IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v35y2010i3p614-618.html
   My bibliography  Save this article

Effects of water on the esterification of free fatty acids by acid catalysts

Author

Listed:
  • Park, Ji-Yeon
  • Wang, Zhong-Ming
  • Kim, Deog-Keun
  • Lee, Jin-Suk

Abstract

To maximize the production of biodiesel from soybean soapstock, the effects of water on the esterification of high-FFA (free fatty acid) oils were investigated. Oleic acid and high acid acid oil (HAAO) were esterified by reaction with methanol in the presence of Amberlyst-15 as a heterogeneous catalyst or sulfuric acid as a homogeneous catalyst. The yield of fatty acid methyl ester (FAME) was studied at oil to methanol molar ratios of 1:3 and 1:6 and reaction temperatures of 60 and 80°C. The rate of esterification of oleic acid significantly decreased as the initial water content increased to 20% of the oil. The activity of Amberlyst-15 decreased more rapidly than that of sulfuric acid, due to the direct poisoning of acid sites by water. Esterification using sulfuric acid was not affected by water until there was a 5% water addition at a 1:6 molar ratio of oil to methanol. FAME content of HAAO prepared from soapstock rapidly increased for the first 30min of esterification. Following the 30-min mark, the rate of FAME production decreased significantly due to the accumulation of water. When methanol and Amberlyst-15 were removed from the HAAO after 30min of esterification and fresh methanol and a catalyst were added, the time required to reach 85% FAME content was reduced from 6h to 1.8h.

