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Detecting performance degradation in a dead-ended hydrogen-oxygen proton exchange membrane fuel cell used for an unmanned underwater vehicle

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  • Liu, Yang
  • Zhao, Junjie
  • Tu, Zhengkai

Abstract

Hydrogen-oxygen proton exchange membrane fuel cells (HO-PEMFCs) play a crucial role in the unmanned underwater vehicle (UUV) transportation field due to their distinct advantages of zero emission and low infrared radiation intensity. Effective water management is essential for the stable operation and performance output of HO-PEMFC. However, the vital role of increasing gas velocity to mitigate performance issues and catalyst degradation during prolonged fuel cell operation is frequently overlooked. The objective of this study is to systematically enhance both catalyst durability and overall system efficiency in dead-ended HO-PEMFCs by manipulating cathode flow velocities. The research findings demonstrate that a recirculation pump speed of 200 rpm (corresponding to a gas flow rate of approximately 0.4 m/s) can enhance cell performance by 58.39% at a current density of 1200 mA cm−2 compared to the dead-ended mode. With the gradual increase in pump speed, the flow pattern of liquid water at the cathode outlet transitions from film flow to droplet flow. Moreover, a weight coefficient is proposed to characterize the Pt oxidation states. Electrochemical and morphological characterization show that the increased gas flow rate mitigates water accumulation at the fuel cell outlet. In addition, the degradation of the catalyst due to dehydration of the membrane in the reactant gas inlet area is also mitigated by exhaust gas recirculation.

Suggested Citation

  • Liu, Yang & Zhao, Junjie & Tu, Zhengkai, 2024. "Detecting performance degradation in a dead-ended hydrogen-oxygen proton exchange membrane fuel cell used for an unmanned underwater vehicle," Renewable Energy, Elsevier, vol. 222(C).
  • Handle: RePEc:eee:renene:v:222:y:2024:i:c:s0960148124000156
    DOI: 10.1016/j.renene.2024.119950
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    References listed on IDEAS

