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A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility

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  • Zhou, X.L.
  • Zhao, T.S.
  • An, L.
  • Zeng, Y.K.
  • Yan, X.H.

Abstract

Previous vanadium redox flow battery models (VRFB) use the ion mobility deduced from the ion diffusivity measured at low ion concentrations, resulting in an overestimation of the ionic conductivity in VRFBs that virtually operate at much higher ion concentrations. To address this issue, we propose to use the Stokes–Einstein relationship to determine an ion concentration-dependent ion mobility. A two-dimensional, transient model that incorporates the effect of ion concentrations on ion mobility is developed for VRFBs. It is shown that the present model results in: (i) a more accurate estimation of ionic conductivity, (ii) a more accurate prediction of cell voltage particularly at high current densities, and (iii) a more realistic simulation of the concentration distributions and local current density distributions in the electrodes. Finally, the model is applied to the study of the effects of important electrode design parameters and operating conditions on cell performance. It is found that the local current density, being distributed across the electrode in a manner opposite to that predicted by previous models, is much lower at the current collector side than that at the membrane side. This fact suggests that the region away from the membrane is not well utilized in conventional electrodes, thus a thinner electrode is preferred.

Suggested Citation

  • Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
  • Handle: RePEc:eee:appene:v:158:y:2015:i:c:p:157-166
    DOI: 10.1016/j.apenergy.2015.08.028
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    References listed on IDEAS

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    Cited by:

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    5. Zou, Wen-Jiang & Kim, Young-Bae & Jung, Seunghun, 2024. "Capacity fade prediction for vanadium redox flow batteries during long-term operations," Applied Energy, Elsevier, vol. 356(C).
    6. Chou, Yi-Sin & Hsu, Ning-Yih & Jeng, King-Tsai & Chen, Kuan-Hsiang & Yen, Shi-Chern, 2016. "A novel ultrasonic velocity sensing approach to monitoring state of charge of vanadium redox flow battery," Applied Energy, Elsevier, vol. 182(C), pages 253-259.
    7. Mahdi, Jasim M. & Nsofor, Emmanuel C., 2017. "Melting enhancement in triplex-tube latent heat energy storage system using nanoparticles-metal foam combination," Applied Energy, Elsevier, vol. 191(C), pages 22-34.
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    9. Zeng, Y.K. & Zhao, T.S. & Zhou, X.L. & Zeng, L. & Wei, L., 2016. "The effects of design parameters on the charge-discharge performance of iron-chromium redox flow batteries," Applied Energy, Elsevier, vol. 182(C), pages 204-209.
    10. López-Vizcaíno, Rubén & Mena, Esperanza & Millán, María & Rodrigo, Manuel A. & Lobato, Justo, 2017. "Performance of a vanadium redox flow battery for the storage of electricity produced in photovoltaic solar panels," Renewable Energy, Elsevier, vol. 114(PB), pages 1123-1133.
    11. He, Qijiao & Li, Zheng & Zhao, Dongqi & Yu, Jie & Tan, Peng & Guo, Meiting & Liao, Tianjun & Zhao, Tianshou & Ni, Meng, 2023. "A 3D modelling study on all vanadium redox flow battery at various operating temperatures," Energy, Elsevier, vol. 282(C).
    12. Sun, Hong & Yu, Mingfu & Li, Qiang & Zhuang, Kaiming & Li, Jie & Almheiri, Saif & Zhang, Xiaochen, 2019. "Characteristics of charge/discharge and alternating current impedance in all-vanadium redox flow batteries," Energy, Elsevier, vol. 168(C), pages 693-701.
    13. Kim, Dong Kyu & Yoon, Sang Jun & Lee, Jaeho & Kim, Sangwon, 2018. "Parametric study and flow rate optimization of all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 228(C), pages 891-901.
    14. Kim, Jungmyung & Park, Heesung, 2017. "Experimental analysis of discharge characteristics in vanadium redox flow battery," Applied Energy, Elsevier, vol. 206(C), pages 451-457.
    15. Wei, L. & Zhao, T.S. & Zeng, L. & Zhou, X.L. & Zeng, Y.K., 2016. "Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries," Applied Energy, Elsevier, vol. 180(C), pages 386-391.
    16. Chen, Hui & Li, Xiangrong & Gao, Hai & Liu, Jianguo & Yan, Chuanwei & Tang, Ao, 2019. "Numerical modelling and in-depth analysis of multi-stack vanadium flow battery module incorporating transport delay," Applied Energy, Elsevier, vol. 247(C), pages 13-23.
    17. Gao, Qingchen & Bao, Zhiming & Li, Weizhuo & Gong, Zhichao & Fan, Linhao & Jiao, Kui, 2024. "Performance analysis and gradient-porosity electrode design of vanadium redox flow batteries based on CFD simulations under open-source environment," Energy, Elsevier, vol. 289(C).
    18. Jiang, H.R. & Wu, M.C. & Ren, Y.X. & Shyy, W. & Zhao, T.S., 2018. "Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries," Applied Energy, Elsevier, vol. 213(C), pages 366-374.
    19. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
    20. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Zhu, X.B., 2016. "Performance of a vanadium redox flow battery with a VANADion membrane," Applied Energy, Elsevier, vol. 180(C), pages 353-359.

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