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Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack

Author

Listed:
  • Li, Bing
  • Wan, Kechuang
  • Xie, Meng
  • Chu, Tiankuo
  • Wang, Xiaolei
  • Li, Xiang
  • Yang, Daijun
  • Ming, Pingwen
  • Zhang, Cunman

Abstract

The durability is one of the crucial factors for commercial application in proton exchange membrane fuel cell (PEMFC) stack. In this work, a 3-cells PEMFC stack had been designed and operated over a durability test of 1600 h, the durability degradation mechanism of the PEMFC stack and performance consistency (mainly involving voltage degradation) of the membrane electrode assembly (MEA) had been analyzed in depth. The result showed the voltage degradation rates of the PEMFC stack were 12.2% and 52.2 uV h−1 at 1000 mA cm−2 after a durability test of 1600 h. Performance behaviors of different regions of MEA were different after the durability test. It was proved that the reasons for the performance degradation of the PEMFC stack could be ascribed to the loss and agglomeration of catalyst and structural damage (mainly involving membrane and catalyst layer) of MEA. Moreover, the performance degradation of the PEMFC stack in different stages was caused by different reasons. The early performance degradation for the PEMFC stack was mainly due to the loss and agglomeration of catalyst, and the later performance degradation was mainly caused by structural damage of MEA. This work will be of great potential to promote the development of the PEMFC stack in automotive applications.

Suggested Citation

  • Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
    • Handle: RePEc:eee:appene:v:314:y:2022:i:c:s0306261922004263
    DOI: 10.1016/j.apenergy.2022.119020
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    2. Zenan Shen & Shaoquan Liu & Wei Zhu & Daoyuan Ren & Qiang Xu & Yu Feng, 2024. "A Review on Key Technologies and Developments of Hydrogen Fuel Cell Multi-Rotor Drones," Energies, MDPI, vol. 17(16), pages 1-36, August.
    3. Chen, Dongfang & Wu, Wenlong & Chang, Kuanyu & Li, Yuehua & Pei, Pucheng & Xu, Xiaoming, 2023. "Performance degradation prediction method of PEM fuel cells using bidirectional long short-term memory neural network based on Bayesian optimization," Energy, Elsevier, vol. 285(C).
    4. Chen, Guohua & Li, Geliang & Xie, Mulin & Xu, Qiming & Zhang, Geng, 2024. "A probabilistic analysis method based on Noisy-OR gate Bayesian network for hydrogen leakage of proton exchange membrane fuel cell," Reliability Engineering and System Safety, Elsevier, vol. 243(C).
    5. Dan Wang & Haitao Min & Weiyi Sun & Bin Zeng & Haiwen Wu, 2023. "Durability Study of Frequent Dry–Wet Cycle on Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 16(11), pages 1-10, May.
    6. Cabello González, G.M. & Toharias, Baltasar & Iranzo, Alfredo & Suárez, Christian & Rosa, Felipe, 2023. "Voltage distribution analysis and non-uniformity assessment in a 100 cm2 PEM fuel cell stack," Energy, Elsevier, vol. 282(C).
    7. Lopez-Juarez, M. & Rockstroh, T. & Novella, R. & Vijayagopal, R., 2024. "A methodology to develop multi-physics dynamic fuel cell system models validated with vehicle realistic drive cycle data," Applied Energy, Elsevier, vol. 358(C).
    8. Zhao, Lei & Hong, Jichao & Xie, Jiaping & Jiang, Shangfeng & Wei, Xuezhe & Ming, Pingwen & Dai, Haifeng, 2023. "Investigation of local sensitivity for vehicle-oriented fuel cell stacks based on electrochemical impedance spectroscopy," Energy, Elsevier, vol. 262(PA).
    9. Pei, Houchang & Xiao, Chenguang & Tu, Zhengkai, 2022. "Experimental study on liquid water formation characteristics in a novel transparent proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 321(C).
    10. Yang, Yue & Yuan, Songmei & Liu, Jieyuan & Zhang, Zikang & Lu, Tie, 2024. "Effect of catalyst ink particle size on the structure of the catalyst layer and electrical performance in the process of ultrasonic spray manufacturing PEMFCs," Energy, Elsevier, vol. 294(C).
    11. Liu, Yang & Zhao, Junjie & Tu, Zhengkai, 2024. "Detecting performance degradation in a dead-ended hydrogen-oxygen proton exchange membrane fuel cell used for an unmanned underwater vehicle," Renewable Energy, Elsevier, vol. 222(C).
    12. Aihua Tang & Yuanhang Yang & Quanqing Yu & Zhigang Zhang & Lin Yang, 2022. "A Review of Life Prediction Methods for PEMFCs in Electric Vehicles," Sustainability, MDPI, vol. 14(16), pages 1-18, August.
    13. Gong, Zhichao & Wang, Bowen & Xu, Yifan & Ni, Meng & Gao, Qingchen & Hou, Zhongjun & Cai, Jun & Gu, Xin & Yuan, Xinjie & Jiao, Kui, 2022. "Adaptive optimization strategy of air supply for automotive polymer electrolyte membrane fuel cell in life cycle," Applied Energy, Elsevier, vol. 325(C).
    14. Lu, Guolong & Liu, Mingxin & Su, Xunkang & Zheng, Tongxi & Luan, Yang & Fan, Wenxuan & Cui, Hao & Liu, Zhenning, 2024. "Study on counter-flow mass transfer characteristics and performance optimization of commercial large-scale proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 359(C).

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