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Charge–discharge performance of carbon fiber-based electrodes in single cell and short stack for vanadium redox flow battery

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  • Di Blasi, A.
  • Briguglio, N.
  • Di Blasi, O.
  • Antonucci, V.

Abstract

Electrode materials, having a different graphitic character, are investigated by using a zero-gap flow field cell configuration for vanadium redox flow battery applications (VRFBs). Carbon felt (CF) and carbon paper (CP) are used as electrodes for the membrane–electrode assemblies (MEAs) realization. The samples are electrochemically characterized both as-received and after chemical treatment by using a 5cm2 single cell. A Nafion 117 membrane is used as polymer electrolyte separators. A MEAs scale-up from 5 to 25cm2 is carried out in order to assembly a 3-cells short stack in series connected. Charge–discharge cycles are carried out both in a small area single cell and in a 3-cells short stack for all samples. CF treated and untreated samples show SOC values of 45% vs. 22% at 60mAcm−2, respectively. After the chemical treatment, the worst performance of the CF sample is attributed to the mass transport issues due to the beginning of corrosion phenomena. On the contrary, CP treated electrode shows a better energy efficiency values than raw sample (72% vs. 67% at 60mAcm−2) without any morphology change on the electrode surface. A proper stack assembly and flow field scale-up record similar performance to the small single cell configuration.

Suggested Citation

  • Di Blasi, A. & Briguglio, N. & Di Blasi, O. & Antonucci, V., 2014. "Charge–discharge performance of carbon fiber-based electrodes in single cell and short stack for vanadium redox flow battery," Applied Energy, Elsevier, vol. 125(C), pages 114-122.
  • Handle: RePEc:eee:appene:v:125:y:2014:i:c:p:114-122
    DOI: 10.1016/j.apenergy.2014.03.043
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    2. Wei, Zhongbao & Zhao, Jiyun & Xiong, Binyu, 2014. "Dynamic electro-thermal modeling of all-vanadium redox flow battery with forced cooling strategies," Applied Energy, Elsevier, vol. 135(C), pages 1-10.
    3. Wei, L. & Zhao, T.S. & Zhao, G. & An, L. & Zeng, L., 2016. "A high-performance carbon nanoparticle-decorated graphite felt electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 176(C), pages 74-79.
    4. López-Vizcaíno, Rubén & Mena, Esperanza & Millán, María & Rodrigo, Manuel A. & Lobato, Justo, 2017. "Performance of a vanadium redox flow battery for the storage of electricity produced in photovoltaic solar panels," Renewable Energy, Elsevier, vol. 114(PB), pages 1123-1133.
    5. Chou, Yi-Sin & Hsu, Ning-Yih & Jeng, King-Tsai & Chen, Kuan-Hsiang & Yen, Shi-Chern, 2016. "A novel ultrasonic velocity sensing approach to monitoring state of charge of vanadium redox flow battery," Applied Energy, Elsevier, vol. 182(C), pages 253-259.
    6. Wu, Maochun & Liu, Mingyao & Long, Guifa & Wan, Kai & Liang, Zhenxing & Zhao, Tim S., 2014. "A novel high-energy-density positive electrolyte with multiple redox couples for redox flow batteries," Applied Energy, Elsevier, vol. 136(C), pages 576-581.
    7. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Experimental study on the performance of a vanadium redox flow battery with non-uniformly compressed carbon felt electrode," Applied Energy, Elsevier, vol. 213(C), pages 293-305.
    8. Wei, L. & Zhao, T.S. & Zeng, L. & Zhou, X.L. & Zeng, Y.K., 2016. "Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries," Applied Energy, Elsevier, vol. 180(C), pages 386-391.
    9. Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
    10. Guarnieri, Massimo & Trovò, Andrea & Picano, Francesco, 2020. "Enhancing the efficiency of kW-class vanadium redox flow batteries by flow factor modulation: An experimental method," Applied Energy, Elsevier, vol. 262(C).
    11. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    12. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Zhu, X.B., 2016. "Performance of a vanadium redox flow battery with a VANADion membrane," Applied Energy, Elsevier, vol. 180(C), pages 353-359.

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