IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v180y2019icp341-355.html
   My bibliography  Save this article

Analysis of storage capacity and energy conversion on the performance of gradient and double-layered porous electrode in all-vanadium redox flow batteries

Author

Listed:
  • Chen, Wei
  • Kang, Jialun
  • Shu, Qing
  • Zhang, Yunsong

Abstract

In the general monolayer electrode of constant porosity, the conflict between the available specific surface area and the hydraulic permeability is a momentous hinder in designing the high-performance electrodes of VRFB. In this paper, several novel electrode structures with gradient or double-layered porous media (GPM or DLPM) are installed in the stack to decouple the conflict and connection between hydraulic permeability and specific surface area. Ten kinds of electrode structures with constant, linear or stepwise decreasing/increasing porosity respectively are designed and compared. The lower concentration polarization loss, higher cell energy efficiency and capacity in the stepwise and linear increasing of porosity profiles are related to the electrolyte flow uniformity in porous electrode and alleviation of conflict between permeability and specific surface area. The higher pumping losses in these arrangements serve as deteriorative factor. In the stepwise increasing porosity mode, the effects of the thickness ratio between two porous layers with different porosities, electrode thickness and porosity variation amplitude were investigated. There is an optimum thickness ratio and electrode thickness to obtain the saturated cell capacity and more energy efficiency, and the rise amplitude of porosity will reduce the system efficiency while increasing the cell capacity.

