IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v314y2022ics0306261922004263.html
   My bibliography  Save this article

Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack

Author

Listed:
  • Li, Bing
  • Wan, Kechuang
  • Xie, Meng
  • Chu, Tiankuo
  • Wang, Xiaolei
  • Li, Xiang
  • Yang, Daijun
  • Ming, Pingwen
  • Zhang, Cunman

Abstract

The durability is one of the crucial factors for commercial application in proton exchange membrane fuel cell (PEMFC) stack. In this work, a 3-cells PEMFC stack had been designed and operated over a durability test of 1600 h, the durability degradation mechanism of the PEMFC stack and performance consistency (mainly involving voltage degradation) of the membrane electrode assembly (MEA) had been analyzed in depth. The result showed the voltage degradation rates of the PEMFC stack were 12.2% and 52.2 uV h−1 at 1000 mA cm−2 after a durability test of 1600 h. Performance behaviors of different regions of MEA were different after the durability test. It was proved that the reasons for the performance degradation of the PEMFC stack could be ascribed to the loss and agglomeration of catalyst and structural damage (mainly involving membrane and catalyst layer) of MEA. Moreover, the performance degradation of the PEMFC stack in different stages was caused by different reasons. The early performance degradation for the PEMFC stack was mainly due to the loss and agglomeration of catalyst, and the later performance degradation was mainly caused by structural damage of MEA. This work will be of great potential to promote the development of the PEMFC stack in automotive applications.

