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Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts

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  • Saba, Tony
  • Estephane, Jane
  • El Khoury, Bilal
  • El Khoury, Maroulla
  • Khazma, Mahmoud
  • El Zakhem, Henri
  • Aouad, Samer

Abstract

ZSM5 zeolite was impregnated with different KOH loadings (15 wt.%, 25 wt.% and 35 wt.%) to prepare a series of KOH/ZSM5 catalysts. The catalysts were calcined at 500 °C for 3 h and then characterized by N2 adsorption–desorption and X-ray diffraction (XRD) techniques. The catalysts were tested in the transesterification reaction in a batch reactor at 60 °C and under atmospheric pressure. It was found that KOH/ZSM5 with 35 wt.% loading showed the best catalytic performance. The best reaction conditions in the presence of KOH/ZSM5 (35 wt.%) were determined while modifying the catalyst to oil ratio and the reaction time. The highest methyl ester yield (>95%) was obtained for a reaction time of 24 h, a catalyst to oil ratio of 18 wt.%, and a methanol to oil molar ratio of 12:1. The properties of produced biodiesel complied with the ASTM specifications. The catalytic stability test showed that 35KOH/ZSM5 was stable for 3 consecutive runs. Characterization of the spent catalyst indicated that a slight deactivation might be due to the leaching of potassium oxides active sites.

Suggested Citation

  • Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
    • Handle: RePEc:eee:renene:v:90:y:2016:i:c:p:301-306
    DOI: 10.1016/j.renene.2016.01.009
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    1. Ashnani, Mohammad Hossein Mohammadi & Johari, Anwar & Hashim, Haslenda & Hasani, Elham, 2014. "A source of renewable energy in Malaysia, why biodiesel?," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 244-257.
    2. Lee, H.V. & Juan, J.C. & Taufiq-Yap, Y.H., 2015. "Preparation and application of binary acid–base CaO–La2O3 catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 74(C), pages 124-132.
    3. Mutreja, Vishal & Singh, Satnam & Ali, Amjad, 2011. "Biodiesel from mutton fat using KOH impregnated MgO as heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(8), pages 2253-2258.
    4. Asif, M. & Muneer, T., 2007. "Energy supply, its demand and security issues for developed and emerging economies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(7), pages 1388-1413, September.
    5. Noiroj, Krisada & Intarapong, Pisitpong & Luengnaruemitchai, Apanee & Jai-In, Samai, 2009. "A comparative study of KOH/Al2O3 and KOH/NaY catalysts for biodiesel production via transesterification from palm oil," Renewable Energy, Elsevier, vol. 34(4), pages 1145-1150.
    6. Farooq, Muhammad & Ramli, Anita & Naeem, Abdul, 2015. "Biodiesel production from low FFA waste cooking oil using heterogeneous catalyst derived from chicken bones," Renewable Energy, Elsevier, vol. 76(C), pages 362-368.
    7. Tariq, Muhammad & Ali, Saqib & Khalid, Nasir, 2012. "Activity of homogeneous and heterogeneous catalysts, spectroscopic and chromatographic characterization of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6303-6316.
    8. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    9. Xie, Wenlei & Yang, Xinli & Fan, Mingliang, 2015. "Novel solid base catalyst for biodiesel production: Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine," Renewable Energy, Elsevier, vol. 80(C), pages 230-237.
    10. Veljković, Vlada B. & Banković-Ilić, Ivana B. & Stamenković, Olivera S., 2015. "Purification of crude biodiesel obtained by heterogeneously-catalyzed transesterification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 500-516.
    11. Choedkiatsakul, I. & Ngaosuwan, K. & Assabumrungrat, S. & Mantegna, S. & Cravotto, G., 2015. "Biodiesel production in a novel continuous flow microwave reactor," Renewable Energy, Elsevier, vol. 83(C), pages 25-29.
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    5. Xie, Wenlei & Xiong, Yunfei & Wang, Hongyan, 2021. "Fe3O4-poly(AGE-DVB-GMA) composites immobilized with guanidine as a magnetically recyclable catalyst for enhanced biodiesel production," Renewable Energy, Elsevier, vol. 174(C), pages 758-768.
    6. Li, Lu & Zou, Changjun & Zhou, Lu & Lin, Lang, 2017. "Cucurbituril-protected Cs2.5H0.5PW12O40 for optimized biodiesel production from waste cooking oil," Renewable Energy, Elsevier, vol. 107(C), pages 14-22.
    7. Sakthivel, R. & Ramesh, K. & Purnachandran, R. & Mohamed Shameer, P., 2018. "A review on the properties, performance and emission aspects of the third generation biodiesels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2970-2992.
    8. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    9. Alsharifi, Mariam & Znad, Hussein & Hena, Sufia & Ang, Ming, 2017. "Biodiesel production from canola oil using novel Li/TiO2 as a heterogeneous catalyst prepared via impregnation method," Renewable Energy, Elsevier, vol. 114(PB), pages 1077-1089.
    10. Fereidooni, Leila & Tahvildari, Kambiz & Mehrpooya, Mehdi, 2018. "Trans-esterification of waste cooking oil with methanol by electrolysis process using KOH," Renewable Energy, Elsevier, vol. 116(PA), pages 183-193.
    11. Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.
    12. Muñoz, Robinson & González, Aixa & Valdebenito, Fabiola & Ciudad, Gustavo & Navia, Rodrigo & Pecchi, Gina & Azócar, Laura, 2020. "Fly ash as a new versatile acid-base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 162(C), pages 1931-1939.
    13. Gohain, Minakshi & Bardhan, Pritam & Laskar, Khairujjaman & Sarmah, Saswati & Mandal, Manabendra & Bora, Utpal & Chandra Kalita, Mohan & Goud, Vaibhav Vasant & Deka, Dhanapati, 2020. "Rhodotorula mucilaginosa: A source of heterogeneous catalyst for biodiesel production from yeast single cell oil and waste cooking oil," Renewable Energy, Elsevier, vol. 160(C), pages 220-230.
    14. Cai, Dongren & Zhan, Guowu & Xiao, Jingran & Zhou, Shu-Feng & Qiu, Ting, 2021. "Design and synthesis of novel amphipathic ionic liquids for biodiesel production from soapberry oil," Renewable Energy, Elsevier, vol. 168(C), pages 779-790.

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    Keywords

    Biodiesel; Transesterification; KOH; ZSM5; Reusability;
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