IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v275y2020ics030626192030622x.html
   My bibliography  Save this article

Anode purge management for hydrogen utilization and stack durability improvement of PEM fuel cell systems

Author

Listed:
  • Liu, Zhiyang
  • Chen, Jian
  • Liu, Hao
  • Yan, Chizhou
  • Hou, Yang
  • He, Qinggang
  • Zhang, Jiujun
  • Hissel, Daniel

Abstract

Proton exchange membrane fuel cell (PEMFC) is one of the most promising power sources for vehicle applications. However, improving efficiency has always been the focus of researches for PEMFCs. To improve the hydrogen utilization and protect the stack of PEMFC systems, a general anode purge scheme is proposed in this paper. Firstly, based on a typical topology of the hydrogen delivery subsystem, the water management of the anode loop is introduced to decouple the performance degradation caused by nitrogen accumulation from water flooding. For the purge strategy, an accurate and fast anode nitrogen concentration observer is established to determine the purge interval. Then, the purge duration is determined by the simulation analysis. Finally, the effectiveness and reliability of the proposed anode purge scheme are verified by testing a new and an aged commercial PEMFC stack. Experimental results show that the proposed anode purge strategy increases the hydrogen utilization rate of the actual PEMFC system to 99% (with considering the hydrogen crossover loss) and greatly prolongs the purge interval based on the real-time estimation of the anode nitrogen concentration.

