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Trans-esterification of waste cooking oil with methanol by electrolysis process using KOH

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  • Fereidooni, Leila
  • Tahvildari, Kambiz
  • Mehrpooya, Mehdi

Abstract

Biodiesel produced form waste cooking oil (WCO) has increasingly attracted the attentions as an alternative fuel due to lower particulate emissions and other beneficial factors such as low cost. The present study investigated the production of biodiesel (BFD) as one of the effective methods in solving energy crises and environmental pollution. To increase the consumption of biofuels, a high yield biodiesels (96%) was produced as an alternative to fossil fuels by electrolysis method using graphite electrodes through trans-esterification reaction of WCO and KOH in presence of methanol. This reaction was done in 2 h without side saponification reaction. Biodiesel decreases the environmental effects of waste oil and can cause a new application for using the waste oil. The effect of the catalysis amount, oil/alcohol molar ratio, the amount of co-solvent, water amount, reaction temperature, voltage and the reaction time on biodiesel production were investigated confirming this method as a highly effective way for obtaining high yields. Increasing the catalyst beyond a known level decreases the reaction yield due to saponification side reactions; in consequence, an optimum amount of the catalyst should be used. Without inserting the electricity current in the environment temperature, trans-esterification reaction is done slightly in a long time but proper voltage should be used to obtain high yield, complete the reaction and decrease the reaction time. The purpose of this study is to show that the rheology of the biodiesel is a strong function of the shear history.

Suggested Citation

  • Fereidooni, Leila & Tahvildari, Kambiz & Mehrpooya, Mehdi, 2018. "Trans-esterification of waste cooking oil with methanol by electrolysis process using KOH," Renewable Energy, Elsevier, vol. 116(PA), pages 183-193.
    • Handle: RePEc:eee:renene:v:116:y:2018:i:pa:p:183-193
    DOI: 10.1016/j.renene.2017.08.067
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    1. Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
    2. Lin, Yuan-Chung & Hsu, Kuo-Hsiang & Chen, Chung-Bang, 2011. "Experimental investigation of the performance and emissions of a heavy-duty diesel engine fueled with waste cooking oil biodiesel/ultra-low sulfur diesel blends," Energy, Elsevier, vol. 36(1), pages 241-248.
    3. Chouhan, A.P. Singh & Sarma, A.K., 2011. "Modern heterogeneous catalysts for biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4378-4399.
    4. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    5. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    6. Gui, M.M. & Lee, K.T. & Bhatia, S., 2008. "Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock," Energy, Elsevier, vol. 33(11), pages 1646-1653.
    7. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    8. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
    9. Mehrpooya, Mehdi & Shahsavan, Mohsen & Sharifzadeh, Mohammad Mehdi Moftakhari, 2016. "Modeling, energy and exergy analysis of solar chimney power plant-Tehran climate data case study," Energy, Elsevier, vol. 115(P1), pages 257-273.
    10. Al-Jammal, Noor & Al-Hamamre, Zayed & Alnaief, Mohammad, 2016. "Manufacturing of zeolite based catalyst from zeolite tuft for biodiesel production from waste sunflower oil," Renewable Energy, Elsevier, vol. 93(C), pages 449-459.
    11. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "The effects of water on biodiesel production and refining technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3456-3470.
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    1. Xia, Shaige & Hu, Yongjie & Chen, Chao & Tao, Junyu & Yan, Beibei & Li, Wanqing & Zhu, Guangbin & Cheng, Zhanjun & Chen, Guanyi, 2022. "Electrolytic transesterification of waste cooking oil using magnetic Co/Fe–Ca based catalyst derived from waste shells: A promising approach towards sustainable biodiesel production," Renewable Energy, Elsevier, vol. 200(C), pages 1286-1299.

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