IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-37995-8.html
   My bibliography  Save this article

Exploiting nonaqueous self-stratified electrolyte systems toward large-scale energy storage

Author

Listed:
  • Zhenkang Wang

    (Soochow University)

  • Haoqing Ji

    (Soochow University)

  • Jinqiu Zhou

    (Nantong University)

  • Yiwei Zheng

    (Soochow University)

  • Jie Liu

    (Nantong University)

  • Tao Qian

    (Nantong University
    Light Industry Institute of Electrochemical Power Sources)

  • Chenglin Yan

    (Soochow University
    Light Industry Institute of Electrochemical Power Sources)

Abstract

Biphasic self-stratified batteries (BSBs) provide a new direction in battery philosophy for large-scale energy storage, which successfully reduces the cost and simplifies the architecture of redox flow batteries. However, current aqueous BSBs have intrinsic limits on the selection range of electrode materials and energy density due to the narrow electrochemical window of water. Thus, herein, we develop nonaqueous BSBs based on Li-S chemistry, which deliver an almost quadruple increase in energy density of 88.5 Wh L−1 as compared with the existing aqueous BSBs systems. In situ spectral characterization and molecular dynamics simulations jointly elucidate that while ensuring the mass transfer of Li+, the positive redox species are strictly confined to the bottom-phase electrolyte. This proof-of-concept of Li-S BSBs pushes the energy densities of BSBs and provides an idea to realize massive-scale energy storage with large capacitance.

