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An improved model of ion selective adsorption in membrane and its application in vanadium redox flow batteries

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  • Lei, Y.
  • Zhang, B.W.
  • Zhang, Z.H.
  • Bai, B.F.
  • Zhao, T.S.

Abstract

An accurate prediction of ion selective adsorption in ion exchange membranes is essential to reflect the role of fixed charges on ion transport through the membrane in vanadium redox flow batteries (VRFB). Unlike those empirical models reported in the literature, this work reports on a new ion selective adsorption model with the Donnan effect considered for movable ions distributed in the membrane pores only. This model, no longer relying on empirical coefficients, is then applied to the calculation of ion transport through membranes in VRFBs. The model shows a more accurate prediction of vanadium crossover and membrane conductivity, and enables to capture the effect of key membrane properties on battery performance. It is found that (i) an increase in H2SO4 concentration reduces the electrolyte imbalance and improves the coulombic efficiency; (ii) an increase in membrane porosity significantly improves the membrane effective conductivity; (iii) the change of fixed charges should be careful to balance all performances. Therefore, membrane properties and operating conditions need proper adjustment to improve the battery performance, and our VRFB model is a good tool to help membrane optimization.

Suggested Citation

  • Lei, Y. & Zhang, B.W. & Zhang, Z.H. & Bai, B.F. & Zhao, T.S., 2018. "An improved model of ion selective adsorption in membrane and its application in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 215(C), pages 591-601.
    • Handle: RePEc:eee:appene:v:215:y:2018:i:c:p:591-601
    DOI: 10.1016/j.apenergy.2018.02.042
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    Cited by:

    1. Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    2. Guarnieri, Massimo & Trovò, Andrea & D'Anzi, Angelo & Alotto, Piergiorgio, 2018. "Developing vanadium redox flow technology on a 9-kW 26-kWh industrial scale test facility: Design review and early experiments," Applied Energy, Elsevier, vol. 230(C), pages 1425-1434.
    3. Chen, Hui & Li, Xiangrong & Gao, Hai & Liu, Jianguo & Yan, Chuanwei & Tang, Ao, 2019. "Numerical modelling and in-depth analysis of multi-stack vanadium flow battery module incorporating transport delay," Applied Energy, Elsevier, vol. 247(C), pages 13-23.
    4. Toja, F. & Perlini, L. & Facchi, D. & Casalegno, A. & Zago, M., 2024. "Dramatic mitigation of capacity decay and volume variation in vanadium redox flow batteries through modified preparation of electrolytes," Applied Energy, Elsevier, vol. 354(PB).
    5. Guarnieri, Massimo & Trovò, Andrea & Picano, Francesco, 2020. "Enhancing the efficiency of kW-class vanadium redox flow batteries by flow factor modulation: An experimental method," Applied Energy, Elsevier, vol. 262(C).

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