IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v115y2016ip1p550-560.html
   My bibliography  Save this article

Experimental study of variable operating parameters effects on overall PEMFC performance and spatial performance distribution

Author

Listed:
  • Zhang, Qian
  • Lin, Rui
  • Técher, Ludovic
  • Cui, Xin

Abstract

Back pressure, relative humidity and air stoichiometry, these operational parameters have a crucial influence on the performance of PEMFC. Overall performance, stability and homogeneity of spatial performance distribution under variable operating parameters are in this paper researched. Polarization curves and Electrochemical Impedance Spectroscopy (EIS) are utilized to show the overall performance and resistance losses of PEMFC at variable operating parameters, while the segmented cell technique can provide real-time spatial current density distribution to reflect the uniformity and stability of the performance. Higher back pressure is an effective approach to improve the overall performance of the fuel cell whereas the uniformity keeps constant and the local stability decreases. The back pressure should be limited to some extent (0.3 bar in this paper). With the relative humidity increasing to a value (70% in this paper), overall performance and current distribution homogeneity of PEMFC enhance, but the stability sustains. Under higher air stoichiometry the fuel cell shows better overall and local performance, current distribution homogeneity and local stability. It's found that in all cases the performance near the outlet parts are worst due to poor water management and low gas concentration which could not be effectively enhanced by optimization of these operating conditions.

