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Metal-organic framework template-guided electrochemical lithography on substrates for SERS sensing applications

Author

Listed:
  • Youyou Lu

    (The First Affiliated Hospital, Zhejiang University School of Medicine
    School of Materials Science and Engineering, Zhejiang University)

  • Xuan Zhang

    (Zhejiang University)

  • Liyan Zhao

    (School of Materials Science and Engineering, Zhejiang University)

  • Hong Liu

    (School of Materials Science and Engineering, Zhejiang University)

  • Mi Yan

    (School of Materials Science and Engineering, Zhejiang University
    Baotou Research Institute of Rare Earths)

  • Xiaochen Zhang

    (The First Affiliated Hospital, Zhejiang University School of Medicine)

  • Kenji Mochizuki

    (Zhejiang University)

  • Shikuan Yang

    (The First Affiliated Hospital, Zhejiang University School of Medicine
    School of Materials Science and Engineering, Zhejiang University
    Baotou Research Institute of Rare Earths
    Zhejiang University)

Abstract

The templating method holds great promise for fabricating surface nanopatterns. To enhance the manufacturing capabilities of complex surface nanopatterns, it is important to explore new modes of the templates beyond their conventional masking and molding modes. Here, we employed the metal-organic framework (MOF) microparticles assembled monolayer films as templates for metal electrodeposition and revealed a previously unidentified guiding growth mode enabling the precise growth of metallic films exclusively underneath the MOF microparticles. The guiding growth mode was induced by the fast ion transportation within the nanochannels of the MOF templates. The MOF template could be repeatedly used, allowing for the creation of identical metallic surface nanopatterns for multiple times on different substrates. The MOF template-guided electrochemical growth mode provided a robust route towards cost-effective fabrication of complex metallic surface nanopatterns with promising applications in metamaterials, plasmonics, and surface-enhanced Raman spectroscopy (SERS) sensing fields.

Suggested Citation

  • Youyou Lu & Xuan Zhang & Liyan Zhao & Hong Liu & Mi Yan & Xiaochen Zhang & Kenji Mochizuki & Shikuan Yang, 2023. "Metal-organic framework template-guided electrochemical lithography on substrates for SERS sensing applications," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-41563-5
    DOI: 10.1038/s41467-023-41563-5
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