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Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment

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  • Dahdah, Eliane
  • Estephane, Jane
  • Haydar, Reem
  • Youssef, Yara
  • El Khoury, Bilal
  • Gennequin, Cedric
  • Aboukaïs, Antoine
  • Abi-Aad, Edmond
  • Aouad, Samer

Abstract

Different Ca–Mg–Al catalysts were prepared by the hydrotalcite route using co-precipitation and impregnation techniques. The effect of thermal treatment was studied and the obtained mixed oxides were characterized by X-ray diffraction, N2 adsorption-desorption and CO2-temperature programmed desorption. Catalysts were then tested in the transesterification of sunflower oil. The catalyst that showed the best catalytic performance was an uncalcined Mg4Al2 support impregnated with 40 wt% of calcium followed by a calcination at 600 °C (Ca600/Mg4Al2HT). Optimum conditions for biodiesel production over this catalyst were a reaction time of 6 h, a catalyst to oil ratio of 2.5 wt%, a 15:1 methanol to oil molar ratio, a stirring rate of 400 rpm and a temperature of 60 °C giving a final FAME yield of 95%.

Suggested Citation

  • Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:1242-1248
    DOI: 10.1016/j.renene.2019.06.171
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    8. Ebrahimian, Elham & Denayer, Joeri F.M. & Aghbashlo, Mortaza & Tabatabaei, Meisam & Karimi, Keikhosro, 2022. "Biomethane and biodiesel production from sunflower crop: A biorefinery perspective," Renewable Energy, Elsevier, vol. 200(C), pages 1352-1361.
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