IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v141y2019icp1042-1053.html
   My bibliography  Save this article

Green production of biodiesel over waste borosilicate glass derived catalyst and the process up-gradation in pilot scale

Author

Listed:
  • Vadery, Vinu
  • Cherikkallinmel, Sudha Kochiyil
  • Ramakrishnan, Resmi M.
  • Sugunan, Sankaran
  • Narayanan, Binitha N.

Abstract

An efficient solid base catalyst derived from waste borosilicate glass, by its reaction with sodium hydroxide, is used here for the production of biodiesel from used cooking oil. The active phase of the catalyst is found to be Na2SiO3 and the material is highly effective in the production of fuel grade biodiesel till 4 numbers of repeated cycles. The catalyst is found to be tolerant to free fatty acid and water content in the oil feedstock. The procedure is up-graded in pilot scale with the aid of a set up made of polypropylene vessels where the formation of high pressure is avoided in the reactors by the continuous condensation of methanol, making the process a safer one. We report the use of a solid catalyst derived from waste materials in a pilot-scale biodiesel production unit for the first time, which has the potential to have an easy and cost-effective industrial scale up. The performance of the prepared biodiesel and its blends with petrodiesel in diesel engine is investigated and it is found that the biodiesel blend (B10) showed the best performance at all engine loads.

