i:c:s0306261920301380
    DOI: 10.1016/j.apenergy.2020.114626
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    References listed on IDEAS

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    4. Pengcheng Liu & Sichuan Xu, 2022. "Experimental Research on the Dynamic Characteristics and Voltage Uniformity of a PEMFC Stack under Subzero Temperatures," Energies, MDPI, vol. 15(9), pages 1-14, April.
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    7. Daeichian, Abolghasem & Ghaderi, Razieh & Kandidayeni, Mohsen & Soleymani, Mehdi & Trovão, João P. & Boulon, Loïc, 2021. "Online characteristics estimation of a fuel cell stack through covariance intersection data fusion," Applied Energy, Elsevier, vol. 292(C).
    8. Zhao, Chen & Wang, Fei & Wu, Xiaoyu, 2024. "Analysis and review on air-cooled open cathode proton exchange membrane fuel cells: Bibliometric, environmental adaptation and prospect," Renewable and Sustainable Energy Reviews, Elsevier, vol. 197(C).
    9. Zhu, Xinning & Liu, Rongkang & Su, Liang & Wang, Xi & Chu, Xuyang & Ma, Yao & Wu, Linjing & Song, Guangji & Zhou, Wei, 2023. "Synergistic mass transfer and performance stability of a proton exchange membrane fuel cell with traveling wave flow channels," Energy, Elsevier, vol. 285(C).
    10. Mohsen Kandidayeni & Alvaro Macias & Loïc Boulon & João Pedro F. Trovão, 2020. "Online Modeling of a Fuel Cell System for an Energy Management Strategy Design," Energies, MDPI, vol. 13(14), pages 1-17, July.
    11. Zizhe Dong & Yuwen Liu & Yanzhou Qin, 2022. "Coupled FEM and CFD Modeling of Structure Deformation and Performance of PEMFC Considering the Effects of Membrane Water Content," Energies, MDPI, vol. 15(15), pages 1-19, July.
    12. Wu, Kangcheng & Du, Qing & Zu, Bingfeng & Wang, Yupeng & Cai, Jun & Gu, Xin & Xuan, Jin & Jiao, Kui, 2021. "Enabling real-time optimization of dynamic processes of proton exchange membrane fuel cell: Data-driven approach with semi-recurrent sliding window method," Applied Energy, Elsevier, vol. 303(C).
    13. Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
    14. Dan Wang & Haitao Min & Honghui Zhao & Weiyi Sun & Bin Zeng & Qun Ma, 2024. "A Data-Driven Prediction Method for Proton Exchange Membrane Fuel Cell Degradation," Energies, MDPI, vol. 17(4), pages 1-17, February.
    15. Tao, Xingxiao & Sun, Kai & Chen, Rui & Li, Qifeng & Liu, Huaiyu & Zhang, Wenzhe & Che, Zhizhao & Wang, Tianyou, 2024. "Effect of gas diffusion layer parameters on cold start of PEMFCs with metal foam flow field," Applied Energy, Elsevier, vol. 364(C).
    16. Yang, Liu & Cao, Chenxi & Gan, Quanquan & Pei, Hao & Zhang, Qi & Li, Ping, 2022. "Revealing failure modes and effect of catalyst layer properties for PEM fuel cell cold start using an agglomerate model," Applied Energy, Elsevier, vol. 312(C).
    17. Yang, Zirong & Jiao, Kui & Wu, Kangcheng & Shi, Weilong & Jiang, Shangfeng & Zhang, Longhai & Du, Qing, 2021. "Numerical investigations of assisted heating cold start strategies for proton exchange membrane fuel cell systems," Energy, Elsevier, vol. 222(C).
    18. Fan, Lixin & Tu, Zhengkai & Chan, Siew Hwa, 2022. "Technological and Engineering design of a megawatt proton exchange membrane fuel cell system," Energy, Elsevier, vol. 257(C).
    19. Bai, Xingying & Luo, Lizhong & Huang, Bi & Huang, Zhe & Jian, Qifei, 2021. "Flow characteristics analysis for multi-path hydrogen supply within proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 301(C).
    20. Zhang, Zhuo & Wang, Qi-yao & Bai, Fan & Chen, Li & Tao, Wen-quan, 2023. "Performance simulation and key parameters in-plane distribution analysis of a commercial-size PEMFC," Energy, Elsevier, vol. 263(PC).
    21. Chen, Dongfang & Pei, Pucheng & Ren, Peng & Song, Xin & Wang, He & Zhang, Lu & Wang, Mingkai, 2022. "Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 258(C).

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