IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v152y2018icp939-959.html
   My bibliography  Save this article

Three-dimensional modeling of PEMFC with contaminated anode fuel

Author

Listed:
  • Abdollahzadeh, M.
  • Ribeirinha, P.
  • Boaventura, M.
  • Mendes, A.

Abstract

A novel transient multi-dimensional non-isothermal multiphase model for simulating PEMFC was developed. A multiphase agglomerate catalyst model was considered for the cathode catalyst layer, while in the anode catalyst layer the effect of CO and CO2 presence was taken into consideration assuming two families of catalysts, Pt/C and Pt-Ru. The model predictions were compared to experimental data found in the literature and from an in-house PEMFC. The model was able to capture accurately the steady polarization curves of PEMFCs fed with hydrogen containing different amounts of CO and CO2. Moreover, the corresponding transient voltage was accurately simulated. The results indicated that even low CO concentration in the anode fuel, leads to a considerable degradation of the fuel cell output current density. Among the tested gas diffusion layers, the ones with the highest thickness showed worst performance of the PEMFC. Results showed, that high tortuosity and low contact angle (hydrophobicity) of the gas diffusion layer, decreases the performance of the PEMFC.

Suggested Citation

  • Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    • Handle: RePEc:eee:energy:v:152:y:2018:i:c:p:939-959
    DOI: 10.1016/j.energy.2018.03.162
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218305711
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.03.162?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    2. Siegel, C., 2008. "Review of computational heat and mass transfer modeling in polymer-electrolyte-membrane (PEM) fuel cells," Energy, Elsevier, vol. 33(9), pages 1331-1352.
    3. Chen, Ben & Wang, Jun & Yang, Tianqi & Cai, Yonghua & Zhang, Caizhi & Chan, Siew Hwa & Yu, Yi & Tu, Zhengkai, 2016. "Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode," Energy, Elsevier, vol. 106(C), pages 54-62.
    4. Abdollahzadeh, M. & Pascoa, J.C. & Ranjbar, A.A. & Esmaili, Q., 2014. "Analysis of PEM (Polymer Electrolyte Membrane) fuel cell cathode two-dimensional modeling," Energy, Elsevier, vol. 68(C), pages 478-494.
    5. Huang, Yu-Xian & Cheng, Chin-Hsiang & Wang, Xiao-Dong & Jang, Jiin-Yuh, 2010. "Effects of porosity gradient in gas diffusion layers on performance of proton exchange membrane fuel cells," Energy, Elsevier, vol. 35(12), pages 4786-4794.
    6. Ribeirinha, P. & Abdollahzadeh, M. & Pereira, A. & Relvas, F. & Boaventura, M. & Mendes, A., 2018. "High temperature PEM fuel cell integrated with a cellular membrane methanol steam reformer: Experimental and modelling," Applied Energy, Elsevier, vol. 215(C), pages 659-669.
    7. Liu, Jia Xing & Guo, Hang & Ye, Fang & Ma, Chong Fang, 2017. "Two-dimensional analytical model of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 119(C), pages 299-308.
    8. Ribeirinha, P. & Alves, I. & Vázquez, F. Vidal & Schuller, G. & Boaventura, M. & Mendes, A., 2017. "Heat integration of methanol steam reformer with a high-temperature polymeric electrolyte membrane fuel cell," Energy, Elsevier, vol. 120(C), pages 468-477.
    9. Hong, Po & Xu, Liangfei & Li, Jianqiu & Ouyang, Minggao, 2017. "Modeling of membrane electrode assembly of PEM fuel cell to analyze voltage losses inside," Energy, Elsevier, vol. 139(C), pages 277-288.
