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Analyzing and modeling of CO purging for high-temperature proton exchange membrane fuel cells

Author

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  • Lei, Gang
  • Zheng, Hualin
  • Zhang, Caizhi
  • Chen, Huicui
  • Chin, Cheng Siong
  • Xu, Xinhai

Abstract

Purging offers a straightforward and cost-effective means of eliminating inert gases that accumulate in high-temperature proton exchange membrane fuel cells (HT-PEMFC) operating in dead-end anode (DEA) mode. Nevertheless, earlier studies primarily concentrated on inert gases, overlooking the significant challenge posed by the strong adsorption of CO within HT-PEMFC, complicating the use of inert gas methods for CO purification. This paper presents an analytical model that was validated experimentally. Leveraging this model, the paper analyzes the crucial parameter of CO concentration within the anode and deduces theoretical extreme values. Subsequently, it proposes purging strategies tailored to different operational conditions. The findings indicate that the minimum CO concentration within HT-PEMFC is influenced by current, feed gas flow rate, and feed gas CO concentration. Additionally, the maximum CO concentration is affected by the off-duration of the purge valve in addition to these factors. Specifically, under the operating condition of 473.15 K, adopting a CO concentration threshold purge strategy is recommended, whereas under the operating condition of 448.15 K, voltage drop and CO concentration threshold purge strategies should be respectively implemented above and below the cutoff line based on the current. This research contributes to mitigating the issue of CO accumulation in DEA mode.

Suggested Citation

  • Lei, Gang & Zheng, Hualin & Zhang, Caizhi & Chen, Huicui & Chin, Cheng Siong & Xu, Xinhai, 2024. "Analyzing and modeling of CO purging for high-temperature proton exchange membrane fuel cells," Energy, Elsevier, vol. 302(C).
  • Handle: RePEc:eee:energy:v:302:y:2024:i:c:s0360544224016517
    DOI: 10.1016/j.energy.2024.131878
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    References listed on IDEAS

