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Performance of a vanadium redox flow battery with a VANADion membrane

Author

Listed:
  • Zhou, X.L.
  • Zhao, T.S.
  • An, L.
  • Zeng, Y.K.
  • Zhu, X.B.

Abstract

Conventional vanadium redox flow batteries (VRFBs) using Nafion 115 suffered from issues associated with high ohmic resistance and high capital cost. In this work, we report a commercial membrane (VANADion), consisting of a porous layer and a dense Nafion layer, as a promising alternative to Nafion 115. In the dual-layer structure, the porous layer (∼210μm) can offer a high ionic conductivity and the dense Nafion layer (∼20μm) can depress the convective flow of electrolyte through the membrane. By comparing with the conventional Nafion 115 in a VRFB, it is found that the change from the conventional Nafion 115 to the composite one results in an increase in the energy efficiency from 71.3% to 76.2% and an increase in the electrolyte utilization from 54.1% to 68.4% at a current density of as high as 240mAcm−2. In addition, although two batteries show the comparable cycling performance at current densities ranging from 80mAcm−2 to 240mAcm−2, the composite membrane is estimated to be significantly cheaper than the conventional Nafion 115 due to the fact that the porous layer is rather cost-effective and the dense Nafion layer is rather thin. The impressive combination of desirable performance and low cost makes this composite membrane highly promising in the VRFB applications.

Suggested Citation

  • Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Zhu, X.B., 2016. "Performance of a vanadium redox flow battery with a VANADion membrane," Applied Energy, Elsevier, vol. 180(C), pages 353-359.
    • Handle: RePEc:eee:appene:v:180:y:2016:i:c:p:353-359
    DOI: 10.1016/j.apenergy.2016.08.001
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    References listed on IDEAS

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    5. Wei, L. & Zhao, T.S. & Zhao, G. & An, L. & Zeng, L., 2016. "A high-performance carbon nanoparticle-decorated graphite felt electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 176(C), pages 74-79.
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    2. Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    3. Hsu, Ning-Yih & Devi, Nitika & Lin, Yu-I & Hu, Yi-Hsin & Ku, Hung-Hsien & Arpornwichanop, Amornchai & Chen, Yong-Song, 2022. "Study on the effect of electrode configuration on the performance of a hydrogen/vanadium redox flow battery," Renewable Energy, Elsevier, vol. 190(C), pages 658-663.
    4. Zeng, L. & Zhao, T.S. & Wei, L. & Jiang, H.R. & Wu, M.C., 2019. "Anion exchange membranes for aqueous acid-based redox flow batteries: Current status and challenges," Applied Energy, Elsevier, vol. 233, pages 622-643.
    5. Souentie, Stamatios & Amr, Issam & Alsuhaibani, Abdulrahman & Almazroei, Essa & Hammad, Ahmad D., 2017. "Temperature, charging current and state of charge effects on iron-vanadium flow batteries operation," Applied Energy, Elsevier, vol. 206(C), pages 568-576.
    6. Lei, Y. & Zhang, B.W. & Zhang, Z.H. & Bai, B.F. & Zhao, T.S., 2018. "An improved model of ion selective adsorption in membrane and its application in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 215(C), pages 591-601.
    7. Trovò, Andrea & Alotto, Piergiorgio & Giomo, Monica & Moro, Federico & Guarnieri, Massimo, 2021. "A validated dynamical model of a kW-class Vanadium Redox Flow Battery," Mathematics and Computers in Simulation (MATCOM), Elsevier, vol. 183(C), pages 66-77.
    8. Guarnieri, Massimo & Trovò, Andrea & D'Anzi, Angelo & Alotto, Piergiorgio, 2018. "Developing vanadium redox flow technology on a 9-kW 26-kWh industrial scale test facility: Design review and early experiments," Applied Energy, Elsevier, vol. 230(C), pages 1425-1434.
    9. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    10. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.

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