IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v162y2020icp1931-1939.html
   My bibliography  Save this article

Fly ash as a new versatile acid-base catalyst for biodiesel production

Author

Listed:
  • Muñoz, Robinson
  • González, Aixa
  • Valdebenito, Fabiola
  • Ciudad, Gustavo
  • Navia, Rodrigo
  • Pecchi, Gina
  • Azócar, Laura

Abstract

The production of fatty acid methyl esters (FAME) from waste frying oil (WFO) was studied using fly ash as received as a heterogeneous catalyst. The fly ash used in this research had a high content of both CaO and SO3, two compounds that have been previously proposed as catalysts in FAME production. The study was carried out on the basis of a response surface methodology (RSM). The model generated by RSM predicted as optimal conditions to obtain a 100% FAME yield at a methanol-to-oil molar ratio of 3.1:1, 11.2 (wt.% based on oil weight) fly ash and a temperature of 59 °C with agitation at 245 rpm and 6 h of reaction time. Additional experiments comparing anhydrous with aqueous medium showed that fly ash presented a high catalytic capacity to transform free fatty acids (FFA) into FAME through consecutive hydrolysis and esterification processes (hydroesterification) compared with that associated with the transesterification mechanism. According to the results, the fly ash used in this study would act as a multipurpose or “versatile” catalyst due to its chemical composition with constituents that act as acidic and basic catalysts, therefore, catalyzing the transesterification and hydroesterification reactions simultaneously and increasing the conversion yields of FAME.

