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Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation II. Under different operation pressures

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  • Chen, Ben
  • Cai, Yonghua
  • Yu, Yi
  • Wang, Jun
  • Tu, Zhengkai
  • Chan, Siew Hwa

Abstract

Gas purging is an effective method to remove the accumulated nitrogen and liquid water during the dead-end operation of polymer electrode membrane fuel cell (PEMFC). The effect of the operation pressure on the degradation characteristic of single cell is investigated under continuous gas purging cycles. Various diagnostic techniques including electrochemical characterization, physicochemical properties, and microstructure of the membrane electrode assembly (MEA) are applied to characterize the performance of the assembled single cells. After 1000 purging cycles, the single cell exhibits an obvious performance degradation, which can be proven from the change of the electrochemical surface area (ECSA), contact angle, cracks on the membrane and membrane thickness. The single cell with a relatively low oxygen pressure of 50 kPa has serious performance degradation. Comparatively, the assembled PEMFC has an enhanced durability with a high oxygen pressure of 200 kPa during the purging cycles under dead-ended operation mode.

Suggested Citation

  • Chen, Ben & Cai, Yonghua & Yu, Yi & Wang, Jun & Tu, Zhengkai & Chan, Siew Hwa, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation II. Under different operation pressures," Energy, Elsevier, vol. 131(C), pages 50-57.
    • Handle: RePEc:eee:energy:v:131:y:2017:i:c:p:50-57
    DOI: 10.1016/j.energy.2017.05.035
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    Cited by:

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    5. Chen, Ben & Cai, Yonghua & Tu, Zhengkai & Chan, Siew Hwa & Wang, Jun & Yu, Yi, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With different electrolytes," Energy, Elsevier, vol. 141(C), pages 40-49.
    6. Zhang, Yuqi & Li, Yu & Zhang, Caizhi & Yang, Yunzi & Yu, Xingzi & Niu, Tong & Wang, Lei & Wang, Gucheng, 2024. "Intelligent diagnosis of proton exchange membrane fuel cell water states based on flooding-specificity experiment and deep learning method," Renewable Energy, Elsevier, vol. 222(C).
    7. Chen, Ben & Zhou, Haoran & He, Shaowen & Meng, Kai & Liu, Yang & Cai, Yonghua, 2021. "Numerical simulation on purge strategy of proton exchange membrane fuel cell with dead-ended anode," Energy, Elsevier, vol. 234(C).
    8. Steinberger, Michael & Geiling, Johannes & Oechsner, Richard & Frey, Lothar, 2018. "Anode recirculation and purge strategies for PEM fuel cell operation with diluted hydrogen feed gas," Applied Energy, Elsevier, vol. 232(C), pages 572-582.
    9. Chen, Ben & Liu, Qi & Zhang, Cheng & Liu, Yang & Shen, Jun & Tu, Zhengkai, 2022. "Numerical study on water transfer characteristics under joint effect of placement orientation and flow channel size for PEMFC with dead-ended anode," Energy, Elsevier, vol. 254(PB).
    10. Wang, Bowen & Wu, Kangcheng & Xi, Fuqiang & Xuan, Jin & Xie, Xu & Wang, Xiaoyang & Jiao, Kui, 2019. "Numerical analysis of operating conditions effects on PEMFC with anode recirculation," Energy, Elsevier, vol. 173(C), pages 844-856.
    11. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    12. Liu, Zhiyang & Chen, Jian & Liu, Hao & Yan, Chizhou & Hou, Yang & He, Qinggang & Zhang, Jiujun & Hissel, Daniel, 2020. "Anode purge management for hydrogen utilization and stack durability improvement of PEM fuel cell systems," Applied Energy, Elsevier, vol. 275(C).
    13. Meng, Kai & Zhou, Haoran & Chen, Ben & Tu, Zhengkai, 2021. "Dynamic current cycles effect on the degradation characteristic of a H2/O2 proton exchange membrane fuel cell," Energy, Elsevier, vol. 224(C).
    14. Yuan, Xian Ming & Guo, Hang & Liu, Jia Xing & Ye, Fang & Ma, Chong Fang, 2018. "Influence of operation parameters on mode switching from electrolysis cell mode to fuel cell mode in a unitized regenerative fuel cell," Energy, Elsevier, vol. 162(C), pages 1041-1051.
    15. Qiu, Diankai & Peng, Linfa & Liang, Peng & Yi, Peiyun & Lai, Xinmin, 2018. "Mechanical degradation of proton exchange membrane along the MEA frame in proton exchange membrane fuel cells," Energy, Elsevier, vol. 165(PB), pages 210-222.
    16. Chen, Huicui & Liu, Zhao & Ye, Xichen & Yi, Liu & Xu, Sichen & Zhang, Tong, 2022. "Air flow and pressure optimization for air supply in proton exchange membrane fuel cell system," Energy, Elsevier, vol. 238(PC).
    17. Yu, Xianxian & Liu, Yang & Tu, Zhengkai & Chan, Siew Hwa, 2023. "Endplate effect in an open-cathode proton exchange membrane fuel cell stack: Phenomenon and resolution," Renewable Energy, Elsevier, vol. 219(P1).
    18. Yang, Zirong & Du, Qing & Jia, Zhiwei & Yang, Chunguang & Jiao, Kui, 2019. "Effects of operating conditions on water and heat management by a transient multi-dimensional PEMFC system model," Energy, Elsevier, vol. 183(C), pages 462-476.
    19. Chen, Dongfang & Pei, Pucheng & Ren, Peng & Song, Xin & Wang, He & Zhang, Lu & Wang, Mingkai, 2022. "Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 258(C).

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