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    1. Xiao, Biao & Zhao, Junjie & Fan, Lixin & Liu, Yang & Chan, Siew Hwa & Tu, Zhengkai, 2022. "Effects of moisture dehumidification on the performance and degradation of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 245(C).
    2. Gong, Chengyuan & Xing, Lu & Liang, Cong & Tu, Zhengkai, 2022. "Modeling and dynamic characteristic simulation of air-cooled proton exchange membrane fuel cell stack for unmanned aerial vehicle," Renewable Energy, Elsevier, vol. 188(C), pages 1094-1104.
    3. Barzegari, Mohammad M. & Dardel, Morteza & Alizadeh, Ebrahim & Ramiar, Abas, 2016. "Dynamic modeling and validation studies of dead-end cascade H2/O2 PEM fuel cell stack with integrated humidifier and separator," Applied Energy, Elsevier, vol. 177(C), pages 298-308.
    4. Li, Jinguang & Ke, Yuzhi & Yuan, Wei & Bai, Yafeng & Zhang, Baotong & Liu, Zi'ang & Lin, Zhenhe & Liu, Qingsen & Tang, Yong, 2023. "Enhancement of two-phase flow and mass transport by a two-dimensional flow channel with variable cross-sections in proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 219(P2).
    5. Chen, Ben & Wang, Jun & Yang, Tianqi & Cai, Yonghua & Zhang, Caizhi & Chan, Siew Hwa & Yu, Yi & Tu, Zhengkai, 2016. "Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode," Energy, Elsevier, vol. 106(C), pages 54-62.
    6. Li, Bing & Wan, Kechuang & Xie, Meng & Chu, Tiankuo & Wang, Xiaolei & Li, Xiang & Yang, Daijun & Ming, Pingwen & Zhang, Cunman, 2022. "Durability degradation mechanism and consistency analysis for proton exchange membrane fuel cell stack," Applied Energy, Elsevier, vol. 314(C).
    7. Xu, Sheng & Yin, Bifeng & Li, Zekai & Dong, Fei, 2023. "A review on gas purge of proton exchange membrane fuel cells: Mechanisms, experimental approaches, numerical approaches, and optimization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 172(C).
    8. Pei, Houchang & Xiao, Chenguang & Tu, Zhengkai, 2022. "Experimental study on liquid water formation characteristics in a novel transparent proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 321(C).
    9. Giacoppo, Giosuè & Hovland, Scott & Barbera, Orazio, 2019. "2 kW Modular PEM fuel cell stack for space applications: Development and test for operation under relevant conditions," Applied Energy, Elsevier, vol. 242(C), pages 1683-1696.
    10. Zhao, Lei & Yuan, Hao & Xie, Jiaping & Jiang, Shangfeng & Wei, Xuezhe & Tang, Wei & Ming, Pingwen & Dai, Haifeng, 2023. "Inconsistency evaluation of vehicle-oriented fuel cell stacks based on electrochemical impedance under dynamic operating conditions," Energy, Elsevier, vol. 265(C).
    11. Yu, Xianxian & Liu, Yang & Tu, Zhengkai & Chan, Siew Hwa, 2023. "Endplate effect in an open-cathode proton exchange membrane fuel cell stack: Phenomenon and resolution," Renewable Energy, Elsevier, vol. 219(P1).
    12. Zhang, Qinguo & Tong, Zheming & Tong, Shuiguang & Cheng, Zhewu, 2021. "Self-humidifying effect of air self-circulation system for proton exchange membrane fuel cell engines," Renewable Energy, Elsevier, vol. 164(C), pages 1143-1155.
    13. Liu, Shihua & Li, Xiaoyang & Pang, Linjia & Geng, Tie & Guo, Yonggang & Jiang, Lin & Kang, Kejia & Wang, Xinchao & Liu, Zongyao, 2022. "Study on the effect of purging time on the performance of PEMFC with dead-ended anode under gravity," Renewable Energy, Elsevier, vol. 200(C), pages 1141-1151.
    14. Yin, Yan & Li, Yu & Qin, Yanzhou & Li, Mengjie & Liu, Guokun & Zhang, Junfeng & Zhao, Jian, 2022. "Ex-situ experimental study on dynamic behaviors and detachment characteristics of liquid water in a transparent channel of PEMFC," Renewable Energy, Elsevier, vol. 187(C), pages 1037-1049.
    15. Büyük, Mehmet & İnci, Mustafa, 2023. "Improved drift-free P&O MPPT method to enhance energy harvesting capability for dynamic operating conditions of fuel cells," Energy, Elsevier, vol. 267(C).
    16. Fan, Lixin & Liu, Yang & Luo, Xiaobing & Tu, Zhengkai & Chan, Siew Hwa, 2023. "Comparison and evaluation of mega watts proton exchange membrane fuel cell combined heat and power system under different waste heat recovery methods," Renewable Energy, Elsevier, vol. 210(C), pages 295-305.
    17. Chen, Ben & Cai, Yonghua & Tu, Zhengkai & Chan, Siew Hwa & Wang, Jun & Yu, Yi, 2017. "Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With different electrolytes," Energy, Elsevier, vol. 141(C), pages 40-49.
    18. Yang, Laishun & Cui, Yi & Wang, Zhen & Shi, Luhao & Zhao, Yang & Sun, Peipei & Wang, Cuiping, 2024. "Optimization of the structure and cathode operating parameters of a serpentine PEMFC with longitudinal vortex generators by response surface method," Renewable Energy, Elsevier, vol. 220(C).
    19. Yu, Xingzi & Zhang, Caizhi & Li, Mengxiao & Wang, Gucheng & Tu, Zhengkai & Yu, Tao & Dong, Hui & Zhao, Fuqiang, 2024. "Thermal management of an open-cathode PEMFC based on constraint generalized predictive control and optimized strategy," Renewable Energy, Elsevier, vol. 220(C).
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