IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v215y2018icp591-601.html
   My bibliography  Save this article

An improved model of ion selective adsorption in membrane and its application in vanadium redox flow batteries

Author

Listed:
  • Lei, Y.
  • Zhang, B.W.
  • Zhang, Z.H.
  • Bai, B.F.
  • Zhao, T.S.

Abstract

An accurate prediction of ion selective adsorption in ion exchange membranes is essential to reflect the role of fixed charges on ion transport through the membrane in vanadium redox flow batteries (VRFB). Unlike those empirical models reported in the literature, this work reports on a new ion selective adsorption model with the Donnan effect considered for movable ions distributed in the membrane pores only. This model, no longer relying on empirical coefficients, is then applied to the calculation of ion transport through membranes in VRFBs. The model shows a more accurate prediction of vanadium crossover and membrane conductivity, and enables to capture the effect of key membrane properties on battery performance. It is found that (i) an increase in H2SO4 concentration reduces the electrolyte imbalance and improves the coulombic efficiency; (ii) an increase in membrane porosity significantly improves the membrane effective conductivity; (iii) the change of fixed charges should be careful to balance all performances. Therefore, membrane properties and operating conditions need proper adjustment to improve the battery performance, and our VRFB model is a good tool to help membrane optimization.

Suggested Citation

  • Lei, Y. & Zhang, B.W. & Zhang, Z.H. & Bai, B.F. & Zhao, T.S., 2018. "An improved model of ion selective adsorption in membrane and its application in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 215(C), pages 591-601.
    • Handle: RePEc:eee:appene:v:215:y:2018:i:c:p:591-601
    DOI: 10.1016/j.apenergy.2018.02.042
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918301673
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.02.042?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yin, Cong & Guo, Shaoyun & Fang, Honglin & Liu, Jiayi & Li, Yang & Tang, Hao, 2015. "Numerical and experimental studies of stack shunt current for vanadium redox flow battery," Applied Energy, Elsevier, vol. 151(C), pages 237-248.
    2. Aneke, Mathew & Wang, Meihong, 2016. "Energy storage technologies and real life applications – A state of the art review," Applied Energy, Elsevier, vol. 179(C), pages 350-377.
    3. Alotto, Piergiorgio & Guarnieri, Massimo & Moro, Federico, 2014. "Redox flow batteries for the storage of renewable energy: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 325-335.
    4. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    5. Li, Li & Nikiforidis, Georgios & Leung, Michael K.H. & Daoud, Walid A., 2016. "Vanadium microfluidic fuel cell with novel multi-layer flow-through porous electrodes: Model, simulations and experiments," Applied Energy, Elsevier, vol. 177(C), pages 729-739.
    6. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
    7. Yang, Xiao-Guang & Ye, Qiang & Cheng, Ping & Zhao, Tim S., 2015. "Effects of the electric field on ion crossover in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 145(C), pages 306-319.
    8. Wei, L. & Zhao, T.S. & Xu, Q. & Zhou, X.L. & Zhang, Z.H., 2017. "In-situ investigation of hydrogen evolution behavior in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 190(C), pages 1112-1118.
    9. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Zhu, X.B., 2016. "Performance of a vanadium redox flow battery with a VANADion membrane," Applied Energy, Elsevier, vol. 180(C), pages 353-359.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Toja, F. & Perlini, L. & Facchi, D. & Casalegno, A. & Zago, M., 2024. "Dramatic mitigation of capacity decay and volume variation in vanadium redox flow batteries through modified preparation of electrolytes," Applied Energy, Elsevier, vol. 354(PB).
    2. Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    3. Guarnieri, Massimo & Trovò, Andrea & D'Anzi, Angelo & Alotto, Piergiorgio, 2018. "Developing vanadium redox flow technology on a 9-kW 26-kWh industrial scale test facility: Design review and early experiments," Applied Energy, Elsevier, vol. 230(C), pages 1425-1434.
    4. Chen, Hui & Li, Xiangrong & Gao, Hai & Liu, Jianguo & Yan, Chuanwei & Tang, Ao, 2019. "Numerical modelling and in-depth analysis of multi-stack vanadium flow battery module incorporating transport delay," Applied Energy, Elsevier, vol. 247(C), pages 13-23.
