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Analysis of a model for the operation of a vanadium redox battery

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  • Vynnycky, M.

Abstract

Although the vanadium redox battery (VRB) has recently attracted considerable interest as an energy storage technology, it has a relatively poor energy-to-volume ratio and a system complexity compared with other technologies; however, modelling can assist in optimizing cell and stack design. This paper analyzes a 2D time-dependent single-phase isothermal model for the operation of a single cell in a VRB. Unlike in all previous work, asymptotic methods are used to determine the characteristic current density scale in terms of operating conditions and cell component properties. Also, the analysis reveals that the fluid mechanics decouples from the electrochemistry, at leading order; an asymptotically reduced model is then proposed which preserves the original geometrical resolution. This approach is recommended for accurate and computationally efficient VRB stack models, as has been achieved for polymer electrolyte fuel cells; this will be a prerequisite for the use of modelling in stack design and thence large-scale commercialization of the VRB. Finite-element methods are used to compute results for the 1D steady state high-stoichiometry limit; although an idealized case, it is recommended for the in-situ experimental acquisition of VRB electrokinetic data that can then be used for the model when applied under more general operating conditions.

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  • Vynnycky, M., 2011. "Analysis of a model for the operation of a vanadium redox battery," Energy, Elsevier, vol. 36(4), pages 2242-2256.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:4:p:2242-2256
    DOI: 10.1016/j.energy.2010.03.060
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    1. Yin, Cong & Guo, Shaoyun & Fang, Honglin & Liu, Jiayi & Li, Yang & Tang, Hao, 2015. "Numerical and experimental studies of stack shunt current for vanadium redox flow battery," Applied Energy, Elsevier, vol. 151(C), pages 237-248.
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    3. Yang, Zunxian & Meng, Qing & Guo, Zaiping & Yu, Xuebin & Guo, Tailiang & Zeng, Rong, 2013. "Highly reversible lithium storage in uniform Li4Ti5O12/carbon hybrid nanowebs as anode material for lithium-ion batteries," Energy, Elsevier, vol. 55(C), pages 925-932.
    4. Yin, Cong & Gao, Yan & Guo, Shaoyun & Tang, Hao, 2014. "A coupled three dimensional model of vanadium redox flow battery for flow field designs," Energy, Elsevier, vol. 74(C), pages 886-895.
    5. Pan, Jianxin & Huang, Mianyan & Li, Xue & Wang, Shubo & Li, Weihua & Ma, Tao & Xie, Xiaofeng & Ramani, Vijay, 2016. "The performance of all vanadium redox flow batteries at below-ambient temperatures," Energy, Elsevier, vol. 107(C), pages 784-790.
    6. Choi, Chanyong & Kim, Soohyun & Kim, Riyul & Choi, Yunsuk & Kim, Soowhan & Jung, Ho-young & Yang, Jung Hoon & Kim, Hee-Tak, 2017. "A review of vanadium electrolytes for vanadium redox flow batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 263-274.
    7. Iñigo Aramendia & Unai Fernandez-Gamiz & Adrian Martinez-San-Vicente & Ekaitz Zulueta & Jose Manuel Lopez-Guede, 2020. "Vanadium Redox Flow Batteries: A Review Oriented to Fluid-Dynamic Optimization," Energies, MDPI, vol. 14(1), pages 1-20, December.
    8. Yang, Xiao-Guang & Ye, Qiang & Cheng, Ping & Zhao, Tim S., 2015. "Effects of the electric field on ion crossover in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 145(C), pages 306-319.
    9. Zhou, X.L. & Zhao, T.S. & An, L. & Zeng, Y.K. & Yan, X.H., 2015. "A vanadium redox flow battery model incorporating the effect of ion concentrations on ion mobility," Applied Energy, Elsevier, vol. 158(C), pages 157-166.
    10. Seng, Kuok Hau & Li, Li & Chen, Da-Peng & Chen, Zhi Xin & Wang, Xiao-Lin & Liu, Hua Kun & Guo, Zai Ping, 2013. "The effects of FEC (fluoroethylene carbonate) electrolyte additive on the lithium storage properties of NiO (nickel oxide) nanocuboids," Energy, Elsevier, vol. 58(C), pages 707-713.
    11. Li, Xianglin & Huang, Jing & Faghri, Amir, 2015. "Modeling study of a Li–O2 battery with an active cathode," Energy, Elsevier, vol. 81(C), pages 489-500.
    12. Xu, Q. & Zhao, T.S. & Leung, P.K., 2013. "Numerical investigations of flow field designs for vanadium redox flow batteries," Applied Energy, Elsevier, vol. 105(C), pages 47-56.
    13. Ting-Chia Ou, 2018. "Design of a Novel Voltage Controller for Conversion of Carbon Dioxide into Clean Fuels Using the Integration of a Vanadium Redox Battery with Solar Energy," Energies, MDPI, vol. 11(3), pages 1-10, February.
    14. Simon, Benedict A. & Gayon-Lombardo, Andrea & Pino-Muñoz, Catalina A. & Wood, Charles E. & Tenny, Kevin M. & Greco, Katharine V. & Cooper, Samuel J. & Forner-Cuenca, Antoni & Brushett, Fikile R. & Kuc, 2022. "Combining electrochemical and imaging analyses to understand the effect of electrode microstructure and electrolyte properties on redox flow batteries," Applied Energy, Elsevier, vol. 306(PB).
    15. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    16. Xu, Q. & Zhao, T.S. & Zhang, C., 2014. "Effects of SOC-dependent electrolyte viscosity on performance of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 130(C), pages 139-147.
    17. Pugach, M. & Kondratenko, M. & Briola, S. & Bischi, A., 2018. "Zero dimensional dynamic model of vanadium redox flow battery cell incorporating all modes of vanadium ions crossover," Applied Energy, Elsevier, vol. 226(C), pages 560-569.
    18. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Numerical study on vanadium redox flow battery performance with non-uniformly compressed electrode and serpentine flow field," Applied Energy, Elsevier, vol. 220(C), pages 106-116.

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