IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-43436-3.html
   My bibliography  Save this article

Design principles for sodium superionic conductors

Author

Listed:
  • Shuo Wang

    (University of Maryland)

  • Jiamin Fu

    (University of Western Ontario
    University of Western Ontario)

  • Yunsheng Liu

    (University of Maryland)

  • Ramanuja Srinivasan Saravanan

    (University of Maryland)

  • Jing Luo

    (University of Western Ontario)

  • Sixu Deng

    (University of Western Ontario)

  • Tsun-Kong Sham

    (University of Western Ontario)

  • Xueliang Sun

    (University of Western Ontario)

  • Yifei Mo

    (University of Maryland
    University of Maryland)

Abstract

Motivated by the high-performance solid-state lithium batteries enabled by lithium superionic conductors, sodium superionic conductor materials have great potential to empower sodium batteries with high energy, low cost, and sustainability. A critical challenge lies in designing and discovering sodium superionic conductors with high ionic conductivities to enable the development of solid-state sodium batteries. Here, by studying the structures and diffusion mechanisms of Li-ion versus Na-ion conducting solids, we reveal the structural feature of face-sharing high-coordination sites for fast sodium-ion conductors. By applying this feature as a design principle, we discover a number of Na-ion conductors in oxides, sulfides, and halides. Notably, we discover a chloride-based family of Na-ion conductors NaxMyCl6 (M = La–Sm) with UCl3-type structure and experimentally validate with the highest reported ionic conductivity. Our findings not only pave the way for the future development of sodium-ion conductors for sodium batteries, but also consolidate design principles of fast ion-conducting materials for a variety of energy applications.