Suggested Citation

  • Vadery, Vinu & Cherikkallinmel, Sudha Kochiyil & Ramakrishnan, Resmi M. & Sugunan, Sankaran & Narayanan, Binitha N., 2019. "Green production of biodiesel over waste borosilicate glass derived catalyst and the process up-gradation in pilot scale," Renewable Energy, Elsevier, vol. 141(C), pages 1042-1053.
    • Handle: RePEc:eee:renene:v:141:y:2019:i:c:p:1042-1053
    DOI: 10.1016/j.renene.2019.04.053
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119305373
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.04.053?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ramachandran, K. & Suganya, T. & Nagendra Gandhi, N. & Renganathan, S., 2013. "Recent developments for biodiesel production by ultrasonic assist transesterification using different heterogeneous catalyst: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 410-418.
    2. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    3. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Raghavan, V. & Saravanan, C.G. & Lee, P.S. & Chua, K.J.E. & Chou, S.K., 2014. "Investigation of evaporation and engine characteristics of pine oil biofuel fumigated in the inlet manifold of a diesel engine," Applied Energy, Elsevier, vol. 115(C), pages 514-524.
    4. Guo, Pingmei & Zheng, Chang & Zheng, Mingming & Huang, Fenghong & Li, Wenlin & Huang, Qingde, 2013. "Solid base catalysts for production of fatty acid methyl esters," Renewable Energy, Elsevier, vol. 53(C), pages 377-383.
    5. Xue, Jinlin & Grift, Tony E. & Hansen, Alan C., 2011. "Effect of biodiesel on engine performances and emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1098-1116, February.
    6. Salvi, B.L. & Panwar, N.L., 2012. "Biodiesel resources and production technologies – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3680-3689.
    7. Vadery, Vinu & Narayanan, Binitha N. & Ramakrishnan, Resmi M. & Cherikkallinmel, Sudha Kochiyil & Sugunan, Sankaran & Narayanan, Divya P. & Sasidharan, Sreenikesh, 2014. "Room temperature production of jatropha biodiesel over coconut husk ash," Energy, Elsevier, vol. 70(C), pages 588-594.
    8. Enweremadu, C.C. & Mbarawa, M.M., 2009. "Technical aspects of production and analysis of biodiesel from used cooking oil--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2205-2224, December.
    9. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    10. Ramadhas, A.S. & Muraleedharan, C. & Jayaraj, S., 2005. "Performance and emission evaluation of a diesel engine fueled with methyl esters of rubber seed oil," Renewable Energy, Elsevier, vol. 30(12), pages 1789-1800.
    11. Gui, M.M. & Lee, K.T. & Bhatia, S., 2008. "Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock," Energy, Elsevier, vol. 33(11), pages 1646-1653.
    12. Farooq, Muhammad & Ramli, Anita & Naeem, Abdul, 2015. "Biodiesel production from low FFA waste cooking oil using heterogeneous catalyst derived from chicken bones," Renewable Energy, Elsevier, vol. 76(C), pages 362-368.
    13. Long, Yun-Duo & Fang, Zhen & Su, Tong-Chao & Yang, Qing, 2014. "Co-production of biodiesel and hydrogen from rapeseed and Jatropha oils with sodium silicate and Ni catalysts," Applied Energy, Elsevier, vol. 113(C), pages 1819-1825.
    14. Panwar, N.L. & Kaushik, S.C. & Kothari, Surendra, 2011. "Role of renewable energy sources in environmental protection: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1513-1524, April.
    15. Shahir, V.K. & Jawahar, C.P. & Suresh, P.R., 2015. "Comparative study of diesel and biodiesel on CI engine with emphasis to emissions—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 686-697.
    16. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    17. Singh, S.P. & Singh, Dipti, 2010. "Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 200-216, January.
    18. An, H. & Yang, W.M. & Maghbouli, A. & Li, J. & Chou, S.K. & Chua, K.J., 2013. "Performance, combustion and emission characteristics of biodiesel derived from waste cooking oils," Applied Energy, Elsevier, vol. 112(C), pages 493-499.
    19. Aydin, Hüseyin & Bayindir, Hasan, 2010. "Performance and emission analysis of cottonseed oil methyl ester in a diesel engine," Renewable Energy, Elsevier, vol. 35(3), pages 588-592.
    20. Chouhan, A.P. Singh & Sarma, A.K., 2011. "Modern heterogeneous catalysts for biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4378-4399.
    21. Xue, Jinlin, 2013. "Combustion characteristics, engine performances and emissions of waste edible oil biodiesel in diesel engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 350-365.
    22. Suresh, M. & Jawahar, C.P. & Richard, Arun, 2018. "A review on biodiesel production, combustion, performance, and emission characteristics of non-edible oils in variable compression ratio diesel engine using biodiesel and its blends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 92(C), pages 38-49.
    23. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "The effects of water on biodiesel production and refining technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3456-3470.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Porcel, Meline Gurtat & de Mello, Bruna Tais Ferreira & Alves, Helton José & Schneider, Ricardo & da Silva, Camila & Borba, Carlos Eduardo, 2023. "Synthesis and characterization of KF/waste glass catalyst for use in the transesterification process under pressurized conditions," Renewable Energy, Elsevier, vol. 203(C), pages 56-67.