Suggested Citation

  • Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
    • Handle: RePEc:eee:appene:v:314:y:2022:i:c:s0306261922004263
    DOI: 10.1016/j.apenergy.2022.119020
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261922004263
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2022.119020?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Liu, Shihua & Chen, Tao & Zhang, Cheng & Xie, Yi, 2020. "Study on the performance of proton exchange membrane fuel cell (PEMFC) with dead-ended anode in gravity environment," Applied Energy, Elsevier, vol. 261(C).
    2. Mu, Yu-Tong & Weber, Adam Z. & Gu, Zhao-Lin & Tao, Wen-Quan, 2019. "Mesoscopic modeling of transport resistances in a polymer-electrolyte fuel-cell catalyst layer: Analysis of hydrogen limiting currents," Applied Energy, Elsevier, vol. 255(C).
    3. Chen, Ben & Ke, Wandi & Luo, Maji & Wang, Jun & Tu, Zhengkai & Pan, Mu & Zhang, Haining & Liu, Xiaowei & Liu, Wei, 2015. "Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization," Energy, Elsevier, vol. 91(C), pages 799-806.
    4. Chu, Tiankuo & Zhang, Ruofan & Wang, Yanbo & Ou, Mingyang & Xie, Meng & Shao, Hangyu & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2021. "Performance degradation and process engineering of the 10 kW proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 219(C).
    5. Sayadi, Parvin & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of hydrogen crossover and proton conductivity of self-humidifying nanocomposite proton exchange membrane based on sulfonated poly (ether ether ketone)," Energy, Elsevier, vol. 94(C), pages 292-303.
    6. Chen, Huicui & Pei, Pucheng & Song, Mancun, 2015. "Lifetime prediction and the economic lifetime of Proton Exchange Membrane fuel cells," Applied Energy, Elsevier, vol. 142(C), pages 154-163.
    7. Chen, Ben & Wang, Jun & Yang, Tianqi & Cai, Yonghua & Zhang, Caizhi & Chan, Siew Hwa & Yu, Yi & Tu, Zhengkai, 2016. "Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode," Energy, Elsevier, vol. 106(C), pages 54-62.
    8. Fu, Ya-Lu & Zhang, Biao & Zhu, Xun & Ye, Ding-Ding & Sui, Pang-Chieh & Djilali, Ned, 2020. "Pore-scale modeling of oxygen transport in the catalyst layer of air-breathing cathode in membraneless microfluidic fuel cells," Applied Energy, Elsevier, vol. 277(C).
    9. He, Pu & Mu, Yu-Tong & Park, Jae Wan & Tao, Wen-Quan, 2020. "Modeling of the effects of cathode catalyst layer design parameters on performance of polymer electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 277(C).
    10. Zhou, Zihan & Qiu, Diankai & Zhai, Shuang & Peng, Linfa & Lai, Xinmin, 2020. "Investigation of the assembly for high-power proton exchange membrane fuel cell stacks through an efficient equivalent model," Applied Energy, Elsevier, vol. 277(C).
    11. Zhang, Ruiyuan & Min, Ting & Chen, Li & Kang, Qinjun & He, Ya-Ling & Tao, Wen-Quan, 2019. "Pore-scale and multiscale study of effects of Pt degradation on reactive transport processes in proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    12. Liu, Zhiyang & Chen, Jian & Liu, Hao & Yan, Chizhou & Hou, Yang & He, Qinggang & Zhang, Jiujun & Hissel, Daniel, 2020. "Anode purge management for hydrogen utilization and stack durability improvement of PEM fuel cell systems," Applied Energy, Elsevier, vol. 275(C).
    13. Pei, Pucheng & Wu, Ziyao & Li, Yuehua & Jia, Xiaoning & Chen, Dongfang & Huang, Shangwei, 2018. "Improved methods to measure hydrogen crossover current in proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 215(C), pages 338-347.
    14. Xia, Lingchao & Ni, Meng & Xu, Qidong & Xu, Haoran & Zheng, Keqing, 2021. "Optimization of catalyst layer thickness for achieving high performance and low cost of high temperature proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 294(C).
    15. Zhong, Di & Lin, Rui & Jiang, Zhenghua & Zhu, Yike & Liu, Dengchen & Cai, Xin & Chen, Liang, 2020. "Low temperature durability and consistency analysis of proton exchange membrane fuel cell stack based on comprehensive characterizations," Applied Energy, Elsevier, vol. 264(C).
    16. Lin, Rui & Zhong, Di & Lan, Shunbo & Guo, Rong & Ma, Yunyang & Cai, Xin, 2021. "Experimental validation for enhancement of PEMFC cold start performance: Based on the optimization of micro porous layer," Applied Energy, Elsevier, vol. 300(C).
    17. Lin, Rui & Zhu, Yike & Ni, Meng & Jiang, Zhenghua & Lou, Diming & Han, Lihang & Zhong, Di, 2019. "Consistency analysis of polymer electrolyte membrane fuel cell stack during cold start," Applied Energy, Elsevier, vol. 241(C), pages 420-432.
    18. Shahgaldi, Samaneh & Ozden, Adnan & Li, Xianguo & Hamdullahpur, Feridun, 2020. "A scaled-up proton exchange membrane fuel cell with enhanced performance and durability," Applied Energy, Elsevier, vol. 268(C).