    as
    1. Zhang, Xiaofeng & Liu, Wenjing & Pan, Jinjun & Zhao, Bin & Yi, Zhengyuan & He, Xu & Liu, Yuting & Li, Hongqiang, 2024. "Comprehensive performance assessment of a novel biomass-based CCHP system integrated with SOFC and HT-PEMFC," Energy, Elsevier, vol. 295(C).
    2. Steinberger, Michael & Geiling, Johannes & Oechsner, Richard & Frey, Lothar, 2018. "Anode recirculation and purge strategies for PEM fuel cell operation with diluted hydrogen feed gas," Applied Energy, Elsevier, vol. 232(C), pages 572-582.
    3. Lei, Gang & Zheng, Hualin & Zhang, Jun & Siong Chin, Cheng & Xu, Xinhai & Zhou, Weijiang & Zhang, Caizhi, 2023. "Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect," Energy, Elsevier, vol. 282(C).
    4. Lu, Xiaohui & Li, Bing & Guo, Lin & Wang, Peifang & Yousefi, Nasser, 2021. "Exergy analysis of a polymer fuel cell and identification of its optimum operating conditions using improved Farmland Fertility Optimization," Energy, Elsevier, vol. 216(C).
    5. Huang, Weifeng & Niu, Tong & Zhang, Caizhi & Fu, Zuhang & Zhang, Yuqi & Zhou, Weijiang & Pan, Zehua & Zhang, Kaiqing, 2023. "Experimental study of the performance degradation of proton exchange membrane fuel cell based on a multi-module stack under selected load profiles by clustering algorithm," Energy, Elsevier, vol. 270(C).
    6. Bornapour, Mosayeb & Hooshmand, Rahmat-Allah & Parastegari, Moein, 2019. "An efficient scenario-based stochastic programming method for optimal scheduling of CHP-PEMFC, WT, PV and hydrogen storage units in micro grids," Renewable Energy, Elsevier, vol. 130(C), pages 1049-1066.
    7. Guo, Xinru & Zhang, Houcheng & Wang, Jiatang & Zhao, Jiapei & Wang, Fu & Miao, He & Yuan, Jinliang & Hou, Shujin, 2020. "A new hybrid system composed of high-temperature proton exchange fuel cell and two-stage thermoelectric generator with Thomson effect: Energy and exergy analyses," Energy, Elsevier, vol. 195(C).
    8. Lopes, Daniel G. & da Silva, E.P. & Pinto, C.S. & Neves, N.P. & Camargo, J.C. & Ferreira, P.F.P. & Furlan, A.L. & Lopes, Davi G., 2012. "Technical and economic analysis of a power supply system based on ethanol reforming and PEMFC," Renewable Energy, Elsevier, vol. 45(C), pages 205-212.
    9. Zhao, Lei & Hong, Jichao & Xie, Jiaping & Jiang, Shangfeng & Wei, Xuezhe & Ming, Pingwen & Dai, Haifeng, 2023. "Investigation of local sensitivity for vehicle-oriented fuel cell stacks based on electrochemical impedance spectroscopy," Energy, Elsevier, vol. 262(PA).
    10. Ismail, A. & Kamarudin, S.K. & Daud, W.R.W. & Masdar, S. & Hasran, U.A., 2018. "Development of 2D multiphase non-isothermal mass transfer model for DMFC system," Energy, Elsevier, vol. 152(C), pages 263-276.
    11. Zhang, Jun & Zhang, Caizhi & Li, Jin & Deng, Bo & Fan, Min & Ni, Meng & Mao, Zhanxin & Yuan, Honggeng, 2021. "Multi-perspective analysis of CO poisoning in high-temperature proton exchange membrane fuel cell stack via numerical investigation," Renewable Energy, Elsevier, vol. 180(C), pages 313-328.
    12. Zhang, Qinguo & Tong, Zheming & Tong, Shuiguang & Cheng, Zhewu, 2021. "Modeling and dynamic performance research on proton exchange membrane fuel cell system with hydrogen cycle and dead-ended anode," Energy, Elsevier, vol. 218(C).
    13. Guo, Xinru & Zhang, Houcheng, 2020. "Performance analyses of a combined system consisting of high-temperature polymer electrolyte membrane fuel cells and thermally regenerative electrochemical cycles," Energy, Elsevier, vol. 193(C).
    14. Chen, Zhijie & Zuo, Wei & Zhou, Kun & Li, Qingqing & Huang, Yuhan & E, Jiaqiang, 2023. "Multi-factor impact mechanism on the performance of high temperature proton exchange membrane fuel cell," Energy, Elsevier, vol. 278(PB).
    15. Boqi Xiao & Qiwen Huang & Hanxin Chen & Xubing Chen & Gongbo Long, 2021. "A Fractal Model For Capillary Flow Through A Single Tortuous Capillary With Roughened Surfaces In Fibrous Porous Media," FRACTALS (fractals), World Scientific Publishing Co. Pte. Ltd., vol. 29(01), pages 1-10, February.
    16. Chen, Ben & Zhou, Haoran & He, Shaowen & Meng, Kai & Liu, Yang & Cai, Yonghua, 2021. "Numerical simulation on purge strategy of proton exchange membrane fuel cell with dead-ended anode," Energy, Elsevier, vol. 234(C).
    17. Sun, Li & Shen, Jiong & Hua, Qingsong & Lee, Kwang Y., 2018. "Data-driven oxygen excess ratio control for proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 231(C), pages 866-875.
    18. Wu, Zhen & Tan, Peng & Chen, Bin & Cai, Weizi & Chen, Meina & Xu, Xiaoming & Zhang, Zaoxiao & Ni, Meng, 2019. "Dynamic modeling and operation strategy of an NG-fueled SOFC-WGS-TSA-PEMFC hybrid energy conversion system for fuel cell vehicle by using MATLAB/SIMULINK," Energy, Elsevier, vol. 175(C), pages 567-579.
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