Suggested Citation

  • Chen, Wei & Kang, Jialun & Shu, Qing & Zhang, Yunsong, 2019. "Analysis of storage capacity and energy conversion on the performance of gradient and double-layered porous electrode in all-vanadium redox flow batteries," Energy, Elsevier, vol. 180(C), pages 341-355.
    • Handle: RePEc:eee:energy:v:180:y:2019:i:c:p:341-355
    DOI: 10.1016/j.energy.2019.05.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219309004
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.05.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Oh, Kyeongmin & Yoo, Haneul & Ko, Johan & Won, Seongyeon & Ju, Hyunchul, 2015. "Three-dimensional, transient, nonisothermal model of all-vanadium redox flow batteries," Energy, Elsevier, vol. 81(C), pages 3-14.
    2. Kim, Jungmyung & Park, Heesung, 2018. "Impact of nanofluidic electrolyte on the energy storage capacity in vanadium redox flow battery," Energy, Elsevier, vol. 160(C), pages 192-199.
    3. Han, Xue & Zhao, Guankun & Xu, Chao & Ju, Xing & Du, Xiaoze & Yang, Yongping, 2017. "Parametric analysis of a hybrid solar concentrating photovoltaic/concentrating solar power (CPV/CSP) system," Applied Energy, Elsevier, vol. 189(C), pages 520-533.
    4. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    5. Sun, Hong & Yu, Mingfu & Li, Qiang & Zhuang, Kaiming & Li, Jie & Almheiri, Saif & Zhang, Xiaochen, 2019. "Characteristics of charge/discharge and alternating current impedance in all-vanadium redox flow batteries," Energy, Elsevier, vol. 168(C), pages 693-701.
    6. Badrinarayanan, Rajagopalan & Tseng, King Jet & Soong, Boon Hee & Wei, Zhongbao, 2017. "Modelling and control of vanadium redox flow battery for profile based charging applications," Energy, Elsevier, vol. 141(C), pages 1479-1488.
    7. Yoon, Sang Jun & Kim, Sangwon & Kim, Dong Kyu, 2019. "Optimization of local porosity in the electrode as an advanced channel for all-vanadium redox flow battery," Energy, Elsevier, vol. 172(C), pages 26-35.
    8. Cunha, Álvaro & Brito, F.P. & Martins, Jorge & Rodrigues, Nuno & Monteiro, Vitor & Afonso, João L. & Ferreira, Paula, 2016. "Assessment of the use of vanadium redox flow batteries for energy storage and fast charging of electric vehicles in gas stations," Energy, Elsevier, vol. 115(P2), pages 1478-1494.
    9. Yin, Cong & Gao, Yan & Guo, Shaoyun & Tang, Hao, 2014. "A coupled three dimensional model of vanadium redox flow battery for flow field designs," Energy, Elsevier, vol. 74(C), pages 886-895.
    10. Jiang, H.R. & Shyy, W. & Ren, Y.X. & Zhang, R.H. & Zhao, T.S., 2019. "A room-temperature activated graphite felt as the cost-effective, highly active and stable electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 544-553.
    11. Pan, Jianxin & Huang, Mianyan & Li, Xue & Wang, Shubo & Li, Weihua & Ma, Tao & Xie, Xiaofeng & Ramani, Vijay, 2016. "The performance of all vanadium redox flow batteries at below-ambient temperatures," Energy, Elsevier, vol. 107(C), pages 784-790.
    12. Zeng, Y.K. & Zhao, T.S. & Zhou, X.L. & Zeng, L. & Wei, L., 2016. "The effects of design parameters on the charge-discharge performance of iron-chromium redox flow batteries," Applied Energy, Elsevier, vol. 182(C), pages 204-209.
    13. Kim, Dong Kyu & Yoon, Sang Jun & Lee, Jaeho & Kim, Sangwon, 2018. "Parametric study and flow rate optimization of all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 228(C), pages 891-901.
    14. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ma, Qiang & Fu, Wenxuan & Zhao, Lijuan & Chen, Zhenqian & Su, Huaneng & Xu, Qian, 2023. "A double-layer electrode for the negative side of deep eutectic solvent electrolyte-based vanadium-iron redox flow battery," Energy, Elsevier, vol. 265(C).
    2. He, Qijiao & Li, Zheng & Zhao, Dongqi & Yu, Jie & Tan, Peng & Guo, Meiting & Liao, Tianjun & Zhao, Tianshou & Ni, Meng, 2023. "A 3D modelling study on all vanadium redox flow battery at various operating temperatures," Energy, Elsevier, vol. 282(C).
    3. Jienkulsawad, Prathak & Jirabovornwisut, Tossaporn & Chen, Yong-Song & Arpornwichanop, Amornchai, 2023. "Effect of battery material and operation on dynamic performance of a vanadium redox flow battery under electrolyte imbalance conditions," Energy, Elsevier, vol. 268(C).
    4. Cheng, Ziqiang & Tenny, Kevin M. & Pizzolato, Alberto & Forner-Cuenca, Antoni & Verda, Vittorio & Chiang, Yet-Ming & Brushett, Fikile R. & Behrou, Reza, 2020. "Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods," Applied Energy, Elsevier, vol. 279(C).