    19. Wang, Junye, 2017. "System integration, durability and reliability of fuel cells: Challenges and solutions," Applied Energy, Elsevier, vol. 189(C), pages 460-479.
    20. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Guohua & Li, Geliang & Xie, Mulin & Xu, Qiming & Zhang, Geng, 2024. "A probabilistic analysis method based on Noisy-OR gate Bayesian network for hydrogen leakage of proton exchange membrane fuel cell," Reliability Engineering and System Safety, Elsevier, vol. 243(C).
    2. Cabello González, G.M. & Toharias, Baltasar & Iranzo, Alfredo & Suárez, Christian & Rosa, Felipe, 2023. "Voltage distribution analysis and non-uniformity assessment in a 100 cm2 PEM fuel cell stack," Energy, Elsevier, vol. 282(C).
    3. Yang, Yue & Yuan, Songmei & Liu, Jieyuan & Zhang, Zikang & Lu, Tie, 2024. "Effect of catalyst ink particle size on the structure of the catalyst layer and electrical performance in the process of ultrasonic spray manufacturing PEMFCs," Energy, Elsevier, vol. 294(C).
    4. Liu, Yang & Zhao, Junjie & Tu, Zhengkai, 2024. "Detecting performance degradation in a dead-ended hydrogen-oxygen proton exchange membrane fuel cell used for an unmanned underwater vehicle," Renewable Energy, Elsevier, vol. 222(C).
    5. Aihua Tang & Yuanhang Yang & Quanqing Yu & Zhigang Zhang & Lin Yang, 2022. "A Review of Life Prediction Methods for PEMFCs in Electric Vehicles," Sustainability, MDPI, vol. 14(16), pages 1-18, August.
    6. Gong, Zhichao & Wang, Bowen & Xu, Yifan & Ni, Meng & Gao, Qingchen & Hou, Zhongjun & Cai, Jun & Gu, Xin & Yuan, Xinjie & Jiao, Kui, 2022. "Adaptive optimization strategy of air supply for automotive polymer electrolyte membrane fuel cell in life cycle," Applied Energy, Elsevier, vol. 325(C).
    7. Lu, Guolong & Liu, Mingxin & Su, Xunkang & Zheng, Tongxi & Luan, Yang & Fan, Wenxuan & Cui, Hao & Liu, Zhenning, 2024. "Study on counter-flow mass transfer characteristics and performance optimization of commercial large-scale proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 359(C).
    8. Jia, Fei & Tian, Xiaodi & Liu, Fengfeng & Ye, Junjie & Yang, Chengpeng, 2023. "Oxidant starvation under various operating conditions on local and transient performance of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 331(C).
    9. Zenan Shen & Shaoquan Liu & Wei Zhu & Daoyuan Ren & Qiang Xu & Yu Feng, 2024. "A Review on Key Technologies and Developments of Hydrogen Fuel Cell Multi-Rotor Drones," Energies, MDPI, vol. 17(16), pages 1-36, August.
    10. Chen, Dongfang & Wu, Wenlong & Chang, Kuanyu & Li, Yuehua & Pei, Pucheng & Xu, Xiaoming, 2023. "Performance degradation prediction method of PEM fuel cells using bidirectional long short-term memory neural network based on Bayesian optimization," Energy, Elsevier, vol. 285(C).
    11. Dan Wang & Haitao Min & Weiyi Sun & Bin Zeng & Haiwen Wu, 2023. "Durability Study of Frequent Dry–Wet Cycle on Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 16(11), pages 1-10, May.
    12. Lopez-Juarez, M. & Rockstroh, T. & Novella, R. & Vijayagopal, R., 2024. "A methodology to develop multi-physics dynamic fuel cell system models validated with vehicle realistic drive cycle data," Applied Energy, Elsevier, vol. 358(C).
    13. Zhao, Lei & Hong, Jichao & Xie, Jiaping & Jiang, Shangfeng & Wei, Xuezhe & Ming, Pingwen & Dai, Haifeng, 2023. "Investigation of local sensitivity for vehicle-oriented fuel cell stacks based on electrochemical impedance spectroscopy," Energy, Elsevier, vol. 262(PA).
    14. Zerong Huang & Daxing Zhang & Xiangdong Wang & Xiaolong Huang & Chunsheng Wang & Liqing Liao & Yaolin Dong & Xiaoshuang Hou & Yuan Cao & Xinyao Zhou, 2024. "Machine Learning Prediction of Fuel Cell Remaining Life Enhanced by Variational Mode Decomposition and Improved Whale Optimization Algorithm," Mathematics, MDPI, vol. 12(19), pages 1-16, September.
    15. Pei, Houchang & Xiao, Chenguang & Tu, Zhengkai, 2022. "Experimental study on liquid water formation characteristics in a novel transparent proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 321(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Dongfang & Pei, Pucheng & Ren, Peng & Song, Xin & Wang, He & Zhang, Lu & Wang, Mingkai, 2022. "Analytical methods for the effect of anode nitrogen concentration on performance and voltage consistency of proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 258(C).
    2. Wan, Yue & Qiu, Diankai & Yi, Peiyun & Peng, Linfa & Lai, Xinmin, 2022. "Design and optimization of gradient wettability pore structure of adaptive PEM fuel cell cathode catalyst layer," Applied Energy, Elsevier, vol. 312(C).