Suggested Citation

  • Liu, Zhiyang & Chen, Jian & Liu, Hao & Yan, Chizhou & Hou, Yang & He, Qinggang & Zhang, Jiujun & Hissel, Daniel, 2020. "Anode purge management for hydrogen utilization and stack durability improvement of PEM fuel cell systems," Applied Energy, Elsevier, vol. 275(C).
    • Handle: RePEc:eee:appene:v:275:y:2020:i:c:s030626192030622x
    DOI: 10.1016/j.apenergy.2020.115110
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626192030622X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2020.115110?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Yong-Song & Yang, Chih-Wei & Lee, Jiunn-Yih, 2014. "Implementation and evaluation for anode purging of a fuel cell based on nitrogen concentration," Applied Energy, Elsevier, vol. 113(C), pages 1519-1524.
    2. Chen, Ben & Wang, Jun & Yang, Tianqi & Cai, Yonghua & Zhang, Caizhi & Chan, Siew Hwa & Yu, Yi & Tu, Zhengkai, 2016. "Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode," Energy, Elsevier, vol. 106(C), pages 54-62.
    3. Rabbani, Abid & Rokni, Masoud, 2013. "Effect of nitrogen crossover on purging strategy in PEM fuel cell systems," Applied Energy, Elsevier, vol. 111(C), pages 1061-1070.
    4. Chen, Ben & Cai, Yonghua & Yu, Yi & Wang, Jun & Tu, Zhengkai & Chan, Siew Hwa, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation II. Under different operation pressures," Energy, Elsevier, vol. 131(C), pages 50-57.
    5. Zachary P. Cano & Dustin Banham & Siyu Ye & Andreas Hintennach & Jun Lu & Michael Fowler & Zhongwei Chen, 2018. "Batteries and fuel cells for emerging electric vehicle markets," Nature Energy, Nature, vol. 3(4), pages 279-289, April.
    6. Wang, Bowen & Deng, Hao & Jiao, Kui, 2018. "Purge strategy optimization of proton exchange membrane fuel cell with anode recirculation," Applied Energy, Elsevier, vol. 225(C), pages 1-13.
    7. Chen, Ben & Cai, Yonghua & Tu, Zhengkai & Chan, Siew Hwa & Wang, Jun & Yu, Yi, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With different electrolytes," Energy, Elsevier, vol. 141(C), pages 40-49.
    8. Jung, Aeri & Oh, Jongkil & Han, Kookil & Kim, Min Soo, 2016. "An experimental study on the hydrogen crossover in polymer electrolyte membrane fuel cells for various current densities," Applied Energy, Elsevier, vol. 175(C), pages 212-217.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liu, Yang & Tu, Zhengkai & Chan, Siew Hwa, 2023. "Water management and performance enhancement in a proton exchange membrane fuel cell system using optimized gas recirculation devices," Energy, Elsevier, vol. 279(C).
    2. Chen, Huicui & Zhang, Ruirui & Xia, Zhifeng & Weng, Qianyao & Zhang, Tong & Pei, Pucheng, 2023. "Experimental investigation on PEM fuel cell flooding mitigation under heavy loading condition," Applied Energy, Elsevier, vol. 349(C).
    3. Ruifeng Guo & Dongfang Chen & Yuehua Li & Wenlong Wu & Song Hu & Xiaoming Xu, 2023. "Anode Nitrogen Concentration Estimation Based on Voltage Variation Characteristics for Proton Exchange Membrane Fuel Cell Stacks," Energies, MDPI, vol. 16(5), pages 1-16, February.
    4. Bahrami, Milad & Martin, Jean-Philippe & Maranzana, Gaël & Pierfederici, Serge & Weber, Mathieu & Didierjean, Sophie, 2022. "Fuel cell management system: An approach to increase its durability," Applied Energy, Elsevier, vol. 306(PB).
    5. Lü, Xueqin & Deng, Ruiyu & Chen, Chao & Wu, Yinbo & Meng, Ruidong & Long, Liyuan, 2022. "Performance optimization of fuel cell hybrid power robot based on power demand prediction and model evaluation," Applied Energy, Elsevier, vol. 316(C).
    6. Liu, Shihua & Li, Xiaoyang & Pang, Linjia & Geng, Tie & Guo, Yonggang & Jiang, Lin & Kang, Kejia & Wang, Xinchao & Liu, Zongyao, 2022. "Study on the effect of purging time on the performance of PEMFC with dead-ended anode under gravity," Renewable Energy, Elsevier, vol. 200(C), pages 1141-1151.
    7. Jianmei Feng & Jiquan Han & Zihui Pang & Xueyuan Peng, 2023. "Designing Hydrogen Recirculation Ejectors for Proton Exchange Membrane Fuel Cell Systems," Energies, MDPI, vol. 16(3), pages 1-10, January.
    8. Yang, Yange & Li, Xiang & Tang, Fumin & Ming, Pingwen & Li, Bing & Zhang, Cunman, 2022. "Power evolution of fuel cell stack driven by anode gas diffusion layer degradation," Applied Energy, Elsevier, vol. 313(C).
    9. Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
    10. Shen, Jun & Du, Changqing & Yan, Fuwu & Chen, Ben & Tu, Zhengkai, 2022. "Experimental study on the dynamic performance of a power system with dual air-cooled PEMFC stacks," Applied Energy, Elsevier, vol. 326(C).
    11. Lei, Gang & Zheng, Hualin & Zhang, Jun & Siong Chin, Cheng & Xu, Xinhai & Zhou, Weijiang & Zhang, Caizhi, 2023. "Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect," Energy, Elsevier, vol. 282(C).
    12. Quan, Shengwei & Wang, Ya-Xiong & Xiao, Xuelian & He, Hongwen & Sun, Fengchun, 2021. "Feedback linearization-based MIMO model predictive control with defined pseudo-reference for hydrogen regulation of automotive fuel cells," Applied Energy, Elsevier, vol. 293(C).
    13. Chen, Xin & Zhang, Ying & Xu, Sheng & Dong, Fei, 2023. "Bibliometric analysis for research trends and hotspots in heat and mass transfer and its management of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 333(C).
    14. Song, Yajie & Wang, Xinli & Wang, Lei & Pan, Fengwen & Chen, Wenmiao & Xi, Fuqiang, 2021. "A twin-nozzle ejector for hydrogen recirculation in wide power operation of polymer electrolyte membrane fuel cell system," Applied Energy, Elsevier, vol. 300(C).