    10. Xing, Lei & Liu, Xiaoteng & Alaje, Taiwo & Kumar, Ravi & Mamlouk, Mohamed & Scott, Keith, 2014. "A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell," Energy, Elsevier, vol. 73(C), pages 618-634.
    11. Carton, J.G. & Olabi, A.G., 2017. "Three-dimensional proton exchange membrane fuel cell model: Comparison of double channel and open pore cellular foam flow plates," Energy, Elsevier, vol. 136(C), pages 185-195.
    12. Carton, J.G. & Lawlor, V. & Olabi, A.G. & Hochenauer, C. & Zauner, G., 2012. "Water droplet accumulation and motion in PEM (Proton Exchange Membrane) fuel cell mini-channels," Energy, Elsevier, vol. 39(1), pages 63-73.
    13. Barelli, L. & Bidini, G. & Gallorini, F. & Servili, S., 2008. "Hydrogen production through sorption-enhanced steam methane reforming and membrane technology: A review," Energy, Elsevier, vol. 33(4), pages 554-570.
    14. Djilali, N., 2007. "Computational modelling of polymer electrolyte membrane (PEM) fuel cells: Challenges and opportunities," Energy, Elsevier, vol. 32(4), pages 269-280.
    15. Díaz, Manuel Antonio & Iranzo, Alfredo & Rosa, Felipe & Isorna, Fernando & López, Eduardo & Bolivar, Juan Pedro, 2015. "Effect of carbon dioxide on the contamination of low temperature and high temperature PEM (polymer electrolyte membrane) fuel cells. Influence of temperature, relative humidity and analysis of regener," Energy, Elsevier, vol. 90(P1), pages 299-309.
    16. Xing, Lei & Das, Prodip K. & Song, Xueguan & Mamlouk, Mohamed & Scott, Keith, 2015. "Numerical analysis of the optimum membrane/ionomer water content of PEMFCs: The interaction of Nafion® ionomer content and cathode relative humidity," Applied Energy, Elsevier, vol. 138(C), pages 242-257.
    17. Ramiar, A. & Mahmoudi, A.H. & Esmaili, Q. & Abdollahzadeh, M., 2016. "Influence of cathode flow pulsation on performance of proton exchange membrane fuel cell with interdigitated gas distributors," Energy, Elsevier, vol. 94(C), pages 206-217.
    18. Xing, Lei & Cai, Qiong & Xu, Chenxi & Liu, Chunbo & Scott, Keith & Yan, Yongsheng, 2016. "Numerical study of the effect of relative humidity and stoichiometric flow ratio on PEM (proton exchange membrane) fuel cell performance with various channel lengths: An anode partial flooding modelli," Energy, Elsevier, vol. 106(C), pages 631-645.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Jun & Zhang, Caizhi & Li, Jin & Deng, Bo & Fan, Min & Ni, Meng & Mao, Zhanxin & Yuan, Honggeng, 2021. "Multi-perspective analysis of CO poisoning in high-temperature proton exchange membrane fuel cell stack via numerical investigation," Renewable Energy, Elsevier, vol. 180(C), pages 313-328.
    2. Yin, Cong & Gao, Yan & Li, Ting & Xie, Guangyou & Li, Kai & Tang, Hao, 2020. "Study of internal multi-parameter distributions of proton exchange membrane fuel cell with segmented cell device and coupled three-dimensional model," Renewable Energy, Elsevier, vol. 147(P1), pages 650-662.
    3. Rezk, Hegazy & Olabi, A.G. & Ferahtia, Seydali & Sayed, Enas Taha, 2022. "Accurate parameter estimation methodology applied to model proton exchange membrane fuel cell," Energy, Elsevier, vol. 255(C).
    4. Wang, Ya-Xiong & Chen, Quan & Zhang, Jin & He, Hongwen, 2021. "Real-time power optimization for an air-coolant proton exchange membrane fuel cell based on active temperature control," Energy, Elsevier, vol. 220(C).