    5. Gao, Qingchen & Bao, Zhiming & Li, Weizhuo & Gong, Zhichao & Fan, Linhao & Jiao, Kui, 2024. "Performance analysis and gradient-porosity electrode design of vanadium redox flow batteries based on CFD simulations under open-source environment," Energy, Elsevier, vol. 289(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yoon, Sang Jun & Kim, Sangwon & Kim, Dong Kyu, 2019. "Optimization of local porosity in the electrode as an advanced channel for all-vanadium redox flow battery," Energy, Elsevier, vol. 172(C), pages 26-35.
    2. Zeng, Yikai & Li, Fenghao & Lu, Fei & Zhou, Xuelong & Yuan, Yanping & Cao, Xiaoling & Xiang, Bo, 2019. "A hierarchical interdigitated flow field design for scale-up of high-performance redox flow batteries," Applied Energy, Elsevier, vol. 238(C), pages 435-441.
    3. Sun, Jie & Zheng, Menglian & Yang, Zhongshu & Yu, Zitao, 2019. "Flow field design pathways from lab-scale toward large-scale flow batteries," Energy, Elsevier, vol. 173(C), pages 637-646.
    4. Kim, Jungmyung & Park, Heesung, 2018. "Impact of nanofluidic electrolyte on the energy storage capacity in vanadium redox flow battery," Energy, Elsevier, vol. 160(C), pages 192-199.
    5. Kim, Jungmyung & Park, Heesung, 2019. "Electrokinetic parameters of a vanadium redox flow battery with varying temperature and electrolyte flow rate," Renewable Energy, Elsevier, vol. 138(C), pages 284-291.
    6. Heidarian, Alireza & Cheung, Sherman C.P. & Ojha, Ruchika & Rosengarten, Gary, 2022. "Effects of current collector shape and configuration on charge percolation and electric conductivity of slurry electrodes for electrochemical systems," Energy, Elsevier, vol. 239(PD).
    7. Zhang, Kaiyue & Xiong, Jing & Yan, Chuanwei & Tang, Ao, 2020. "In-situ measurement of electrode kinetics in porous electrode for vanadium flow batteries using symmetrical cell design," Applied Energy, Elsevier, vol. 272(C).
    8. Iñigo Aramendia & Unai Fernandez-Gamiz & Adrian Martinez-San-Vicente & Ekaitz Zulueta & Jose Manuel Lopez-Guede, 2020. "Vanadium Redox Flow Batteries: A Review Oriented to Fluid-Dynamic Optimization," Energies, MDPI, vol. 14(1), pages 1-20, December.
    9. Weng, Guo-Ming & Li, Chi-Ying Vanessa & Chan, Kwong-Yu, 2019. "Three-electrolyte electrochemical energy storage systems using both anion- and cation-exchange membranes as separators," Energy, Elsevier, vol. 167(C), pages 1011-1018.
    10. Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    11. Sun, Hong & Yu, Mingfu & Li, Qiang & Zhuang, Kaiming & Li, Jie & Almheiri, Saif & Zhang, Xiaochen, 2019. "Characteristics of charge/discharge and alternating current impedance in all-vanadium redox flow batteries," Energy, Elsevier, vol. 168(C), pages 693-701.
    12. Messaggi, M. & Canzi, P. & Mereu, R. & Baricci, A. & Inzoli, F. & Casalegno, A. & Zago, M., 2018. "Analysis of flow field design on vanadium redox flow battery performance: Development of 3D computational fluid dynamic model and experimental validation," Applied Energy, Elsevier, vol. 228(C), pages 1057-1070.
    13. Cheng, Ziqiang & Tenny, Kevin M. & Pizzolato, Alberto & Forner-Cuenca, Antoni & Verda, Vittorio & Chiang, Yet-Ming & Brushett, Fikile R. & Behrou, Reza, 2020. "Data-driven electrode parameter identification for vanadium redox flow batteries through experimental and numerical methods," Applied Energy, Elsevier, vol. 279(C).
    14. Gao, Qingchen & Bao, Zhiming & Li, Weizhuo & Gong, Zhichao & Fan, Linhao & Jiao, Kui, 2024. "Performance analysis and gradient-porosity electrode design of vanadium redox flow batteries based on CFD simulations under open-source environment," Energy, Elsevier, vol. 289(C).
    15. Jiang, H.R. & Zeng, Y.K. & Wu, M.C. & Shyy, W. & Zhao, T.S., 2019. "A uniformly distributed bismuth nanoparticle-modified carbon cloth electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 240(C), pages 226-235.
    16. Leung, P. & Martin, T. & Liras, M. & Berenguer, A.M. & Marcilla, R. & Shah, A. & An, L. & Anderson, M.A. & Palma, J., 2017. "Cyclohexanedione as the negative electrode reaction for aqueous organic redox flow batteries," Applied Energy, Elsevier, vol. 197(C), pages 318-326.
    17. Longchun Zhong & Fengming Chu, 2023. "A Novel Biomimetic Lung-Shaped Flow Field for All-Vanadium Redox Flow Battery," Sustainability, MDPI, vol. 15(18), pages 1-14, September.
    18. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    19. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Numerical study on vanadium redox flow battery performance with non-uniformly compressed electrode and serpentine flow field," Applied Energy, Elsevier, vol. 220(C), pages 106-116.
    20. Jiang, H.R. & Shyy, W. & Ren, Y.X. & Zhang, R.H. & Zhao, T.S., 2019. "A room-temperature activated graphite felt as the cost-effective, highly active and stable electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 544-553.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:180:y:2019:i:c:p:341-355. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.