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Transesterification of waste cooking oil using FeCl3-modified resin catalyst and the research of catalytic mechanism

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  • Ma, Yingqun
  • Wang, Qunhui
  • Gao, Zhen
  • Sun, Xiaohong
  • Wang, Nan
  • Niu, Ruxuan
  • Ma, Hongzhi

Abstract

Biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst was investigated. In the optimum conditions, Fe load rate of resin of 10.97%. Comparison of effects of modified resin, unmodified resin, and homogeneous catalyst (FeCl3·6H2O) for the transesterification of waste cooking oil and methanol revealed that the transesterification rate of modified resin as catalyst reached 92.13%, which was 13.37% and 27.81% higher than those of unmodified resin and FeCl3·6H2O as catalysts, respectively. After the ninth run of reusing modified resin, transesterification rate stilled reach 73%. The result of NH3-Fourier transform infrared analysis proved that FeCl3 reacted with Bronsted acid site (SO3H) to form a new Lewis acid site. Results of Fourier transform infrared and X-ray diffraction analyses showed that –OH group disappeared and no crystalline phase was present in modified resin, which illustrated that the new Lewis acid site was formed by chemical reactions.

Suggested Citation

  • Ma, Yingqun & Wang, Qunhui & Gao, Zhen & Sun, Xiaohong & Wang, Nan & Niu, Ruxuan & Ma, Hongzhi, 2016. "Transesterification of waste cooking oil using FeCl3-modified resin catalyst and the research of catalytic mechanism," Renewable Energy, Elsevier, vol. 86(C), pages 643-650.
    • Handle: RePEc:eee:renene:v:86:y:2016:i:c:p:643-650
    DOI: 10.1016/j.renene.2015.08.079
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    Cited by:

    1. Gargari, M. Hashemzadeh & Sadrameli, S.M., 2019. "A single-phase transesterification of linseed oil using different co-solvents and hydrogel in the presence of calcium oxide: An optimization study," Renewable Energy, Elsevier, vol. 139(C), pages 426-434.
    2. Porcel, Meline Gurtat & de Mello, Bruna Tais Ferreira & Alves, Helton José & Schneider, Ricardo & da Silva, Camila & Borba, Carlos Eduardo, 2023. "Synthesis and characterization of KF/waste glass catalyst for use in the transesterification process under pressurized conditions," Renewable Energy, Elsevier, vol. 203(C), pages 56-67.
    3. di Bitonto, Luigi & Pastore, Carlo, 2019. "Metal hydrated-salts as efficient and reusable catalysts for pre-treating waste cooking oils and animal fats for an effective production of biodiesel," Renewable Energy, Elsevier, vol. 143(C), pages 1193-1200.
    4. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    5. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.

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