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Recent development of membrane for vanadium redox flow battery applications: A review

Author

Listed:
  • Shi, Yu
  • Eze, Chika
  • Xiong, Binyu
  • He, Weidong
  • Zhang, Han
  • Lim, T.M.
  • Ukil, A.
  • Zhao, Jiyun

Abstract

Responding to rapid growth of the renewable energy applications, it is crucial to develop low cost and high efficient large-scale energy storage systems in order to smooth out the intermittency of the renewable energy resources. As one of the most promising large-scale energy storage systems, vanadium redox flow battery (VRFB) has attracted great attention in recent times. Membrane is one of the key components of VRFB which not only affects the whole cyclability performance but also determines the economic viability of the system. The membrane separates the positive and negative half-cells and prevents the cross-mixing of vanadium ions while providing required ionic conductivity. The ideal membrane should have good ionic exchange capacity; high ionic conductivity, low water uptake, swelling ratio, area electrical resistance and vanadium and other poly-halide ions permeability; and good chemical stability, as well as low cost. Numerous efforts have been spent on the development of different types of membranes, including different functional groups ion exchange membrane and non-ionic porous membrane. This paper reviews the research on membranes in VRFB system, including the properties, development of traditional commercial membranes as well as recently developed membranes. It explores various methods of fabrication of the membrane products which have received relatively little attention. A detailed summary table of the new membranes with their properties, fabrication and costs is provided to serve as a reference guide for researchers and industrialists interested in VRFB system building and dynamic modelling set. Subsequently, the challenges and future directions of membrane research are examined.

Suggested Citation

  • Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    • Handle: RePEc:eee:appene:v:238:y:2019:i:c:p:202-224
    DOI: 10.1016/j.apenergy.2018.12.087
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    5. Toja, F. & Perlini, L. & Facchi, D. & Casalegno, A. & Zago, M., 2024. "Dramatic mitigation of capacity decay and volume variation in vanadium redox flow batteries through modified preparation of electrolytes," Applied Energy, Elsevier, vol. 354(PB).
    6. Manshu Kapoor & Anil Verma, 2022. "Technical benchmarking and challenges of kilowatt scale vanadium redox flow battery," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(5), September.
    7. Liu, Yongbin & Yu, Lihong & Liu, Le & Xi, Jingyu, 2021. "Tailoring the vanadium/proton ratio of electrolytes to boost efficiency and stability of vanadium flow batteries over a wide temperature range," Applied Energy, Elsevier, vol. 301(C).
    8. Robert Bock & Björn Kleinsteinberg & Bjørn Selnes-Volseth & Odne Stokke Burheim, 2021. "A Novel Iron Chloride Red-Ox Concentration Flow Cell Battery (ICFB) Concept; Power and Electrode Optimization," Energies, MDPI, vol. 14(4), pages 1-12, February.
    9. Zhang, Ziyu & Ding, Tao & Zhou, Quan & Sun, Yuge & Qu, Ming & Zeng, Ziyu & Ju, Yuntao & Li, Li & Wang, Kang & Chi, Fangde, 2021. "A review of technologies and applications on versatile energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    10. Zhenkang Wang & Haoqing Ji & Jinqiu Zhou & Yiwei Zheng & Jie Liu & Tao Qian & Chenglin Yan, 2023. "Exploiting nonaqueous self-stratified electrolyte systems toward large-scale energy storage," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    11. Iñigo Aramendia & Unai Fernandez-Gamiz & Adrian Martinez-San-Vicente & Ekaitz Zulueta & Jose Manuel Lopez-Guede, 2020. "Vanadium Redox Flow Batteries: A Review Oriented to Fluid-Dynamic Optimization," Energies, MDPI, vol. 14(1), pages 1-20, December.
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