Suggested Citation

  • Zhenkang Wang & Haoqing Ji & Jinqiu Zhou & Yiwei Zheng & Jie Liu & Tao Qian & Chenglin Yan, 2023. "Exploiting nonaqueous self-stratified electrolyte systems toward large-scale energy storage," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37995-8
    DOI: 10.1038/s41467-023-37995-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-37995-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-37995-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Rochelle Weber & Matthew Genovese & A. J. Louli & Samuel Hames & Cameron Martin & Ian G. Hill & J. R. Dahn, 2019. "Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte," Nature Energy, Nature, vol. 4(8), pages 683-689, August.
    2. Shi, Yu & Eze, Chika & Xiong, Binyu & He, Weidong & Zhang, Han & Lim, T.M. & Ukil, A. & Zhao, Jiyun, 2019. "Recent development of membrane for vanadium redox flow battery applications: A review," Applied Energy, Elsevier, vol. 238(C), pages 202-224.
    3. Xiaowei Shen & Yutao Li & Tao Qian & Jie Liu & Jinqiu Zhou & Chenglin Yan & John B. Goodenough, 2019. "Lithium anode stable in air for low-cost fabrication of a dendrite-free lithium battery," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    4. Wen Yan & Caixing Wang & Jiaqi Tian & Guoyin Zhu & Lianbo Ma & Yanrong Wang & Renpeng Chen & Yi Hu & Lei Wang & Tao Chen & Jing Ma & Zhong Jin, 2019. "All-polymer particulate slurry batteries," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shujuan Meng & Binyu Xiong & Tuti Mariana Lim, 2019. "Model-Based Condition Monitoring of a Vanadium Redox Flow Battery," Energies, MDPI, vol. 12(15), pages 1-16, August.
    2. Pier Giorgio Schiavi & Flavia Carla dos Santos Martins Padoan & Pietro Altimari & Francesca Pagnanelli, 2020. "Cryo-Mechanical Treatment and Hydrometallurgical Process for Recycling Li-MnO 2 Primary Batteries with the Direct Production of LiMnPO 4 Nanoparticles," Energies, MDPI, vol. 13(15), pages 1-11, August.
    3. Chao Wang & Ming Liu & Michel Thijs & Frans G. B. Ooms & Swapna Ganapathy & Marnix Wagemaker, 2021. "High dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    4. Shaozhen Huang & Zhibin Wu & Bernt Johannessen & Kecheng Long & Piao Qing & Pan He & Xiaobo Ji & Weifeng Wei & Yuejiao Chen & Libao Chen, 2023. "Interfacial friction enabling ≤ 20 μm thin free-standing lithium strips for lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    6. Zhang, Ziyu & Ding, Tao & Zhou, Quan & Sun, Yuge & Qu, Ming & Zeng, Ziyu & Ju, Yuntao & Li, Li & Wang, Kang & Chi, Fangde, 2021. "A review of technologies and applications on versatile energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    7. Yuan, Yuxin & Yuan, Xiaodong, 2024. "The advances and opportunities of developing solid-state battery technology: Based on the patent Information Relation Matrix," Energy, Elsevier, vol. 296(C).
    8. Alejandro Clemente & Ramon Costa-Castelló, 2020. "Redox Flow Batteries: A Literature Review Oriented to Automatic Control," Energies, MDPI, vol. 13(17), pages 1-31, September.
    9. Xin He & Jonathan M. Larson & Hans A. Bechtel & Robert Kostecki, 2022. "In situ infrared nanospectroscopy of the local processes at the Li/polymer electrolyte interface," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    10. Yan, Zhe & Zhang, Yongming & Liang, Runqi & Jin, Wenrui, 2020. "An allocative method of hybrid electrical and thermal energy storage capacity for load shifting based on seasonal difference in district energy planning," Energy, Elsevier, vol. 207(C).
    11. Iñigo Aramendia & Unai Fernandez-Gamiz & Adrian Martinez-San-Vicente & Ekaitz Zulueta & Jose Manuel Lopez-Guede, 2020. "Vanadium Redox Flow Batteries: A Review Oriented to Fluid-Dynamic Optimization," Energies, MDPI, vol. 14(1), pages 1-20, December.
    12. Xinhua Zheng & Zaichun Liu & Jifei Sun & Ruihao Luo & Kui Xu & Mingyu Si & Ju Kang & Yuan Yuan & Shuang Liu & Touqeer Ahmad & Taoli Jiang & Na Chen & Mingming Wang & Yan Xu & Mingyan Chuai & Zhengxin , 2023. "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    13. Manshu Kapoor & Anil Verma, 2022. "Technical benchmarking and challenges of kilowatt scale vanadium redox flow battery," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(5), September.
    14. Yan Zhao & Tianhong Zhou & Mounir Mensi & Jang Wook Choi & Ali Coskun, 2023. "Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    15. Adarsh Dave & Jared Mitchell & Sven Burke & Hongyi Lin & Jay Whitacre & Venkatasubramanian Viswanathan, 2022. "Autonomous optimization of non-aqueous Li-ion battery electrolytes via robotic experimentation and machine learning coupling," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    16. Liu, Yongbin & Yu, Lihong & Liu, Le & Xi, Jingyu, 2021. "Tailoring the vanadium/proton ratio of electrolytes to boost efficiency and stability of vanadium flow batteries over a wide temperature range," Applied Energy, Elsevier, vol. 301(C).
    17. Nayeong Kim & Johannes Elbert & Ekaterina Shchukina & Xiao Su, 2024. "Integrating redox-electrodialysis and electrosorption for the removal of ultra-short- to long-chain PFAS," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    18. Solomon T. Oyakhire & Wenbo Zhang & Andrew Shin & Rong Xu & David T. Boyle & Zhiao Yu & Yusheng Ye & Yufei Yang & James A. Raiford & William Huang & Joel R. Schneider & Yi Cui & Stacey F. Bent, 2022. "Electrical resistance of the current collector controls lithium morphology," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    19. Hyeokjin Kwon & Hongsin Kim & Jaemin Hwang & Wonsik Oh & Youngil Roh & Dongseok Shin & Hee-Tak Kim, 2024. "Borate–pyran lean electrolyte-based Li-metal batteries with minimal Li corrosion," Nature Energy, Nature, vol. 9(1), pages 57-69, January.
    20. Chen, Ying & Liu, Lianchao & Huang, Yue & Cao, Haidong & Liu, Tiantian & Qi, Zhixian & Hu, Jingwen & Guo, Yonggui & Sun, Jianteng & Liang, Maofeng & Wei, Junfu & Zhang, Huan & Zhang, Xiaoqing & Wang, , 2024. "Low-salt organohydrogel electrolytes for wide-potential-window flexible all-solid-state supercapacitors," Applied Energy, Elsevier, vol. 363(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-37995-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.