    5. Somayeh Toghyani & Seyed Ali Atyabi & Xin Gao, 2021. "Enhancing the Specific Power of a PEM Fuel Cell Powered UAV with a Novel Bean-Shaped Flow Field," Energies, MDPI, vol. 14(9), pages 1-23, April.
    6. Lei, Gang & Zheng, Hualin & Zhang, Jun & Siong Chin, Cheng & Xu, Xinhai & Zhou, Weijiang & Zhang, Caizhi, 2023. "Analyzing characteristic and modeling of high-temperature proton exchange membrane fuel cells with CO poisoning effect," Energy, Elsevier, vol. 282(C).
    7. Asensio, F.J. & San Martín, J.I. & Zamora, I. & Saldaña, G. & Oñederra, O., 2019. "Analysis of electrochemical and thermal models and modeling techniques for polymer electrolyte membrane fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    8. Zhang, Weixin & Yi, Peiyun & Peng, Linfa & Lai, Xinmin, 2018. "Strategy of alternating bias voltage on corrosion resistance and interfacial conductivity enhancement of TiCx/a-C coatings on metallic bipolar plates in PEMFCs," Energy, Elsevier, vol. 162(C), pages 933-943.
    9. Zhu, Jingyu & Tan, Jinzhu & Pan, Qing & Liu, Zenghui & Hou, Qiong, 2019. "Effects of Mg2+ contamination on the performance of proton exchange membrane fuel cell," Energy, Elsevier, vol. 189(C).
    10. Lu Zhang & Yongfeng Liu & Pucheng Pei & Xintong Liu & Long Wang & Yuan Wan, 2022. "Variation Characteristic Analysis of Water Content at the Flow Channel of Proton Exchange Membrane Fuel Cell," Energies, MDPI, vol. 15(9), pages 1-20, April.
    11. Cai, Yonghua & Wu, Di & Sun, Jingming & Chen, Ben, 2021. "The effect of cathode channel blockages on the enhanced mass transfer and performance of PEMFC," Energy, Elsevier, vol. 222(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chowdhury, Mohammad Ziauddin & Timurkutluk, Bora, 2018. "Transport phenomena of convergent and divergent serpentine flow fields for PEMFC," Energy, Elsevier, vol. 161(C), pages 104-117.
    2. Xu, Liangfei & Fang, Chuan & Hu, Junming & Cheng, Siliang & Li, Jianqiu & Ouyang, Minggao & Lehnert, Werner, 2017. "Parameter extraction of polymer electrolyte membrane fuel cell based on quasi-dynamic model and periphery signals," Energy, Elsevier, vol. 122(C), pages 675-690.
    3. Hu, Junming & Li, Jianqiu & Xu, Liangfei & Huang, Fusen & Ouyang, Minggao, 2016. "Analytical calculation and evaluation of water transport through a proton exchange membrane fuel cell based on a one-dimensional model," Energy, Elsevier, vol. 111(C), pages 869-883.
    4. Yin, Cong & Gao, Jianlong & Wen, Xuhui & Xie, Guangyou & Yang, Chunhua & Fang, Honglin & Tang, Hao, 2016. "In situ investigation of proton exchange membrane fuel cell performance with novel segmented cell design and a two-phase flow model," Energy, Elsevier, vol. 113(C), pages 1071-1089.
    5. Xing, Lei & Cai, Qiong & Xu, Chenxi & Liu, Chunbo & Scott, Keith & Yan, Yongsheng, 2016. "Numerical study of the effect of relative humidity and stoichiometric flow ratio on PEM (proton exchange membrane) fuel cell performance with various channel lengths: An anode partial flooding modelli," Energy, Elsevier, vol. 106(C), pages 631-645.
    6. Afshari, E. & Mosharaf-Dehkordi, M. & Rajabian, H., 2017. "An investigation of the PEM fuel cells performance with partially restricted cathode flow channels and metal foam as a flow distributor," Energy, Elsevier, vol. 118(C), pages 705-715.
    7. Xing, Lei & Liu, Xiaoteng & Alaje, Taiwo & Kumar, Ravi & Mamlouk, Mohamed & Scott, Keith, 2014. "A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell," Energy, Elsevier, vol. 73(C), pages 618-634.