Suggested Citation

  • Muñoz, Robinson & González, Aixa & Valdebenito, Fabiola & Ciudad, Gustavo & Navia, Rodrigo & Pecchi, Gina & Azócar, Laura, 2020. "Fly ash as a new versatile acid-base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 162(C), pages 1931-1939.
    • Handle: RePEc:eee:renene:v:162:y:2020:i:c:p:1931-1939
    DOI: 10.1016/j.renene.2020.09.099
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S096014812031524X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.09.099?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. da Costa Evangelista, João Paulo & Gondim, Amanda Duarte & Souza, Luiz Di & Araujo, Antonio Souza, 2016. "Alumina-supported potassium compounds as heterogeneous catalysts for biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 887-894.
    2. Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
    3. Tan, Yie Hua & Abdullah, Mohammad Omar & Nolasco-Hipolito, Cirilo & Ahmad Zauzi, Nur Syuhada, 2017. "Application of RSM and Taguchi methods for optimizing the transesterification of waste cooking oil catalyzed by solid ostrich and chicken-eggshell derived CaO," Renewable Energy, Elsevier, vol. 114(PB), pages 437-447.
    4. Panchal, Tirth M. & Patel, Ankit & Chauhan, D.D. & Thomas, Merlin & Patel, Jigar V., 2017. "A methodological review on bio-lubricants from vegetable oil based resources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 65-70.
    5. Masteri-Farahani, Majid & Hosseini, Mahdiyeh-Sadat & Forouzeshfar, Newsha, 2020. "Propyl-SO3H functionalized graphene oxide as multipurpose solid acid catalyst for biodiesel synthesis and acid-catalyzed esterification and acetalization reactions," Renewable Energy, Elsevier, vol. 151(C), pages 1092-1101.
    6. Marinković, Dalibor M. & Stanković, Miroslav V. & Veličković, Ana V. & Avramović, Jelena M. & Miladinović, Marija R. & Stamenković, Olivera O. & Veljković, Vlada B. & Jovanović, Dušan M., 2016. "Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1387-1408.
    7. Gutierrez, Andrea & Miró, Laia & Gil, Antoni & Rodríguez-Aseguinolaza, Javier & Barreneche, Camila & Calvet, Nicolas & Py, Xavier & Inés Fernández, A. & Grágeda, Mario & Ushak, Svetlana & Cabeza, Luis, 2016. "Advances in the valorization of waste and by-product materials as thermal energy storage (TES) materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 763-783.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.
    2. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    3. Ahmad, Shamshad & Chaudhary, Shalini & Pathak, Vinayak V. & Kothari, Richa & Tyagi, V.V., 2020. "Optimization of direct transesterification of Chlorella pyrenoidosa catalyzed by waste egg shell based heterogenous nano – CaO catalyst," Renewable Energy, Elsevier, vol. 160(C), pages 86-97.
    4. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    5. Babu, D. & Karvembu, R. & Anand, R., 2018. "Impact of split injection strategy on combustion, performance and emissions characteristics of biodiesel fuelled common rail direct injection assisted diesel engine," Energy, Elsevier, vol. 165(PB), pages 577-592.
    6. Nahas, Lea & Dahdah, Eliane & Aouad, Samer & El Khoury, Bilal & Gennequin, Cedric & Abi Aad, Edmond & Estephane, Jane, 2023. "Highly efficient scallop seashell-derived catalyst for biodiesel production from sunflower and waste cooking oils: Reaction kinetics and effect of calcination temperature studies," Renewable Energy, Elsevier, vol. 202(C), pages 1086-1095.
    7. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    8. Lani, Nurul Saadiah & Ngadi, Norzita & Inuwa, Ibrahim Mohammed, 2020. "New route for the synthesis of silica-supported calcium oxide catalyst in biodiesel production," Renewable Energy, Elsevier, vol. 156(C), pages 1266-1277.
    9. Singh, Thokchom Subhaschandra & Verma, Tikendra Nath, 2019. "Biodiesel production from Momordica Charantia (L.): Extraction and engine characteristics," Energy, Elsevier, vol. 189(C).
    10. Farfan-Cabrera, Leonardo Israel & Gallardo-Hernández, Ezequiel Alberto & Gómez-Guarneros, Mario & Pérez-González, José & Godínez-Salcedo, Jesús Gilberto, 2020. "Alteration of lubricity of Jatropha oil used as bio-lubricant for engines due to thermal ageing," Renewable Energy, Elsevier, vol. 149(C), pages 1197-1204.
    11. Li, Hui & Wang, Junchi & Ma, Xiaoling & Wang, Yangyang & Li, Guoning & Guo, Min & Cui, Ping & Lu, Wanpeng & Zhou, Shoujun & Yu, Mingzhi, 2021. "Carbonized MIL−100(Fe) used as support for recyclable solid acid synthesis for biodiesel production," Renewable Energy, Elsevier, vol. 179(C), pages 1191-1203.
    12. Ahmad O. Hasan & Khamis Essa & Mohamed R. Gomaa, 2022. "Synthesis, Structure Characterization and Study of a New Kind of Catalyst: A Monolith of Nickel Made by Additive Manufacturing Coated with Platinum," Energies, MDPI, vol. 15(20), pages 1-13, October.
    13. Ortega-Fernández, Iñigo & Rodríguez-Aseguinolaza, Javier, 2019. "Thermal energy storage for waste heat recovery in the steelworks: The case study of the REslag project," Applied Energy, Elsevier, vol. 237(C), pages 708-719.
    14. Seyyedeh Faezeh Mirab Haghighi & Payam Parvasi & Seyyed Mohammad Jokar & Angelo Basile, 2021. "Investigating the Effects of Ultrasonic Frequency and Membrane Technology on Biodiesel Production from Chicken Waste," Energies, MDPI, vol. 14(8), pages 1-21, April.
    15. Yusuff, Adeyinka S. & Bhonsle, Aman K. & Bangwal, Dinesh P. & Atray, Neeraj, 2021. "Development of a barium-modified zeolite catalyst for biodiesel production from waste frying oil: Process optimization by design of experiment," Renewable Energy, Elsevier, vol. 177(C), pages 1253-1264.
    16. Zhu, Qing-li & Gu, Heng & Ke, Zengguang, 2018. "Congeneration biodiesel, ricinine and nontoxic meal from castor seed," Renewable Energy, Elsevier, vol. 120(C), pages 51-59.
    17. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    18. Yang, Yang & Zhou, Ling & Hang, Jianwei & Du, Danyang & Shi, Weidong & He, Zhaoming, 2021. "Energy characteristics and optimal design of diffuser meridian in an electrical submersible pump," Renewable Energy, Elsevier, vol. 167(C), pages 718-727.
    19. Sánchez, A.S. & Almeida, M.B. & Torres, E.A. & Kalid, R.A. & Cohim, E. & Gasparatos, A., 2018. "Alternative biodiesel feedstock systems in the Semi-arid region of Brazil: Implications for ecosystem services," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 2744-2758.
    20. Goli, Jibril & Sahu, Omprakash, 2018. "Development of heterogeneous alkali catalyst from waste chicken eggshell for biodiesel production," Renewable Energy, Elsevier, vol. 128(PA), pages 142-154.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:162:y:2020:i:c:p:1931-1939. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.