    2. Ella Cebisa Linganiso & Boitumelo Tlhaole & Lindokuhle Precious Magagula & Silas Dziike & Linda Zikhona Linganiso & Tshwafo Elias Motaung & Nosipho Moloto & Zikhona Nobuntu Tetana, 2022. "Biodiesel Production from Waste Oils: A South African Outlook," Sustainability, MDPI, vol. 14(4), pages 1-21, February.
    3. Mijangos, Gabriela E. & Cuautli, Cristina & Romero-Ibarra, Issis C. & Vazquez-Arenas, Jorge & Santolalla-Vargas, Carlos E. & Santes, Víctor & Castañeda-Galván, Adrián A. & Pfeiffer, Heriberto, 2022. "Experimental and theoretical analysis revealing the underlying chemistry accounting for the heterogeneous transesterification reaction in Na2SiO3 and Li2SiO3 catalysts," Renewable Energy, Elsevier, vol. 184(C), pages 845-856.
    4. Foteinis, Spyros & Chatzisymeon, Efthalia & Litinas, Alexandros & Tsoutsos, Theocharis, 2020. "Used-cooking-oil biodiesel: Life cycle assessment and comparison with first- and third-generation biofuel," Renewable Energy, Elsevier, vol. 153(C), pages 588-600.
    5. Tamilselvi, R. & Ramesh, M. & Lekshmi, G.S. & Bazaka, Olha & Levchenko, Igor & Bazaka, Kateryna & Mandhakini, M., 2020. "Graphene oxide – Based supercapacitors from agricultural wastes: A step to mass production of highly efficient electrodes for electrical transportation systems," Renewable Energy, Elsevier, vol. 151(C), pages 731-739.
    6. Irfan, Muhammad & Zhou, Lei & Ji, Jia-Heng & Chen, Jing & Yuan, Shan & Liang, Tian-Tian & Liu, Jin-Feng & Yang, Shi-Zhong & Gu, Ji-Dong & Mu, Bo-Zhong, 2020. "Enhanced energy generation and altered biochemical pathways in an enrichment microbial consortium amended with natural iron minerals," Renewable Energy, Elsevier, vol. 159(C), pages 585-594.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    2. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    3. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    4. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    5. Mukhtar, Ahmad & Saqib, Sidra & Lin, Hongfei & Hassan Shah, Mansoor Ul & Ullah, Sami & Younas, Muhammad & Rezakazemi, Mashallah & Ibrahim, Muhammad & Mahmood, Abid & Asif, Saira & Bokhari, Awais, 2022. "Current status and challenges in the heterogeneous catalysis for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    6. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K. & Hazrat, M.A., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel – Part 2: Properties, performance and emission characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1129-1146.
    7. Takase, Mohammed & Zhao, Ting & Zhang, Min & Chen, Yao & Liu, Hongyang & Yang, Liuqing & Wu, Xiangyang, 2015. "An expatiate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 495-520.
    8. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    9. No, Soo-Young, 2011. "Inedible vegetable oils and their derivatives for alternative diesel fuels in CI engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 131-149, January.
    10. Fereidooni, Leila & Tahvildari, Kambiz & Mehrpooya, Mehdi, 2018. "Trans-esterification of waste cooking oil with methanol by electrolysis process using KOH," Renewable Energy, Elsevier, vol. 116(PA), pages 183-193.
    11. Sierra-Cantor, Jonathan Fabián & Guerrero-Fajardo, Carlos Alberto, 2017. "Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 774-790.
    12. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    13. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Hazrat, M.A., 2015. "Prospect of biofuels as an alternative transport fuel in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 331-351.
    14. Yang, Liuqing & Takase, Mohammed & Zhang, Min & Zhao, Ting & Wu, Xiangyang, 2014. "Potential non-edible oil feedstock for biodiesel production in Africa: A survey," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 461-477.
    15. Singh, Paramvir & Varun, & Chauhan, S.R., 2016. "Carbonyl and aromatic hydrocarbon emissions from diesel engine exhaust using different feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 269-291.
    16. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
    17. Venu, Harish & Raju, V. Dhana & Subramani, Lingesan & Appavu, Prabhu, 2020. "Experimental assessment on the regulated and unregulated emissions of DI diesel engine fuelled with Chlorella emersonii methyl ester (CEME)," Renewable Energy, Elsevier, vol. 151(C), pages 88-102.
    18. Mofijur, M. & Atabani, A.E. & Masjuki, H.H. & Kalam, M.A. & Masum, B.M., 2013. "A study on the effects of promising edible and non-edible biodiesel feedstocks on engine performance and emissions production: A comparative evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 391-404.
    19. Nongbe, Medy C. & Ekou, Tchirioua & Ekou, Lynda & Yao, Kouassi Benjamin & Le Grognec, Erwan & Felpin, François-Xavier, 2017. "Biodiesel production from palm oil using sulfonated graphene catalyst," Renewable Energy, Elsevier, vol. 106(C), pages 135-141.
    20. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:141:y:2019:i:c:p:1042-1053. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.