    8. Abdin, Z. & Webb, C.J. & Gray, E.MacA., 2016. "PEM fuel cell model and simulation in Matlab–Simulink based on physical parameters," Energy, Elsevier, vol. 116(P1), pages 1131-1144.
    9. Salva, J. Antonio & Iranzo, Alfredo & Rosa, Felipe & Tapia, Elvira, 2016. "Validation of cell voltage and water content in a PEM (polymer electrolyte membrane) fuel cell model using neutron imaging for different operating conditions," Energy, Elsevier, vol. 101(C), pages 100-112.
    10. Ismail, M.S. & Ingham, D.B. & Ma, L. & Hughes, K.J. & Pourkashanian, M., 2017. "Effects of catalyst agglomerate shape in polymer electrolyte fuel cells investigated by a multi-scale modelling framework," Energy, Elsevier, vol. 122(C), pages 420-430.
    11. Tzelepis, Stefanos & Kavadias, Kosmas A. & Marnellos, George E. & Xydis, George, 2021. "A review study on proton exchange membrane fuel cell electrochemical performance focusing on anode and cathode catalyst layer modelling at macroscopic level," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    12. Wu, Horng-Wen, 2016. "A review of recent development: Transport and performance modeling of PEM fuel cells," Applied Energy, Elsevier, vol. 165(C), pages 81-106.
    13. Zhang, Qian & Lin, Rui & Técher, Ludovic & Cui, Xin, 2016. "Experimental study of variable operating parameters effects on overall PEMFC performance and spatial performance distribution," Energy, Elsevier, vol. 115(P1), pages 550-560.
    14. Barzegari, Mohammad M. & Dardel, Morteza & Alizadeh, Ebrahim & Ramiar, Abas, 2016. "Reduced-order model of cascade-type PEM fuel cell stack with integrated humidifiers and water separators," Energy, Elsevier, vol. 113(C), pages 683-692.
    15. Ijaodola, O.S. & El- Hassan, Zaki & Ogungbemi, E. & Khatib, F.N. & Wilberforce, Tabbi & Thompson, James & Olabi, A.G., 2019. "Energy efficiency improvements by investigating the water flooding management on proton exchange membrane fuel cell (PEMFC)," Energy, Elsevier, vol. 179(C), pages 246-267.
    16. Fofana, Daouda & Natarajan, Sadesh Kumar & Hamelin, Jean & Benard, Pierre, 2014. "Low platinum, high limiting current density of the PEMFC (proton exchange membrane fuel cell) based on multilayer cathode catalyst approach," Energy, Elsevier, vol. 64(C), pages 398-403.
    17. Ramiar, A. & Mahmoudi, A.H. & Esmaili, Q. & Abdollahzadeh, M., 2016. "Influence of cathode flow pulsation on performance of proton exchange membrane fuel cell with interdigitated gas distributors," Energy, Elsevier, vol. 94(C), pages 206-217.
    18. Ashrafi, Moosa & Kanani, Homayoon & Shams, Mehrzad, 2018. "Numerical and experimental study of two-phase flow uniformity in channels of parallel PEM fuel cells with modified Z-type flow-fields," Energy, Elsevier, vol. 147(C), pages 317-328.
    19. Toghyani, S. & Afshari, E. & Baniasadi, E. & Atyabi, S.A. & Naterer, G.F., 2018. "Thermal and electrochemical performance assessment of a high temperature PEM electrolyzer," Energy, Elsevier, vol. 152(C), pages 237-246.
    20. Guo, Hang & Liu, Xuan & Zhao, Jian Fu & Ye, Fang & Ma, Chong Fang, 2016. "Effect of low gravity on water removal inside proton exchange membrane fuel cells (PEMFCs) with different flow channel configurations," Energy, Elsevier, vol. 112(C), pages 926-934.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:152:y:2018:i:c:p:939-959. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.