    3. Zheng Huang & Laisuo Su & Yunjie Yang & Linsong Gao & Xinyu Liu & Heng Huang & Yubai Li & Yongchen Song, 2023. "Three-Dimensional Simulation on the Effects of Different Parameters and Pt Loading on the Long-Term Performance of Proton Exchange Membrane Fuel Cells," Sustainability, MDPI, vol. 15(4), pages 1-22, February.
    4. Pei, Pucheng & Meng, Yining & Chen, Dongfang & Ren, Peng & Wang, Mingkai & Wang, Xizhong, 2023. "Lifetime prediction method of proton exchange membrane fuel cells based on current degradation law," Energy, Elsevier, vol. 265(C).
    5. Chu, Tiankuo & Zhang, Ruofan & Wang, Yanbo & Ou, Mingyang & Xie, Meng & Shao, Hangyu & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2021. "Performance degradation and process engineering of the 10 kW proton exchange membrane fuel cell stack," Energy, Elsevier, vol. 219(C).
    6. Bai, Fan & Quan, Hong-Bing & Yin, Ren-Jie & Zhang, Zhuo & Jin, Shu-Qi & He, Pu & Mu, Yu-Tong & Gong, Xiao-Ming & Tao, Wen-Quan, 2022. "Three-dimensional multi-field digital twin technology for proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 324(C).
    7. Liu, Yang & Tu, Zhengkai & Chan, Siew Hwa, 2023. "Water management and performance enhancement in a proton exchange membrane fuel cell system using optimized gas recirculation devices," Energy, Elsevier, vol. 279(C).
    8. Yang, Liu & Cao, Chenxi & Gan, Quanquan & Pei, Hao & Zhang, Qi & Li, Ping, 2022. "Revealing failure modes and effect of catalyst layer properties for PEM fuel cell cold start using an agglomerate model," Applied Energy, Elsevier, vol. 312(C).
    9. Kang, Zhenye & Wang, Hao & Liu, Yanrong & Mo, Jingke & Wang, Min & Li, Jing & Tian, Xinlong, 2022. "Exploring and understanding the internal voltage losses through catalyst layers in proton exchange membrane water electrolysis devices," Applied Energy, Elsevier, vol. 317(C).
    10. Yuemeng Zhang & Jia Wang & Zhanhui Yao, 2023. "Recent Development of Fuel Cell Core Components and Key Materials: A Review," Energies, MDPI, vol. 16(5), pages 1-23, February.
    11. Song, Ke & Wang, Yimin & Ding, Yuhang & Xu, Hongjie & Mueller-Welt, Philip & Stuermlinger, Tobias & Bause, Katharina & Ehrmann, Christopher & Weinmann, Hannes W. & Schaefer, Jens & Fleischer, Juergen , 2022. "Assembly techniques for proton exchange membrane fuel cell stack: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    12. Lin, Rui & Zhong, Di & Lan, Shunbo & Guo, Rong & Ma, Yunyang & Cai, Xin, 2021. "Experimental validation for enhancement of PEMFC cold start performance: Based on the optimization of micro porous layer," Applied Energy, Elsevier, vol. 300(C).
    13. Wu, Kangcheng & Du, Qing & Zu, Bingfeng & Wang, Yupeng & Cai, Jun & Gu, Xin & Xuan, Jin & Jiao, Kui, 2021. "Enabling real-time optimization of dynamic processes of proton exchange membrane fuel cell: Data-driven approach with semi-recurrent sliding window method," Applied Energy, Elsevier, vol. 303(C).
    14. Yu, Rui Jiao & Guo, Hang & Ye, Fang & Chen, Hao, 2022. "Multi-parameter optimization of stepwise distribution of parameters of gas diffusion layer and catalyst layer for PEMFC peak power density," Applied Energy, Elsevier, vol. 324(C).
    15. Ren, Peng & Pei, Pucheng & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Zhang, Lu & Li, Zizhao & Wang, Mingkai & Wang, He & Wang, Bozheng & Wang, Xizhong, 2022. "Novel analytic method of membrane electrode assembly parameters for fuel cell consistency evaluation by micro-current excitation," Applied Energy, Elsevier, vol. 306(PB).
    16. Song, Yajie & Wang, Xinli & Wang, Lei & Pan, Fengwen & Chen, Wenmiao & Xi, Fuqiang, 2021. "A twin-nozzle ejector for hydrogen recirculation in wide power operation of polymer electrolyte membrane fuel cell system," Applied Energy, Elsevier, vol. 300(C).
    17. Zhang, Tong & Wang, Peiqi & Chen, Huicui & Pei, Pucheng, 2018. "A review of automotive proton exchange membrane fuel cell degradation under start-stop operating condition," Applied Energy, Elsevier, vol. 223(C), pages 249-262.
    18. Saeidfar, Asal & Yesilyurt, Serhat, 2023. "Numerical investigation of the effects of catalyst layer composition and channel to rib width ratios for low platinum loaded PEMFCs," Applied Energy, Elsevier, vol. 339(C).
    19. Chen, Ben & Cai, Yonghua & Tu, Zhengkai & Chan, Siew Hwa & Wang, Jun & Yu, Yi, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With different electrolytes," Energy, Elsevier, vol. 141(C), pages 40-49.
    20. Ahmad Baroutaji & Arun Arjunan & John Robinson & Tabbi Wilberforce & Mohammad Ali Abdelkareem & Abdul Ghani Olabi, 2021. "PEMFC Poly-Generation Systems: Developments, Merits, and Challenges," Sustainability, MDPI, vol. 13(21), pages 1-31, October.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:314:y:2022:i:c:s0306261922004263. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.