IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v180y2016icp386-391.html
   My bibliography  Save this article

Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries

Author

Listed:
  • Wei, L.
  • Zhao, T.S.
  • Zeng, L.
  • Zhou, X.L.
  • Zeng, Y.K.

Abstract

A copper nanoparticle deposited graphite felt electrode for all vanadium redox flow batteries (VRFBs) is developed and tested. It is found that the copper catalyst enables a significant improvement in the electrochemical kinetics of the V3+/V2+ redox reaction. The battery’s utilization of the electrolyte and energy efficiency are found to be as high as 83.7% and 80.1%, at a current density of 300mAcm−2, which are 53.1% and 17.8% higher than those of the battery without the catalyst. Moreover, the present battery shows a good stability during the cycle test. The results suggest that the inexpensive copper nanoparticle catalyst without tedious preparation process offers a great promise for VRFB application.

Suggested Citation

  • Wei, L. & Zhao, T.S. & Zeng, L. & Zhou, X.L. & Zeng, Y.K., 2016. "Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries," Applied Energy, Elsevier, vol. 180(C), pages 386-391.
    • Handle: RePEc:eee:appene:v:180:y:2016:i:c:p:386-391
    DOI: 10.1016/j.apenergy.2016.07.134
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916310844
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.07.134?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Mohamed, M.R. & Leung, P.K. & Sulaiman, M.H., 2015. "Performance characterization of a vanadium redox flow battery at different operating parameters under a standardized test-bed system," Applied Energy, Elsevier, vol. 137(C), pages 402-412.
    2. Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
    3. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    4. Wei, Zhongbao & Lim, Tuti Mariana & Skyllas-Kazacos, Maria & Wai, Nyunt & Tseng, King Jet, 2016. "Online state of charge and model parameter co-estimation based on a novel multi-timescale estimator for vanadium redox flow battery," Applied Energy, Elsevier, vol. 172(C), pages 169-179.
    5. Di Blasi, A. & Briguglio, N. & Di Blasi, O. & Antonucci, V., 2014. "Charge–discharge performance of carbon fiber-based electrodes in single cell and short stack for vanadium redox flow battery," Applied Energy, Elsevier, vol. 125(C), pages 114-122.
    6. Bin Li & Zimin Nie & M. Vijayakumar & Guosheng Li & Jun Liu & Vincent Sprenkle & Wei Wang, 2015. "Ambipolar zinc-polyiodide electrolyte for a high-energy density aqueous redox flow battery," Nature Communications, Nature, vol. 6(1), pages 1-8, May.
    7. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
    8. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
    9. Wei, L. & Zhao, T.S. & Zhao, G. & An, L. & Zeng, L., 2016. "A high-performance carbon nanoparticle-decorated graphite felt electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 176(C), pages 74-79.
    10. Wu, Maochun & Liu, Mingyao & Long, Guifa & Wan, Kai & Liang, Zhenxing & Zhao, Tim S., 2014. "A novel high-energy-density positive electrolyte with multiple redox couples for redox flow batteries," Applied Energy, Elsevier, vol. 136(C), pages 576-581.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ren, Y.X. & Zhao, T.S. & Tan, P. & Wei, Z.H. & Zhou, X.L., 2017. "Modeling of an aprotic Li-O2 battery incorporating multiple-step reactions," Applied Energy, Elsevier, vol. 187(C), pages 706-716.
    2. Ma, Qiang & Fu, Wenxuan & Zhao, Lijuan & Chen, Zhenqian & Su, Huaneng & Xu, Qian, 2023. "A double-layer electrode for the negative side of deep eutectic solvent electrolyte-based vanadium-iron redox flow battery," Energy, Elsevier, vol. 265(C).
    3. Wang, Tao & Fu, Jiahui & Zheng, Menglian & Yu, Zitao, 2018. "Dynamic control strategy for the electrolyte flow rate of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 227(C), pages 613-623.
    4. Kim, Jungmyung & Park, Heesung, 2017. "Experimental analysis of discharge characteristics in vanadium redox flow battery," Applied Energy, Elsevier, vol. 206(C), pages 451-457.
    5. Igor Iwakiri & Tiago Antunes & Helena Almeida & João P. Sousa & Rita Bacelar Figueira & Adélio Mendes, 2021. "Redox Flow Batteries: Materials, Design and Prospects," Energies, MDPI, vol. 14(18), pages 1-45, September.
    6. Simon, Benedict A. & Gayon-Lombardo, Andrea & Pino-Muñoz, Catalina A. & Wood, Charles E. & Tenny, Kevin M. & Greco, Katharine V. & Cooper, Samuel J. & Forner-Cuenca, Antoni & Brushett, Fikile R. & Kuc, 2022. "Combining electrochemical and imaging analyses to understand the effect of electrode microstructure and electrolyte properties on redox flow batteries," Applied Energy, Elsevier, vol. 306(PB).
    7. Sun, J. & Jiang, H.R. & Wu, M.C. & Fan, X.Z. & Chao, C.Y.H. & Zhao, T.S., 2020. "Aligned hierarchical electrodes for high-performance aqueous redox flow battery," Applied Energy, Elsevier, vol. 271(C).
    8. Wang, Shaoliang & Xu, Zeyu & Wu, Xiaoliang & Zhao, Huan & Zhao, Jinling & Liu, Jianguo & Yan, Chuanwei & Fan, Xinzhuang, 2020. "Analyses and optimization of electrolyte concentration on the electrochemical performance of iron-chromium flow battery," Applied Energy, Elsevier, vol. 271(C).