Suggested Citation

  • Zhang, Qian & Lin, Rui & Técher, Ludovic & Cui, Xin, 2016. "Experimental study of variable operating parameters effects on overall PEMFC performance and spatial performance distribution," Energy, Elsevier, vol. 115(P1), pages 550-560.
    • Handle: RePEc:eee:energy:v:115:y:2016:i:p1:p:550-560
    DOI: 10.1016/j.energy.2016.08.086
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544216311999
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2016.08.086?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gomez, Alberto & Raj, Abhishek & Sasmito, Agus P. & Shamim, Tariq, 2014. "Effect of operating parameters on the transient performance of a polymer electrolyte membrane fuel cell stack with a dead-end anode," Applied Energy, Elsevier, vol. 130(C), pages 692-701.
    2. Pérez, Luis C. & Brandão, Lúcia & Sousa, José M. & Mendes, Adélio, 2011. "Segmented polymer electrolyte membrane fuel cells--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 169-185, January.
    3. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    4. Chen, Ben & Wang, Jun & Yang, Tianqi & Cai, Yonghua & Zhang, Caizhi & Chan, Siew Hwa & Yu, Yi & Tu, Zhengkai, 2016. "Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode," Energy, Elsevier, vol. 106(C), pages 54-62.
    5. Abdollahzadeh, M. & Pascoa, J.C. & Ranjbar, A.A. & Esmaili, Q., 2014. "Analysis of PEM (Polymer Electrolyte Membrane) fuel cell cathode two-dimensional modeling," Energy, Elsevier, vol. 68(C), pages 478-494.
    6. Chen, Ben & Ke, Wandi & Luo, Maji & Wang, Jun & Tu, Zhengkai & Pan, Mu & Zhang, Haining & Liu, Xiaowei & Liu, Wei, 2015. "Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization," Energy, Elsevier, vol. 91(C), pages 799-806.
    7. Kong, Im Mo & Jung, Aeri & Kim, Beom Jun & Baik, Kyung Don & Kim, Min Soo, 2015. "Experimental study on the start-up with dry gases from normal cell temperatures in self-humidified proton exchange membrane fuel cells," Energy, Elsevier, vol. 93(P1), pages 57-66.
    8. Xing, Lei & Cai, Qiong & Xu, Chenxi & Liu, Chunbo & Scott, Keith & Yan, Yongsheng, 2016. "Numerical study of the effect of relative humidity and stoichiometric flow ratio on PEM (proton exchange membrane) fuel cell performance with various channel lengths: An anode partial flooding modelli," Energy, Elsevier, vol. 106(C), pages 631-645.
    9. Zhiani, Mohammad & Majidi, Somayeh & Silva, Valter Bruno & Gharibi, Hussein, 2016. "Comparison of the performance and EIS (electrochemical impedance spectroscopy) response of an activated PEMFC (proton exchange membrane fuel cell) under low and high thermal and pressure stresses," Energy, Elsevier, vol. 97(C), pages 560-567.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    2. Chen, Ben & Cai, Yonghua & Yu, Yi & Wang, Jun & Tu, Zhengkai & Chan, Siew Hwa, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation II. Under different operation pressures," Energy, Elsevier, vol. 131(C), pages 50-57.
    3. Abdin, Z. & Webb, C.J. & Gray, E.MacA., 2016. "PEM fuel cell model and simulation in Matlab–Simulink based on physical parameters," Energy, Elsevier, vol. 116(P1), pages 1131-1144.
    4. Hu, Junming & Li, Jianqiu & Xu, Liangfei & Huang, Fusen & Ouyang, Minggao, 2016. "Analytical calculation and evaluation of water transport through a proton exchange membrane fuel cell based on a one-dimensional model," Energy, Elsevier, vol. 111(C), pages 869-883.
    5. Oh, Taek Hyun, 2016. "A formic acid hydrogen generator using Pd/C3N4 catalyst for mobile proton exchange membrane fuel cell systems," Energy, Elsevier, vol. 112(C), pages 679-685.
    6. Chowdhury, Mohammad Ziauddin & Timurkutluk, Bora, 2018. "Transport phenomena of convergent and divergent serpentine flow fields for PEMFC," Energy, Elsevier, vol. 161(C), pages 104-117.
    7. Chen, Ben & Cai, Yonghua & Tu, Zhengkai & Chan, Siew Hwa & Wang, Jun & Yu, Yi, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With different electrolytes," Energy, Elsevier, vol. 141(C), pages 40-49.
    8. Chen, Ben & Wang, Jun & Yang, Tianqi & Cai, Yonghua & Zhang, Caizhi & Chan, Siew Hwa & Yu, Yi & Tu, Zhengkai, 2016. "Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode," Energy, Elsevier, vol. 106(C), pages 54-62.
    9. Yin, Cong & Gao, Jianlong & Wen, Xuhui & Xie, Guangyou & Yang, Chunhua & Fang, Honglin & Tang, Hao, 2016. "In situ investigation of proton exchange membrane fuel cell performance with novel segmented cell design and a two-phase flow model," Energy, Elsevier, vol. 113(C), pages 1071-1089.
    10. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    11. Xu, Liangfei & Fang, Chuan & Hu, Junming & Cheng, Siliang & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2017. "Parameter extraction of polymer electrolyte membrane fuel cell based on quasi-dynamic model and periphery signals," Energy, Elsevier, vol. 122(C), pages 675-690.
    12. Tsai, Shang-Wen & Chen, Yong-Song, 2017. "A mathematical model to study the energy efficiency of a proton exchange membrane fuel cell with a dead-ended anode," Applied Energy, Elsevier, vol. 188(C), pages 151-159.
    13. Wu, Horng-Wen, 2016. "A review of recent development: Transport and performance modeling of PEM fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 81-106.
    14. Wang, Bowen & Deng, Hao & Jiao, Kui, 2018. "Purge strategy optimization of proton exchange membrane fuel cell with anode recirculation," Applied Energy, Elsevier, vol. 225(C), pages 1-13.
    15. Lin, R. & Ren, Y.S. & Lin, X.W. & Jiang, Z.H. & Yang, Z. & Chang, Y.T., 2017. "Investigation of the internal behavior in segmented PEMFCs of different flow fields during cold start process," Energy, Elsevier, vol. 123(C), pages 367-377.
    16. Barzegari, Mohammad M. & Dardel, Morteza & Alizadeh, Ebrahim & Ramiar, Abas, 2016. "Reduced-order model of cascade-type PEM fuel cell stack with integrated humidifiers and water separators," Energy, Elsevier, vol. 113(C), pages 683-692.
    17. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    18. Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
    19. Chen, Huicui & Zhao, Xin & Qu, Bingwang & Zhang, Tong & Pei, Pucheng & Li, Congxin, 2018. "An evaluation method of gas distribution quality in dynamic process of proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 232(C), pages 26-35.
    20. Xu, Liangfei & Fang, Chuan & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2018. "Nonlinear dynamic mechanism modeling of a polymer electrolyte membrane fuel cell with dead-ended anode considering mass transport and actuator properties," Applied Energy, Elsevier, vol. 230(C), pages 106-121.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:115:y:2016:i:p1:p:550-560. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.