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Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect

Author

Listed:
  • Lei, Gang
  • Zheng, Hualin
  • Zhang, Jun
  • Siong Chin, Cheng
  • Xu, Xinhai
  • Zhou, Weijiang
  • Zhang, Caizhi

Abstract

High-temperature proton exchange membrane fuel cells (HT-PEMFC) have strong resistance to CO poisoning. However, the published CO poisoning models for HT-PEMFC are based on the finite element analysis method, which are difficult to use for the performance prediction and development of system control strategies due to a large amount of calculation. In the beginning, a semi-empirical model of HT-PEMFC is deduced based on the analysis of the CO poisoning characteristics. Then the key parameters of ohmic impedance and concentration polarization advance correction factor are obtained by fitting the polarization curves, dissociation and adsorption activation energy of H2 and CO are obtained by the calculation, respectively. The slope of the straight line segment in the ohmic polarization interval of the polarization curve is linearly related to ln[H2/CO]. The change of limiting current density is the main factor for the advance of concentration polarization. The fitted ohmic impedance varies with temperature and CO concentration, but changes little above 175 °C. CO coverage depends primarily on dissociation and adsorption activation energy of CO. Subsequently, the proposed model is validated with experimental data and shows high similarity. The model can be used for studying the systematic control strategy development and performance monitoring of HT-PEMFC.