    9. Mehboob, Sheeraz & Ali, Ghulam & Shin, Hyun-Jin & Hwang, Jinyeon & Abbas, Saleem & Chung, Kyung Yoon & Ha, Heung Yong, 2018. "Enhancing the performance of all-vanadium redox flow batteries by decorating carbon felt electrodes with SnO2 nanoparticles," Applied Energy, Elsevier, vol. 229(C), pages 910-921.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Experimental study on the performance of a vanadium redox flow battery with non-uniformly compressed carbon felt electrode," Applied Energy, Elsevier, vol. 213(C), pages 293-305.
    2. Messaggi, M. & Canzi, P. & Mereu, R. & Baricci, A. & Inzoli, F. & Casalegno, A. & Zago, M., 2018. "Analysis of flow field design on vanadium redox flow battery performance: Development of 3D computational fluid dynamic model and experimental validation," Applied Energy, Elsevier, vol. 228(C), pages 1057-1070.
    3. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Zhu, X.B., 2016. "Performance of a vanadium redox flow battery with a VANADion membrane," Applied Energy, Elsevier, vol. 180(C), pages 353-359.
    4. Wei, L. & Zhao, T.S. & Xu, Q. & Zhou, X.L. & Zhang, Z.H., 2017. "In-situ investigation of hydrogen evolution behavior in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 190(C), pages 1112-1118.
    5. Kim, Jungmyung & Park, Heesung, 2017. "Experimental analysis of discharge characteristics in vanadium redox flow battery," Applied Energy, Elsevier, vol. 206(C), pages 451-457.
    6. Wang, Shaoliang & Xu, Zeyu & Wu, Xiaoliang & Zhao, Huan & Zhao, Jinling & Liu, Jianguo & Yan, Chuanwei & Fan, Xinzhuang, 2020. "Analyses and optimization of electrolyte concentration on the electrochemical performance of iron-chromium flow battery," Applied Energy, Elsevier, vol. 271(C).
    7. Wei, L. & Zhao, T.S. & Zhao, G. & An, L. & Zeng, L., 2016. "A high-performance carbon nanoparticle-decorated graphite felt electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 176(C), pages 74-79.
    8. Kim, Dong Kyu & Yoon, Sang Jun & Lee, Jaeho & Kim, Sangwon, 2018. "Parametric study and flow rate optimization of all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 228(C), pages 891-901.
    9. Wei, L. & Zeng, L. & Wu, M.C. & Fan, X.Z. & Zhao, T.S., 2019. "Seawater as an alternative to deionized water for electrolyte preparations in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    10. Leung, P. & Martin, T. & Liras, M. & Berenguer, A.M. & Marcilla, R. & Shah, A. & An, L. & Anderson, M.A. & Palma, J., 2017. "Cyclohexanedione as the negative electrode reaction for aqueous organic redox flow batteries," Applied Energy, Elsevier, vol. 197(C), pages 318-326.
    11. Yue, Meng & Lv, Zhiqiang & Zheng, Qiong & Li, Xianfeng & Zhang, Huamin, 2019. "Battery assembly optimization: Tailoring the electrode compression ratio based on the polarization analysis in vanadium flow batteries," Applied Energy, Elsevier, vol. 235(C), pages 495-508.
    12. Yin, Cong & Guo, Shaoyun & Fang, Honglin & Liu, Jiayi & Li, Yang & Tang, Hao, 2015. "Numerical and experimental studies of stack shunt current for vanadium redox flow battery," Applied Energy, Elsevier, vol. 151(C), pages 237-248.
    13. Chou, Yi-Sin & Hsu, Ning-Yih & Jeng, King-Tsai & Chen, Kuan-Hsiang & Yen, Shi-Chern, 2016. "A novel ultrasonic velocity sensing approach to monitoring state of charge of vanadium redox flow battery," Applied Energy, Elsevier, vol. 182(C), pages 253-259.
    14. Zeng, Yikai & Li, Fenghao & Lu, Fei & Zhou, Xuelong & Yuan, Yanping & Cao, Xiaoling & Xiang, Bo, 2019. "A hierarchical interdigitated flow field design for scale-up of high-performance redox flow batteries," Applied Energy, Elsevier, vol. 238(C), pages 435-441.
    15. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
    16. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Numerical study on vanadium redox flow battery performance with non-uniformly compressed electrode and serpentine flow field," Applied Energy, Elsevier, vol. 220(C), pages 106-116.
    17. Wang, Tao & Fu, Jiahui & Zheng, Menglian & Yu, Zitao, 2018. "Dynamic control strategy for the electrolyte flow rate of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 227(C), pages 613-623.
    18. Jiang, H.R. & Wu, M.C. & Ren, Y.X. & Shyy, W. & Zhao, T.S., 2018. "Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries," Applied Energy, Elsevier, vol. 213(C), pages 366-374.
    19. López-Vizcaíno, Rubén & Mena, Esperanza & Millán, María & Rodrigo, Manuel A. & Lobato, Justo, 2017. "Performance of a vanadium redox flow battery for the storage of electricity produced in photovoltaic solar panels," Renewable Energy, Elsevier, vol. 114(PB), pages 1123-1133.
    20. Souentie, Stamatios & Amr, Issam & Alsuhaibani, Abdulrahman & Almazroei, Essa & Hammad, Ahmad D., 2017. "Temperature, charging current and state of charge effects on iron-vanadium flow batteries operation," Applied Energy, Elsevier, vol. 206(C), pages 568-576.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:180:y:2016:i:c:p:386-391. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.