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A validated dynamical model of a kW-class Vanadium Redox Flow Battery

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  • Trovò, Andrea
  • Alotto, Piergiorgio
  • Giomo, Monica
  • Moro, Federico
  • Guarnieri, Massimo

Abstract

The development of redox flow batteries depends on the research on new materials as well as on the technological development, but also on appropriate models which allow to simulate their performance in operative conditions. Very few investigations are reported in the literature concerning the technology, modeling and simulation of large-scale Vanadium Redox Flow Battery systems, built around multi-cell stacks. This paper regards the modeling of an industrial-sized 9 kW test facility. In particular, a complete dynamic model is presented, that takes into account all thermal effects occurring inside the stack, resulting in a complex non-linear coupled formulation, that allows to simulate the battery operation in any realistic conditions. The model is able to simulate the thermal behavior both in standby, i.e. without power and reactant flow, as well as in load operation, i.e. in charge and discharge. The numerical implementation of the model is described in detail. The model validation is also described, consisting in comparing computed data with experimental measurements taken on the available test facility.

Suggested Citation

  • Trovò, Andrea & Alotto, Piergiorgio & Giomo, Monica & Moro, Federico & Guarnieri, Massimo, 2021. "A validated dynamical model of a kW-class Vanadium Redox Flow Battery," Mathematics and Computers in Simulation (MATCOM), Elsevier, vol. 183(C), pages 66-77.
    • Handle: RePEc:eee:matcom:v:183:y:2021:i:c:p:66-77
    DOI: 10.1016/j.matcom.2019.12.011
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    References listed on IDEAS

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    1. Messaggi, M. & Canzi, P. & Mereu, R. & Baricci, A. & Inzoli, F. & Casalegno, A. & Zago, M., 2018. "Analysis of flow field design on vanadium redox flow battery performance: Development of 3D computational fluid dynamic model and experimental validation," Applied Energy, Elsevier, vol. 228(C), pages 1057-1070.
    2. Oh, Kyeongmin & Yoo, Haneul & Ko, Johan & Won, Seongyeon & Ju, Hyunchul, 2015. "Three-dimensional, transient, nonisothermal model of all-vanadium redox flow batteries," Energy, Elsevier, vol. 81(C), pages 3-14.
    3. Alotto, Piergiorgio & Guarnieri, Massimo & Moro, Federico, 2014. "Redox flow batteries for the storage of renewable energy: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 325-335.
    4. Trovò, Andrea & Marini, Giacomo & Sutto, Alessandro & Alotto, Piergiorgio & Giomo, Monica & Moro, Federico & Guarnieri, Massimo, 2019. "Standby thermal model of a vanadium redox flow battery stack with crossover and shunt-current effects," Applied Energy, Elsevier, vol. 240(C), pages 893-906.
    5. Guarnieri, Massimo & Trovò, Andrea & D'Anzi, Angelo & Alotto, Piergiorgio, 2018. "Developing vanadium redox flow technology on a 9-kW 26-kWh industrial scale test facility: Design review and early experiments," Applied Energy, Elsevier, vol. 230(C), pages 1425-1434.
    6. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Zhu, X.B., 2016. "Performance of a vanadium redox flow battery with a VANADion membrane," Applied Energy, Elsevier, vol. 180(C), pages 353-359.
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    Cited by:

    1. Kurilovich, Aleksandr A. & Trovò, Andrea & Pugach, Mikhail & Stevenson, Keith J. & Guarnieri, Massimo, 2022. "Prospect of modeling industrial scale flow batteries – From experimental data to accurate overpotential identification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    2. Park, Gyunho & Jeong, Hayoung & Lee, Wonmi & Han, Jeong Woo & Chang, Duck Rye & Kwon, Yongchai, 2024. "Scaled-up aqueous redox flow battery using anthraquinone negalyte and vanadium posilyte with inorganic additive," Applied Energy, Elsevier, vol. 353(PB).

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