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Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries

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  • Jiang, H.R.
  • Wu, M.C.
  • Ren, Y.X.
  • Shyy, W.
  • Zhao, T.S.

Abstract

Achieving a uniform distribution of zinc in the negative electrode is crucial to increase the electrode utilization, maximize the discharge capacity, suppress the dendrite formation and enhance the cycling stability for zinc bromine flow batteries (ZBFBs). To promote the uniform distribution of zinc and thus propel the commercial applications for ZBFBs, in this work, a first-principles study is carried out to investigate the zinc adsorption and diffusion on representative carbon surfaces, including a pristine graphite (0 0 0 1) surface, two surfaces with vacancies, and three surfaces with oxygen-functional groups, aiming to unravel the effect of carbon defects on the ion transport inside the porous electrode, clarify the underlying zinc anchoring mechanism and seek effective ways to promote the uniform distribution of zinc. It is found that the zinc distribution and morphology can be varied by adjusting carbon surface properties, especially by increasing the number of single vacancy. A graphite felt negative electrode with a high content of carbon defects is then prepared and tested in ZBFBs. Experimental results reveal that a much more uniform distribution of zinc is achieved in the prepared electrode than the original electrode does after charing, demonstrating the validity of our proposed mechanism and method. The results reported here provide new insights and novel methods to fabricate uniformly distributed zinc negative electrode, which can guide the rational design of electrode and promote the future applications of ZBFBs and other hybrid flow batteries (e.g. Zn-I2, Zn-Ce and all-iron).

Suggested Citation

  • Jiang, H.R. & Wu, M.C. & Ren, Y.X. & Shyy, W. & Zhao, T.S., 2018. "Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries," Applied Energy, Elsevier, vol. 213(C), pages 366-374.
    • Handle: RePEc:eee:appene:v:213:y:2018:i:c:p:366-374
    DOI: 10.1016/j.apenergy.2018.01.061
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    2. Jiang, H.R. & Shyy, W. & Ren, Y.X. & Zhang, R.H. & Zhao, T.S., 2019. "A room-temperature activated graphite felt as the cost-effective, highly active and stable electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 544-553.
    3. Wang, Keliang & Pei, Pucheng & Wang, Yichun & Liao, Cheng & Wang, Wei & Huang, Shangwei, 2018. "Advanced rechargeable zinc-air battery with parameter optimization," Applied Energy, Elsevier, vol. 225(C), pages 848-856.
    4. Sangeetha, Thangavel & Chen, Po-Tuan & Yan, Wei-Mon & Huang, K. David, 2020. "Enhancement of air-flow management in Zn-air fuel cells by the optimization of air-flow parameters," Energy, Elsevier, vol. 197(C).
    5. Shang, Wenxu & Yu, Wentao & Xiao, Xu & Ma, Yanyi & Chen, Ziqi & Ni, Meng & Tan, Peng, 2022. "Optimizing the charging protocol to address the self-discharge issues in rechargeable alkaline Zn-Co batteries," Applied Energy, Elsevier, vol. 308(C).
    6. Xu, Zhicheng & Fan, Qi & Li, Yang & Wang, Jun & Lund, Peter D., 2020. "Review of zinc dendrite formation in zinc bromine redox flow battery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    7. Jiang, H.R. & Shyy, W. & Wu, M.C. & Zhang, R.H. & Zhao, T.S., 2019. "A bi-porous graphite felt electrode with enhanced surface area and catalytic activity for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 233, pages 105-113.
    8. Jiang, H.R. & Zeng, Y.K. & Wu, M.C. & Shyy, W. & Zhao, T.S., 2019. "A uniformly distributed bismuth nanoparticle-modified carbon cloth electrode for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 240(C), pages 226-235.

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