Suggested Citation

  • Lei, Gang & Zheng, Hualin & Zhang, Jun & Siong Chin, Cheng & Xu, Xinhai & Zhou, Weijiang & Zhang, Caizhi, 2023. "Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect," Energy, Elsevier, vol. 282(C).
  • Handle: RePEc:eee:energy:v:282:y:2023:i:c:s0360544223016997
    DOI: 10.1016/j.energy.2023.128305
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    as
    1. Bornapour, Mosayeb & Hooshmand, Rahmat-Allah & Parastegari, Moein, 2019. "An efficient scenario-based stochastic programming method for optimal scheduling of CHP-PEMFC, WT, PV and hydrogen storage units in micro grids," Renewable Energy, Elsevier, vol. 130(C), pages 1049-1066.
    2. Guo, Xinru & Zhang, Houcheng & Wang, Jiatang & Zhao, Jiapei & Wang, Fu & Miao, He & Yuan, Jinliang & Hou, Shujin, 2020. "A new hybrid system composed of high-temperature proton exchange fuel cell and two-stage thermoelectric generator with Thomson effect: Energy and exergy analyses," Energy, Elsevier, vol. 195(C).
    3. Wang, Hsueh-Sheng & Chang, Cheng-Ping & Huang, Yuh-Jeen & Su, Yu-Chuan & Tseng, Fan-Gang, 2017. "A high-yield and ultra-low-temperature methanol reformer integratable with phosphoric acid fuel cell (PAFC)," Energy, Elsevier, vol. 133(C), pages 1142-1152.
    4. Lopes, Daniel G. & da Silva, E.P. & Pinto, C.S. & Neves, N.P. & Camargo, J.C. & Ferreira, P.F.P. & Furlan, A.L. & Lopes, Davi G., 2012. "Technical and economic analysis of a power supply system based on ethanol reforming and PEMFC," Renewable Energy, Elsevier, vol. 45(C), pages 205-212.
    5. Steinberger, Michael & Geiling, Johannes & Oechsner, Richard & Frey, Lothar, 2018. "Anode recirculation and purge strategies for PEM fuel cell operation with diluted hydrogen feed gas," Applied Energy, Elsevier, vol. 232(C), pages 572-582.
    6. Inamuddin, & Cheema, Taqi Ahmad & Zaidi, S.M.J. & Rahman, S.U., 2011. "Three dimensional numerical investigations for the effects of gas diffusion layer on PEM fuel cell performance," Renewable Energy, Elsevier, vol. 36(2), pages 529-535.
    7. Cai, Wei & Mohammaditab, Rasoul & Fathi, Gholamreza & Wakil, Karzan & Ebadi, Abdol Ghaffar & Ghadimi, Noradin, 2019. "Optimal bidding and offering strategies of compressed air energy storage: A hybrid robust-stochastic approach," Renewable Energy, Elsevier, vol. 143(C), pages 1-8.
    8. Chen, Ben & Zhou, Haoran & He, Shaowen & Meng, Kai & Liu, Yang & Cai, Yonghua, 2021. "Numerical simulation on purge strategy of proton exchange membrane fuel cell with dead-ended anode," Energy, Elsevier, vol. 234(C).
    9. Cheng, Shan-Jen & Miao, Jr-Ming & Wu, Sheng-Ju, 2012. "Investigating the effects of operational factors on PEMFC performance based on CFD simulations using a three-level full-factorial design," Renewable Energy, Elsevier, vol. 39(1), pages 250-260.
    10. Chen, Ben & Ke, Wandi & Luo, Maji & Wang, Jun & Tu, Zhengkai & Pan, Mu & Zhang, Haining & Liu, Xiaowei & Liu, Wei, 2015. "Operation characteristics and carbon corrosion of PEMFC (Proton exchange membrane fuel cell) with dead-ended anode for high hydrogen utilization," Energy, Elsevier, vol. 91(C), pages 799-806.
    11. Perna, Alessandra & Minutillo, Mariagiovanna & Jannelli, Elio, 2015. "Investigations on an advanced power system based on a high temperature polymer electrolyte membrane fuel cell and an organic Rankine cycle for heating and power production," Energy, Elsevier, vol. 88(C), pages 874-884.
    12. Wu, Zhen & Zhu, Pengfei & Yao, Jing & Tan, Peng & Xu, Haoran & Chen, Bin & Yang, Fusheng & Zhang, Zaoxiao & Ni, Meng, 2020. "Thermo-economic modeling and analysis of an NG-fueled SOFC-WGS-TSA-PEMFC hybrid energy conversion system for stationary electricity power generation," Energy, Elsevier, vol. 192(C).
    13. Authayanun, Suthida & Saebea, Dang & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai, 2014. "Effect of different fuel options on performance of high-temperature PEMFC (proton exchange membrane fuel cell) systems," Energy, Elsevier, vol. 68(C), pages 989-997.
    14. Lu, Xiaohui & Li, Bing & Guo, Lin & Wang, Peifang & Yousefi, Nasser, 2021. "Exergy analysis of a polymer fuel cell and identification of its optimum operating conditions using improved Farmland Fertility Optimization," Energy, Elsevier, vol. 216(C).
    15. Wu, Zhen & Tan, Peng & Chen, Bin & Cai, Weizi & Chen, Meina & Xu, Xiaoming & Zhang, Zaoxiao & Ni, Meng, 2019. "Dynamic modeling and operation strategy of an NG-fueled SOFC-WGS-TSA-PEMFC hybrid energy conversion system for fuel cell vehicle by using MATLAB/SIMULINK," Energy, Elsevier, vol. 175(C), pages 567-579.
    16. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    17. Liu, Zhiyang & Chen, Jian & Liu, Hao & Yan, Chizhou & Hou, Yang & He, Qinggang & Zhang, Jiujun & Hissel, Daniel, 2020. "Anode purge management for hydrogen utilization and stack durability improvement of PEM fuel cell systems," Applied Energy, Elsevier, vol. 275(C).
    18. Ismail, A. & Kamarudin, S.K. & Daud, W.R.W. & Masdar, S. & Hasran, U.A., 2018. "Development of 2D multiphase non-isothermal mass transfer model for DMFC system," Energy, Elsevier, vol. 152(C), pages 263-276.
    19. Zeng, Tao & Zhang, Caizhi & Hao, Dong & Cao, Dongpu & Chen, Jiawei & Chen, Jinrui & Li, Jin, 2020. "Data-driven approach for short-term power demand prediction of fuel cell hybrid vehicles," Energy, Elsevier, vol. 208(C).
    20. Ong, Samuel & Al-Othman, Amani & Tawalbeh, Muhammad, 2023. "Emerging technologies in prognostics for fuel cells including direct hydrocarbon fuel cells," Energy, Elsevier, vol. 277(C).
    21. Blal, Mohamed & Benatiallah, Ali & NeÇaibia, Ammar & Lachtar, Salah & Sahouane, Nordine & Belasri, Ahmed, 2019. "Contribution and investigation to compare models parameters of (PEMFC), comprehensives review of fuel cell models and their degradation," Energy, Elsevier, vol. 168(C), pages 182-199.
    22. Deng, Bo & Huang, Wentao & Jian, Qifei, 2023. "An open-cathode PEMFC efficiency optimization strategy based on exergy analysis and data-driven modeling," Energy, Elsevier, vol. 264(C).
    23. Ribeirinha, P. & Abdollahzadeh, M. & Sousa, J.M. & Boaventura, M. & Mendes, A., 2017. "Modelling of a high-temperature polymer electrolyte membrane fuel cell integrated with a methanol steam reformer cell," Applied Energy, Elsevier, vol. 202(C), pages 6-19.
    24. Ryu, Sung Kwan & Vinothkannan, Mohanraj & Kim, Ae Rhan & Yoo, Dong Jin, 2022. "Effect of type and stoichiometry of fuels on performance of polybenzimidazole-based proton exchange membrane fuel cells operating at the temperature range of 120–160 °C," Energy, Elsevier, vol. 238(PB).
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    More about this item

    Keywords

    High temperature proton exchange membrane fuel cell (HT-PEMFC); CO poisoning; Equivalent resistance; Limiting current density; H2 and CO coverage;
    All these keywords.

    JEL classification:

    • H2 - Public Economics - - Taxation, Subsidies, and Revenue

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