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Experimental analysis of discharge characteristics in vanadium redox flow battery

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  • Kim, Jungmyung
  • Park, Heesung

Abstract

There has been growing interest in the performance of vanadium redox flow batteries (VRFBs) depending on the electrolyte temperature and flow rate. In this work, we have devised a single-cell test system with four reservoirs which can effectively control the temperature and flow rate of VRFB to investigate electrochemical properties during discharging in VRFB. The temperature has been set between 278K and 318K for the electrolytes composed of 1600mol/m3 V3+/V4+ with 4000mol/m3 H2SO4, while the flow rate of the electrolytes is in the range of 10–100mL/min. The exchange current density extracted by Tafel theory is expressed by Arrhenius-like equation and ranges between 38.83 and 49.07A/m2. Meanwhile, the electron transfer coefficient increases from 0.31 to 0.51 with increased temperature and flow rate. The area-specific resistance is found to decrease with increased temperature at the rate of 20.3mΩcm2/K. With these, the proposed analytical method successfully predicts the obtained experimental data with excellent accuracy. Our study offers the fundamental understandings of electrochemical properties of VRFB as well as can be applied to evaluate the VRFB energy storage system at the early conceptual design even without prototypes.

Suggested Citation

  • Kim, Jungmyung & Park, Heesung, 2017. "Experimental analysis of discharge characteristics in vanadium redox flow battery," Applied Energy, Elsevier, vol. 206(C), pages 451-457.
    • Handle: RePEc:eee:appene:v:206:y:2017:i:c:p:451-457
    DOI: 10.1016/j.apenergy.2017.08.218
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    Cited by:

    1. Hyeonhong Jung & Seongjun Lee, 2023. "A Study on Capacity and State of Charge Estimation of VRFB Systems Using Cumulated Charge and Electrolyte Volume under Rebalancing Conditions," Energies, MDPI, vol. 16(5), pages 1-14, March.
    2. Wei, L. & Zeng, L. & Wu, M.C. & Fan, X.Z. & Zhao, T.S., 2019. "Seawater as an alternative to deionized water for electrolyte preparations in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    3. Bhattacharjee, Ankur & Saha, Hiranmay, 2018. "Development of an efficient thermal management system for Vanadium Redox Flow Battery under different charge-discharge conditions," Applied Energy, Elsevier, vol. 230(C), pages 1182-1192.
    4. Yue, Meng & Lv, Zhiqiang & Zheng, Qiong & Li, Xianfeng & Zhang, Huamin, 2019. "Battery assembly optimization: Tailoring the electrode compression ratio based on the polarization analysis in vanadium flow batteries," Applied Energy, Elsevier, vol. 235(C), pages 495-508.
    5. Kim, Jungmyung & Park, Heesung, 2018. "Impact of nanofluidic electrolyte on the energy storage capacity in vanadium redox flow battery," Energy, Elsevier, vol. 160(C), pages 192-199.
    6. Jiang, H.R. & Wu, M.C. & Ren, Y.X. & Shyy, W. & Zhao, T.S., 2018. "Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries," Applied Energy, Elsevier, vol. 213(C), pages 366-374.
    7. Liu, Yongbin & Yu, Lihong & Liu, Le & Xi, Jingyu, 2021. "Tailoring the vanadium/proton ratio of electrolytes to boost efficiency and stability of vanadium flow batteries over a wide temperature range," Applied Energy, Elsevier, vol. 301(C).

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