Suggested Citation

  • Shuo Wang & Jiamin Fu & Yunsheng Liu & Ramanuja Srinivasan Saravanan & Jing Luo & Sixu Deng & Tsun-Kong Sham & Xueliang Sun & Yifei Mo, 2023. "Design principles for sodium superionic conductors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43436-3
    DOI: 10.1038/s41467-023-43436-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-43436-3
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-43436-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Ying Zhang & Xingfeng He & Zhiqian Chen & Qiang Bai & Adelaide M. Nolan & Charles A. Roberts & Debasish Banerjee & Tomoya Matsunaga & Yifei Mo & Chen Ling, 2019. "Unsupervised discovery of solid-state lithium ion conductors," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    2. You Zhou & Xiaofei Guan & Hua Zhou & Koushik Ramadoss & Suhare Adam & Huajun Liu & Sungsik Lee & Jian Shi & Masaru Tsuchiya & Dillon D. Fong & Shriram Ramanathan, 2016. "Strongly correlated perovskite fuel cells," Nature, Nature, vol. 534(7606), pages 231-234, June.
    3. Jürgen Janek & Wolfgang G. Zeier, 2016. "A solid future for battery development," Nature Energy, Nature, vol. 1(9), pages 1-4, September.
    4. Xingfeng He & Yizhou Zhu & Yifei Mo, 2017. "Origin of fast ion diffusion in super-ionic conductors," Nature Communications, Nature, vol. 8(1), pages 1-7, August.
    5. Shuya Wei & Shaomao Xu & Akanksha Agrawral & Snehashis Choudhury & Yingying Lu & Zhengyuan Tu & Lin Ma & Lynden A. Archer, 2016. "A stable room-temperature sodium–sulfur battery," Nature Communications, Nature, vol. 7(1), pages 1-10, September.
    6. A. Hayashi & N. Masuzawa & S. Yubuchi & F. Tsuji & C. Hotehama & A. Sakuda & M. Tatsumisago, 2019. "A sodium-ion sulfide solid electrolyte with unprecedented conductivity at room temperature," Nature Communications, Nature, vol. 10(1), pages 1-6, December.
    7. William D. Richards & Tomoyuki Tsujimura & Lincoln J. Miara & Yan Wang & Jae Chul Kim & Shyue Ping Ong & Ichiro Uechi & Naoki Suzuki & Gerbrand Ceder, 2016. "Design and synthesis of the superionic conductor Na10SnP2S12," Nature Communications, Nature, vol. 7(1), pages 1-8, April.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Youyou Lu & Xuan Zhang & Liyan Zhao & Hong Liu & Mi Yan & Xiaochen Zhang & Kenji Mochizuki & Shikuan Yang, 2023. "Metal-organic framework template-guided electrochemical lithography on substrates for SERS sensing applications," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    2. Hyeokjin Kwon & Hyun-Ji Choi & Jung-kyu Jang & Jinhong Lee & Jinkwan Jung & Wonjun Lee & Youngil Roh & Jaewon Baek & Dong Jae Shin & Ju-Hyuk Lee & Nam-Soon Choi & Ying Shirley Meng & Hee-Tak Kim, 2023. "Weakly coordinated Li ion in single-ion-conductor-based composite enabling low electrolyte content Li-metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    3. Sebastian Scheld, Walter & Charlotte Hoff, Linda & Vedder, Christian & Stollenwerk, Jochen & Grüner, Daniel & Rosen, Melanie & Lobe, Sandra & Ihrig, Martin & Seok, Ah–Ram & Finsterbusch, Martin & Uhle, 2023. "Enabling metal substrates for garnet-based composite cathodes by laser sintering," Applied Energy, Elsevier, vol. 345(C).
    4. Sewon Kim & Ju-Sik Kim & Lincoln Miara & Yan Wang & Sung-Kyun Jung & Seong Yong Park & Zhen Song & Hyungsub Kim & Michael Badding & JaeMyung Chang & Victor Roev & Gabin Yoon & Ryounghee Kim & Jung-Hwa, 2022. "High-energy and durable lithium metal batteries using garnet-type solid electrolytes with tailored lithium-metal compatibility," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    5. Jessica Kersey & Natalie D. Popovich & Amol A. Phadke, 2022. "Rapid battery cost declines accelerate the prospects of all-electric interregional container shipping," Nature Energy, Nature, vol. 7(7), pages 664-674, July.
    6. Wang, Chaoqi & Lü, Zhe & Li, Jingwei & Cao, Zhiqun & Wei, Bo & Li, Huan & Shang, Minghao & Su, Chaoxiang, 2020. "Efficient use of waste carton for power generation, tar and fertilizer through direct carbon solid oxide fuel cell," Renewable Energy, Elsevier, vol. 158(C), pages 410-420.
    7. Abdulrahman S. Binfaris & Alexander G. Zestos & Jandro L. Abot, 2023. "Development of Carbon Nanotube Yarn Supercapacitors and Energy Storage for Integrated Structural Health Monitoring," Energies, MDPI, vol. 16(15), pages 1-14, August.
    8. Bornmann, Lutz & Haunschild, Robin, 2022. "Empirical analysis of recent temporal dynamics of research fields: Annual publications in chemistry and related areas as an example," Journal of Informetrics, Elsevier, vol. 16(2).
    9. Nian Zhang & Guoxi Ren & Lili Li & Zhi Wang & Pengfei Yu & Xiaobao Li & Jing Zhou & Hui Zhang & Linjuan Zhang & Zhi Liu & Xiaosong Liu, 2024. "Dynamical evolution of CO2 and H2O on garnet electrolyte elucidated by ambient pressure X-ray spectroscopies," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    10. Dewu Zeng & Jingming Yao & Long Zhang & Ruonan Xu & Shaojie Wang & Xinlin Yan & Chuang Yu & Lin Wang, 2022. "Promoting favorable interfacial properties in lithium-based batteries using chlorine-rich sulfide inorganic solid-state electrolytes," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    11. Lv Hu & Jinzhu Wang & Kai Wang & Zhenqi Gu & Zhiwei Xi & Hui Li & Fang Chen & Youxi Wang & Zhenyu Li & Cheng Ma, 2023. "A cost-effective, ionically conductive and compressible oxychloride solid-state electrolyte for stable all-solid-state lithium-based batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    12. Neda Alsadat Aghamiri & Guangwei Hu & Alireza Fali & Zhen Zhang & Jiahan Li & Sivacarendran Balendhran & Sumeet Walia & Sharath Sriram & James H. Edgar & Shriram Ramanathan & Andrea Alù & Yohannes Aba, 2022. "Reconfigurable hyperbolic polaritonics with correlated oxide metasurfaces," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    13. Shah, M.A.K. Yousaf & Lu, Yuzheng & Mushtaq, Naveed & Yousaf, Muhammad & Akbar, Nabeela & Xia, Chen & Yun, Sining & Zhu, Bin, 2023. "Semiconductor-membrane fuel cell (SMFC) for renewable energy technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).
    14. Yao-Jie Lei & Xinxin Lu & Hirofumi Yoshikawa & Daiju Matsumura & Yameng Fan & Lingfei Zhao & Jiayang Li & Shijian Wang & Qinfen Gu & Hua-Kun Liu & Shi-Xue Dou & Shanmukaraj Devaraj & Teofilo Rojo & We, 2024. "Understanding the charge transfer effects of single atoms for boosting the performance of Na-S batteries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    15. Chao Zhu & Till Fuchs & Stefan A. L. Weber & Felix. H. Richter & Gunnar Glasser & Franjo Weber & Hans-Jürgen Butt & Jürgen Janek & Rüdiger Berger, 2023. "Understanding the evolution of lithium dendrites at Li6.25Al0.25La3Zr2O12 grain boundaries via operando microscopy techniques," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    16. Coester, Andreas & Hofkes, Marjan W. & Papyrakis, Elissaios, 2020. "Economic analysis of batteries: Impact on security of electricity supply and renewable energy expansion in Germany," Applied Energy, Elsevier, vol. 275(C).
    17. Xinxin Wang & Jingjing Chen & Dajian Wang & Zhiyong Mao, 2021. "Improving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid welding," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    18. Ruiz, V. & Pfrang, A. & Kriston, A. & Omar, N. & Van den Bossche, P. & Boon-Brett, L., 2018. "A review of international abuse testing standards and regulations for lithium ion batteries in electric and hybrid electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1427-1452.
    19. Wanqing Song & Xinyi Yang & Tao Zhang & Zechuan Huang & Haozhi Wang & Jie Sun & Yunhua Xu & Jia Ding & Wenbin Hu, 2024. "Optimizing potassium polysulfides for high performance potassium-sulfur batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    20. Aziam, Hasna & Larhrib, Badre & Hakim, Charifa & Sabi, Noha & Ben Youcef, Hicham & Saadoune, Ismael, 2022. "Solid-state electrolytes for beyond lithium-ion batteries: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-43436-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.