Suggested Citation

  • Park, Ji-Yeon & Wang, Zhong-Ming & Kim, Deog-Keun & Lee, Jin-Suk, 2010. "Effects of water on the esterification of free fatty acids by acid catalysts," Renewable Energy, Elsevier, vol. 35(3), pages 614-618.
    • Handle: RePEc:eee:renene:v:35:y:2010:i:3:p:614-618
    DOI: 10.1016/j.renene.2009.08.007
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148109003528
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2009.08.007?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Keskin, Ali & Gürü, Metin & Altiparmak, Duran & Aydin, Kadir, 2008. "Using of cotton oil soapstock biodiesel–diesel fuel blends as an alternative diesel fuel," Renewable Energy, Elsevier, vol. 33(4), pages 553-557.
    2. Janulis, P., 2004. "Reduction of energy consumption in biodiesel fuel life cycle," Renewable Energy, Elsevier, vol. 29(6), pages 861-871.
    3. Yuan, Xingzhong & Liu, Jia & Zeng, Guangming & Shi, Jingang & Tong, Jingyi & Huang, Guohe, 2008. "Optimization of conversion of waste rapeseed oil with high FFA to biodiesel using response surface methodology," Renewable Energy, Elsevier, vol. 33(7), pages 1678-1684.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Hui & Wang, Junchi & Ma, Xiaoling & Wang, Yangyang & Li, Guoning & Guo, Min & Cui, Ping & Lu, Wanpeng & Zhou, Shoujun & Yu, Mingzhi, 2021. "Carbonized MIL−100(Fe) used as support for recyclable solid acid synthesis for biodiesel production," Renewable Energy, Elsevier, vol. 179(C), pages 1191-1203.
    2. Jincheng Ding & Zheng Xia & Jie Lu, 2012. "Esterification and Deacidification of a Waste Cooking Oil (TAN 68.81 mg KOH/g) for Biodiesel Production," Energies, MDPI, vol. 5(8), pages 1-9, July.
    3. Kaur, Navjot & Ali, Amjad, 2015. "Preparation and application of Ce/ZrO2−TiO2/SO42− as solid catalyst for the esterification of fatty acids," Renewable Energy, Elsevier, vol. 81(C), pages 421-431.
    4. Cherng-Yuan Lin & Yi-Wei Lin, 2012. "Fuel Characteristics of Biodiesel Produced from a High-Acid Oil from Soybean Soapstock by Supercritical-Methanol Transesterification," Energies, MDPI, vol. 5(7), pages 1-11, July.
    5. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    6. Idowu, Ibijoke & Pedrola, Montserrat Ortoneda & Wylie, Steve & Teng, K.H. & Kot, Patryk & Phipps, David & Shaw, Andy, 2019. "Improving biodiesel yield of animal waste fats by combination of a pre-treatment technique and microwave technology," Renewable Energy, Elsevier, vol. 142(C), pages 535-542.
    7. Ibrahim, Shaimaa M., 2021. "Preparation, characterization and application of novel surface-modified ZrSnO4 as Sn-based TMOs catalysts for the stearic acid esterification with methanol to biodiesel," Renewable Energy, Elsevier, vol. 173(C), pages 151-163.
    8. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    9. Mendonça, Iasmin M. & Paes, Orlando A.R.L. & Maia, Paulo J.S. & Souza, Mayane P. & Almeida, Richardson A. & Silva, Cláudia C. & Duvoisin, Sérgio & de Freitas, Flávio A., 2019. "New heterogeneous catalyst for biodiesel production from waste tucumã peels (Astrocaryum aculeatum Meyer): Parameters optimization study," Renewable Energy, Elsevier, vol. 130(C), pages 103-110.
    10. Kanjaikaew, Utaiwan & Tongurai, Chakrit & Chongkhong, Sininart & Prasertsit, Kulchanat, 2018. "Two-step esterification of palm fatty acid distillate in ethyl ester production: Optimization and sensitivity analysis," Renewable Energy, Elsevier, vol. 119(C), pages 336-344.
    11. Zanette, Andréia F. & Barella, Rodrigo A. & Pergher, Sibele B.C. & Treichel, Helen & Oliveira, Débora & Mazutti, Marcio A. & Silva, Edson A. & Oliveira, J. Vladimir, 2011. "Screening, optimization and kinetics of Jatropha curcas oil transesterification with heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(2), pages 726-731.
    12. Somnuk, Krit & Soysuwan, Natthapon & Prateepchaikul, Gumpon, 2019. "Continuous process for biodiesel production from palm fatty acid distillate (PFAD) using helical static mixers as reactors," Renewable Energy, Elsevier, vol. 131(C), pages 100-110.
    13. Doğan, Tuba Hatice, 2016. "The testing of the effects of cooking conditions on the quality of biodiesel produced from waste cooking oils," Renewable Energy, Elsevier, vol. 94(C), pages 466-473.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2011. "Membrane biodiesel production and refining technology: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 5051-5062.
    2. Harsha Hebbar, H.R. & Math, M.C. & Yatish, K.V., 2018. "Optimization and kinetic study of CaO nano-particles catalyzed biodiesel production from Bombax ceiba oil," Energy, Elsevier, vol. 143(C), pages 25-34.
    3. Subramaniam, D. & Murugesan, A. & Avinash, A. & Kumaravel, A., 2013. "Bio-diesel production and its engine characteristics—An expatiate view," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 361-370.
    4. Rial, Rafael Cardoso & de Freitas, Osmar Nunes & Nazário, Carlos Eduardo Domingues & Viana, Luíz Henrique, 2020. "Biodiesel from soybean oil using Porcine pancreas lipase immobilized on a new support: p-nitrobenzyl cellulose xanthate," Renewable Energy, Elsevier, vol. 149(C), pages 970-979.
    5. Lilis Yuaningsih & R. Adjeng Mariana Febrianti & Hafiz Waqas Kamran, 2021. "Climate Change and Energy Consumption Patterns in Thailand: Time Trends During 1988-2013," International Journal of Energy Economics and Policy, Econjournals, vol. 11(1), pages 571-576.
    6. Garcez, Catherine Aliana Gucciardi & Vianna, João Nildo de Souza, 2009. "Brazilian Biodiesel Policy: Social and environmental considerations of sustainability," Energy, Elsevier, vol. 34(5), pages 645-654.
    7. Russi, Daniela, 2008. "An integrated assessment of a large-scale biodiesel production in Italy: Killing several birds with one stone?," Energy Policy, Elsevier, vol. 36(3), pages 1169-1180, March.
    8. Chen, Lei & Yin, Ping & Liu, Xiguang & Yang, Lixia & Yu, Zhongxi & Guo, Xin & Xin, Xinquan, 2011. "Biodiesel production over copper vanadium phosphate," Energy, Elsevier, vol. 36(1), pages 175-180.
    9. Dijkman, T.J. & Benders, R.M.J., 2010. "Comparison of renewable fuels based on their land use using energy densities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3148-3155, December.
    10. Yang, Xuanmin & Kang, Kang & Qiu, Ling & Zhao, Lixin & Sun, Renhua, 2020. "Effects of carbonization conditions on the yield and fixed carbon content of biochar from pruned apple tree branches," Renewable Energy, Elsevier, vol. 146(C), pages 1691-1699.
    11. repec:zib:zbjtin:v:2:y:2022:i:2:p:52-61 is not listed on IDEAS
    12. Milazzo, M.F. & Spina, F. & Vinci, A. & Espro, C. & Bart, J.C.J., 2013. "Brassica biodiesels: Past, present and future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 350-389.
    13. Hájek, Martin & Skopal, František & Čapek, Libor & Černoch, Michal & Kutálek, Petr, 2012. "Ethanolysis of rapeseed oil by KOH as homogeneous and as heterogeneous catalyst supported on alumina and CaO," Energy, Elsevier, vol. 48(1), pages 392-397.
    14. Nayak, Milap G. & Vyas, Amish P., 2019. "Optimization of microwave-assisted biodiesel production from Papaya oil using response surface methodology," Renewable Energy, Elsevier, vol. 138(C), pages 18-28.
    15. Malça, João & Freire, Fausto, 2011. "Life-cycle studies of biodiesel in Europe: A review addressing the variability of results and modeling issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 338-351, January.
    16. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    17. Admasu Asfaw Maruta & Rajabrata Banerjee, 2021. "Does energy aid improve energy efficiency in developing countries?," Empirical Economics, Springer, vol. 61(1), pages 355-388, July.
    18. Krishnamurthy, K.N. & Sridhara, S.N. & Ananda Kumar, C.S., 2018. "Synthesis and optimization of Hydnocarpus wightiana and dairy waste scum as feed stock for biodiesel production by using response surface methodology," Energy, Elsevier, vol. 153(C), pages 1073-1086.
    19. Abuhabaya, Abdullah & Fieldhouse, John & Brown, David, 2013. "The effects of using biodiesel on CI (compression ignition) engine and optimization of its production by using response surface methodology," Energy, Elsevier, vol. 59(C), pages 56-62.
    20. Yatish, K.V. & Lalithamba, H.S. & Suresh, R. & Latha, H.K.E., 2020. "Ochrocarpus longifolius assisted green synthesis of CaTiO3 nanoparticle for biodiesel production and its kinetic study," Renewable Energy, Elsevier, vol. 147(P1), pages 310-321.
    21. André Cremonez, Paulo & Feroldi, Michael & Cézar Nadaleti, Willian & de Rossi, Eduardo & Feiden, Armin & de Camargo, Mariele Pasuch & Cremonez, Filipe Eliazar & Klajn, Felipe Fernandes, 2015. "Biodiesel production in Brazil: Current scenario and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 415-428.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:35:y:2010:i:3:p:614-618. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.