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Modelling of a high-temperature polymer electrolyte membrane fuel cell integrated with a methanol steam reformer cell

Author

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  • Ribeirinha, P.
  • Abdollahzadeh, M.
  • Sousa, J.M.
  • Boaventura, M.
  • Mendes, A.

Abstract

A 3-dimensional non-isothermal simulator comprising a high temperature polymer electrolyte membrane fuel cell (HT-PEMFC) and a methanol steam-reforming cell (MSR-C) was developed in Fluent (Ansys™). The simulator takes into account most of the significant physical processes, including the electrochemical reactions and carbon monoxide poisoning effect on the electro-catalytic activity of the FC; it also considers the methanol steam reforming (MSR), water gas shift (WGS) and methanol decomposition (MD) reactions in the MSR-C. The developed model for the integrated MSR-C/HT-PEMFC unit was simulated between 443K and 473K and validated with experimental results reported in the literature, showing always a very good agreement. The thermal sustainability of the MSR-C/HT-PEMFC unit was assessed, and the role of the thermal insulation and air intake (cathode) stoichiometry in the thermal equilibrium of the device were analysed. A novel integrated MSR-C/HT-PEM stack with ten cells was proposed and simulated, showing a performance above the reported in the literature for similar devices. The results indicated that the proposed stack operates at currents between 4.5A (0.1Acm−2) and 54A (1.2Acm−2) without any external heat source. To minimize the degradation of the components the stack should adapt the operating temperature to the current density.

Suggested Citation

  • Ribeirinha, P. & Abdollahzadeh, M. & Sousa, J.M. & Boaventura, M. & Mendes, A., 2017. "Modelling of a high-temperature polymer electrolyte membrane fuel cell integrated with a methanol steam reformer cell," Applied Energy, Elsevier, vol. 202(C), pages 6-19.
    • Handle: RePEc:eee:appene:v:202:y:2017:i:c:p:6-19
    DOI: 10.1016/j.apenergy.2017.05.120
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    References listed on IDEAS

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    3. Perng, Shiang-Wuu & Wu, Horng-Wen, 2022. "Influence of inlet-nozzle and outlet-diffuser mounted in the plate-shape reactor on PEMFC net power output and methanol steam reforming performance," Applied Energy, Elsevier, vol. 323(C).
    4. Xu, Jiawei & Xiao, Shengying & Xu, Xinrui & Xu, Xinhai, 2022. "Numerical study of carbon monoxide poisoning effect on high temperature PEMFCs based on an elementary reaction kinetics coupled electrochemical reaction model," Applied Energy, Elsevier, vol. 318(C).
    5. Zhang, S. & Reimer, U. & Beale, S.B. & Lehnert, W. & Stolten, D., 2019. "Modeling polymer electrolyte fuel cells: A high precision analysis," Applied Energy, Elsevier, vol. 233, pages 1094-1103.
    6. Kwan, Trevor Hocksun & Wu, Xiaofeng & Yao, Qinghe, 2018. "Multi-objective genetic optimization of the thermoelectric system for thermal management of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 217(C), pages 314-327.
    7. Zhang, Jun & Zhang, Caizhi & Li, Jin & Deng, Bo & Fan, Min & Ni, Meng & Mao, Zhanxin & Yuan, Honggeng, 2021. "Multi-perspective analysis of CO poisoning in high-temperature proton exchange membrane fuel cell stack via numerical investigation," Renewable Energy, Elsevier, vol. 180(C), pages 313-328.
    8. Ribeirinha, P. & Abdollahzadeh, M. & Pereira, A. & Relvas, F. & Boaventura, M. & Mendes, A., 2018. "High temperature PEM fuel cell integrated with a cellular membrane methanol steam reformer: Experimental and modelling," Applied Energy, Elsevier, vol. 215(C), pages 659-669.
    9. Li, Na & Cui, Xiaoti & Zhu, Jimin & Zhou, Mengfan & Liso, Vincenzo & Cinti, Giovanni & Sahlin, Simon Lennart & Araya, Samuel Simon, 2023. "A review of reformed methanol-high temperature proton exchange membrane fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    10. Hyunyong Lee & Inchul Jung & Gilltae Roh & Youngseung Na & Hokeun Kang, 2020. "Comparative Analysis of On-Board Methane and Methanol Reforming Systems Combined with HT-PEM Fuel Cell and CO 2 Capture/Liquefaction System for Hydrogen Fueled Ship Application," Energies, MDPI, vol. 13(1), pages 1-25, January.

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