    5. Guarnieri, Massimo & Trovò, Andrea & Picano, Francesco, 2020. "Enhancing the efficiency of kW-class vanadium redox flow batteries by flow factor modulation: An experimental method," Applied Energy, Elsevier, vol. 262(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
    2. Toja, F. & Perlini, L. & Facchi, D. & Casalegno, A. & Zago, M., 2024. "Dramatic mitigation of capacity decay and volume variation in vanadium redox flow batteries through modified preparation of electrolytes," Applied Energy, Elsevier, vol. 354(PB).
    3. Bhattarai, Arjun & Wai, Nyunt & Schweiss, Rüdiger & Whitehead, Adam & Scherer, Günther G. & Ghimire, Purna C. & Lim, Tuti M. & Hng, Huey Hoon, 2019. "Vanadium redox flow battery with slotted porous electrodes and automatic rebalancing demonstrated on a 1 kW system level," Applied Energy, Elsevier, vol. 236(C), pages 437-443.
    4. Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    5. Chen, Hui & Li, Xiangrong & Gao, Hai & Liu, Jianguo & Yan, Chuanwei & Tang, Ao, 2019. "Numerical modelling and in-depth analysis of multi-stack vanadium flow battery module incorporating transport delay," Applied Energy, Elsevier, vol. 247(C), pages 13-23.
    6. Souentie, Stamatios & Amr, Issam & Alsuhaibani, Abdulrahman & Almazroei, Essa & Hammad, Ahmad D., 2017. "Temperature, charging current and state of charge effects on iron-vanadium flow batteries operation," Applied Energy, Elsevier, vol. 206(C), pages 568-576.
    7. Pugach, M. & Vyshinsky, V. & Bischi, A., 2019. "Energy efficiency analysis for a kilo-watt class vanadium redox flow battery system," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    8. Zeng, Yikai & Li, Fenghao & Lu, Fei & Zhou, Xuelong & Yuan, Yanping & Cao, Xiaoling & Xiang, Bo, 2019. "A hierarchical interdigitated flow field design for scale-up of high-performance redox flow batteries," Applied Energy, Elsevier, vol. 238(C), pages 435-441.
    9. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
    10. Wei, L. & Wu, M.C. & Zhao, T.S. & Zeng, Y.K. & Ren, Y.X., 2018. "An aqueous alkaline battery consisting of inexpensive all-iron redox chemistries for large-scale energy storage," Applied Energy, Elsevier, vol. 215(C), pages 98-105.
    11. Leung, P. & Martin, T. & Liras, M. & Berenguer, A.M. & Marcilla, R. & Shah, A. & An, L. & Anderson, M.A. & Palma, J., 2017. "Cyclohexanedione as the negative electrode reaction for aqueous organic redox flow batteries," Applied Energy, Elsevier, vol. 197(C), pages 318-326.
    12. Raijmakers, L.H.J. & Danilov, D.L. & Eichel, R.-A. & Notten, P.H.L., 2019. "A review on various temperature-indication methods for Li-ion batteries," Applied Energy, Elsevier, vol. 240(C), pages 918-945.
    13. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    14. Pugach, M. & Kondratenko, M. & Briola, S. & Bischi, A., 2018. "Zero dimensional dynamic model of vanadium redox flow battery cell incorporating all modes of vanadium ions crossover," Applied Energy, Elsevier, vol. 226(C), pages 560-569.
    15. Yue, Meng & Lv, Zhiqiang & Zheng, Qiong & Li, Xianfeng & Zhang, Huamin, 2019. "Battery assembly optimization: Tailoring the electrode compression ratio based on the polarization analysis in vanadium flow batteries," Applied Energy, Elsevier, vol. 235(C), pages 495-508.
    16. Trovò, Andrea & Alotto, Piergiorgio & Giomo, Monica & Moro, Federico & Guarnieri, Massimo, 2021. "A validated dynamical model of a kW-class Vanadium Redox Flow Battery," Mathematics and Computers in Simulation (MATCOM), Elsevier, vol. 183(C), pages 66-77.
    17. Culcasi, Andrea & Gurreri, Luigi & Zaffora, Andrea & Cosenza, Alessandro & Tamburini, Alessandro & Micale, Giorgio, 2020. "On the modelling of an Acid/Base Flow Battery: An innovative electrical energy storage device based on pH and salinity gradients," Applied Energy, Elsevier, vol. 277(C).
    18. Guarnieri, Massimo & Trovò, Andrea & D'Anzi, Angelo & Alotto, Piergiorgio, 2018. "Developing vanadium redox flow technology on a 9-kW 26-kWh industrial scale test facility: Design review and early experiments," Applied Energy, Elsevier, vol. 230(C), pages 1425-1434.
    19. Arenas, Luis F. & Loh, Adeline & Trudgeon, David P. & Li, Xiaohong & Ponce de León, Carlos & Walsh, Frank C., 2018. "The characteristics and performance of hybrid redox flow batteries with zinc negative electrodes for energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 992-1016.
    20. Daniel Akinyele & Juri Belikov & Yoash Levron, 2017. "Battery Storage Technologies for Electrical Applications: Impact in Stand-Alone Photovoltaic Systems," Energies, MDPI, vol. 10(11), pages 1-39, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:215:y:2018:i:c:p:591-601. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.