    15. Xu, Sheng & Yin, Bifeng & Li, Zekai & Dong, Fei, 2023. "A review on gas purge of proton exchange membrane fuel cells: Mechanisms, experimental approaches, numerical approaches, and optimization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 172(C).
    16. Yanbo Yang & Tiancai Ma & Boyu Du & Weikang Lin & Naiyuan Yao, 2021. "Investigation on the Operating Conditions of Proton Exchange Membrane Fuel Cell Based on Constant Voltage Cold Start Mode," Energies, MDPI, vol. 14(3), pages 1-10, January.
    17. Yuemeng Zhang & Jia Wang & Zhanhui Yao, 2023. "Recent Development of Fuel Cell Core Components and Key Materials: A Review," Energies, MDPI, vol. 16(5), pages 1-23, February.
    18. Ireneusz Pielecha & Filip Szwajca & Kinga Skobiej, 2023. "Load Capacity of Nickel–Metal Hydride Battery and Proton-Exchange-Membrane Fuel Cells in the Fuel-Cell-Hybrid-Electric-Vehicle Powertrain," Energies, MDPI, vol. 16(22), pages 1-14, November.
    19. Chen, Dongfang & Pei, Pucheng & Ren, Peng & Song, Xin & Wang, He & Zhang, Lu & Wang, Mingkai, 2022. "Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 258(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Bowen & Deng, Hao & Jiao, Kui, 2018. "Purge strategy optimization of proton exchange membrane fuel cell with anode recirculation," Applied Energy, Elsevier, vol. 225(C), pages 1-13.
    2. Chen, Dongfang & Pei, Pucheng & Ren, Peng & Song, Xin & Wang, He & Zhang, Lu & Wang, Mingkai, 2022. "Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 258(C).
    3. Steinberger, Michael & Geiling, Johannes & Oechsner, Richard & Frey, Lothar, 2018. "Anode recirculation and purge strategies for PEM fuel cell operation with diluted hydrogen feed gas," Applied Energy, Elsevier, vol. 232(C), pages 572-582.
    4. Wang, Bowen & Wu, Kangcheng & Xi, Fuqiang & Xuan, Jin & Xie, Xu & Wang, Xiaoyang & Jiao, Kui, 2019. "Numerical analysis of operating conditions effects on PEMFC with anode recirculation," Energy, Elsevier, vol. 173(C), pages 844-856.
    5. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    6. Chen, Ben & Zhou, Haoran & He, Shaowen & Meng, Kai & Liu, Yang & Cai, Yonghua, 2021. "Numerical simulation on purge strategy of proton exchange membrane fuel cell with dead-ended anode," Energy, Elsevier, vol. 234(C).
    7. Dashti, Isar & Asghari, Saeed & Goudarzi, Mohammad & Meyer, Quentin & Mehrabani-Zeinabad, Arjomand & Brett, Dan J.L., 2019. "Optimization of the performance, operation conditions and purge rate for a dead-ended anode proton exchange membrane fuel cell using an analytical model," Energy, Elsevier, vol. 179(C), pages 173-185.
    8. Meng, Kai & Zhou, Haoran & Chen, Ben & Tu, Zhengkai, 2021. "Dynamic current cycles effect on the degradation characteristic of a H2/O2 proton exchange membrane fuel cell," Energy, Elsevier, vol. 224(C).
    9. Chen, Ben & Cai, Yonghua & Tu, Zhengkai & Chan, Siew Hwa & Wang, Jun & Yu, Yi, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With different electrolytes," Energy, Elsevier, vol. 141(C), pages 40-49.
    10. Liu, Shihua & Chen, Tao & Zhang, Cheng & Xie, Yi, 2020. "Study on the performance of proton exchange membrane fuel cell (PEMFC) with dead-ended anode in gravity environment," Applied Energy, Elsevier, vol. 261(C).
    11. Liu, Yang & Tu, Zhengkai & Chan, Siew Hwa, 2023. "Water management and performance enhancement in a proton exchange membrane fuel cell system using optimized gas recirculation devices," Energy, Elsevier, vol. 279(C).
    12. Hou, Junbo & Yang, Min & Zhang, Junliang, 2020. "Active and passive fuel recirculation for solid oxide and proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 155(C), pages 1355-1371.
    13. Yang, Zirong & Du, Qing & Jia, Zhiwei & Yang, Chunguang & Jiao, Kui, 2019. "Effects of operating conditions on water and heat management by a transient multi-dimensional PEMFC system model," Energy, Elsevier, vol. 183(C), pages 462-476.
    14. Zhang, Qinguo & Tong, Zheming & Tong, Shuiguang & Cheng, Zhewu, 2021. "Modeling and dynamic performance research on proton exchange membrane fuel cell system with hydrogen cycle and dead-ended anode," Energy, Elsevier, vol. 218(C).
    15. Wang, Chuang & Liu, Mingkun & Li, Zengqun & Xing, Ziwen & Shu, Yue, 2023. "Performance improvement of twin-screw air expander used in PEMFC systems by two-phase expansion," Energy, Elsevier, vol. 273(C).
    16. Chen, Huicui & Zhang, Ruirui & Xia, Zhifeng & Weng, Qianyao & Zhang, Tong & Pei, Pucheng, 2023. "Experimental investigation on PEM fuel cell flooding mitigation under heavy loading condition," Applied Energy, Elsevier, vol. 349(C).
    17. Tsai, Shang-Wen & Chen, Yong-Song, 2017. "A mathematical model to study the energy efficiency of a proton exchange membrane fuel cell with a dead-ended anode," Applied Energy, Elsevier, vol. 188(C), pages 151-159.
    18. Ma, Shuai & Lin, Meng & Lin, Tzu-En & Lan, Tian & Liao, Xun & Maréchal, François & Van herle, Jan & Yang, Yongping & Dong, Changqing & Wang, Ligang, 2021. "Fuel cell-battery hybrid systems for mobility and off-grid applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    19. shi, Lei & Tang, Xingwang & Xu, Sichuan & Liu, Ze, 2024. "Numerical research on liquid water removal mechanism and the influence of pore structure on water removal rate based on real pore GDL structure during shutdown purge of fuel cell," Energy, Elsevier, vol. 288(C).
    20. Liu, Yang & Zhao, Junjie & Tu, Zhengkai, 2024. "Detecting performance degradation in a dead-ended hydrogen-oxygen proton exchange membrane fuel cell used for an unmanned underwater vehicle," Renewable Energy, Elsevier, vol. 222(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:275:y:2020:i:c:s030626192030622x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.