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An aqueous alkaline battery consisting of inexpensive all-iron redox chemistries for large-scale energy storage

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  • Wei, L.
  • Wu, M.C.
  • Zhao, T.S.
  • Zeng, Y.K.
  • Ren, Y.X.

Abstract

In this work, an iron-based alkaline battery using the same redox-active element featuring different coordination chemistries is developed and tested. The battery achieves a significantly low active material cost per kilowatt hour ($22 kW h−1) due to the inherently inexpensive price and availability of iron oxide and iron ferricyanide, particularly when compared with state-of-the-art vanadium redox flow batteries ($118 kW h−1) or the commercialized nickel cadmium battery ($51 kW h−1). Experimental results show that the present battery creates an equilibrium cell potential of 1.2 V and its coulombic efficiency reaches as high as 99% at a current density higher than 4 mA cm−2. Moreover, the energy efficiency can be maintained above 76% and the capacity decay rate is only 0.15% per cycle at a current density of 2 mA cm−2 over 150 cycles. With these advantages, the battery offers a promising solution for low-cost energy storage applications.

Suggested Citation

  • Wei, L. & Wu, M.C. & Zhao, T.S. & Zeng, Y.K. & Ren, Y.X., 2018. "An aqueous alkaline battery consisting of inexpensive all-iron redox chemistries for large-scale energy storage," Applied Energy, Elsevier, vol. 215(C), pages 98-105.
    • Handle: RePEc:eee:appene:v:215:y:2018:i:c:p:98-105
    DOI: 10.1016/j.apenergy.2018.01.080
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    References listed on IDEAS

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    1. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
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    Cited by:

    1. Trocino, Stefano & Lo Faro, Massimiliano & Zignani, Sabrina Campagna & Antonucci, Vincenzo & Aricò, Antonino Salvatore, 2019. "High performance solid-state iron-air rechargeable ceramic battery operating at intermediate temperatures (500–650 °C)," Applied Energy, Elsevier, vol. 233, pages 386-394.

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