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2D CdPS3-based versatile superionic conductors

Author

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  • Xin Yu

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Wencai Ren

    (Chinese Academy of Sciences
    University of Science and Technology of China)

Abstract

Ion transport in nanochannels is crucial for applications in life science, filtration, and energy storage. However, multivalent ion transport is more difficult than the monovalent analogues due to the steric effect and stronger interactions with channel walls, and the ion mobility decreases significantly as temperature decreases. Although many kinds of solid ionic conductors (SICs) have been developed, they can attain practically useful conductivities (0.01 S cm−1) only for monovalent ions above 0 °C. Here, we report a class of versatile superionic conductors, monolayer CdPS3 nanosheets-based membranes intercalated with diverse cations with a high density up to ∼2 nm−2. They exhibit unexpectedly similar superhigh ion conductivities for monovalent (K+, Na+, Li+) and multivalent ions (Ca2+, Mg2+, Al3+), ∼0.01 to 0.8 S cm−1 in the temperature range of −30 ‒ 90 °C, which are one to two orders of magnitude higher than those of the corresponding best SICs. We reveal that the high conductivity originates from the concerted movement of high-density cations in the well-ordered nanochannels with high mobility and low energy barrier. Our work opens an avenue for designing superionic conductors that can conduct various cations and provides possibilities for discovering unusual nanofluidic phenomena in nanocapillaries.

Suggested Citation

  • Xin Yu & Wencai Ren, 2023. "2D CdPS3-based versatile superionic conductors," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39725-6
    DOI: 10.1038/s41467-023-39725-6
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    1. K. Huang & P. Rowe & C. Chi & V. Sreepal & T. Bohn & K.-G. Zhou & Y. Su & E. Prestat & P. Balakrishna Pillai & C. T. Cherian & A. Michaelides & R. R. Nair, 2020. "Cation-controlled wetting properties of vermiculite membranes and its promise for fouling resistant oil–water separation," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    2. G. Algara-Siller & O. Lehtinen & F. C. Wang & R. R. Nair & U. Kaiser & H. A. Wu & A. K. Geim & I. V. Grigorieva, 2015. "Square ice in graphene nanocapillaries," Nature, Nature, vol. 519(7544), pages 443-445, March.
    3. Marco-Tulio F. Rodrigues & Ganguli Babu & Hemtej Gullapalli & Kaushik Kalaga & Farheen N. Sayed & Keiko Kato & Jarin Joyner & Pulickel M. Ajayan, 2017. "A materials perspective on Li-ion batteries at extreme temperatures," Nature Energy, Nature, vol. 2(8), pages 1-14, August.
    4. Qiu Zhang & Yilin Ma & Yong Lu & Lin Li & Fang Wan & Kai Zhang & Jun Chen, 2020. "Modulating electrolyte structure for ultralow temperature aqueous zinc batteries," Nature Communications, Nature, vol. 11(1), pages 1-10, December.
    5. Xingfeng He & Yizhou Zhu & Yifei Mo, 2017. "Origin of fast ion diffusion in super-ionic conductors," Nature Communications, Nature, vol. 8(1), pages 1-7, August.
    6. Liang Chen & Guosheng Shi & Jie Shen & Bingquan Peng & Bowu Zhang & Yuzhu Wang & Fenggang Bian & Jiajun Wang & Deyuan Li & Zhe Qian & Gang Xu & Gongping Liu & Jianrong Zeng & Lijuan Zhang & Yizhou Yan, 2017. "Ion sieving in graphene oxide membranes via cationic control of interlayer spacing," Nature, Nature, vol. 550(7676), pages 380-383, October.
    7. Lalita Saini & Siva Sankar Nemala & Aparna Rathi & Suvigya Kaushik & Gopinadhan Kalon, 2022. "Selective transport of water molecules through interlayer spaces in graphite," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    8. Simon Bernèche & Benoît Roux, 2001. "Energetics of ion conduction through the K+ channel," Nature, Nature, vol. 414(6859), pages 73-77, November.
    9. Wenzhong Bao & Jiayu Wan & Xiaogang Han & Xinghan Cai & Hongli Zhu & Dohun Kim & Dakang Ma & Yunlu Xu & Jeremy N. Munday & H. Dennis Drew & Michael S. Fuhrer & Liangbing Hu, 2014. "Approaching the limits of transparency and conductivity in graphitic materials through lithium intercalation," Nature Communications, Nature, vol. 5(1), pages 1-9, September.
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