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Screening, optimization and kinetics of Jatropha curcas oil transesterification with heterogeneous catalysts

Author

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  • Zanette, Andréia F.
  • Barella, Rodrigo A.
  • Pergher, Sibele B.C.
  • Treichel, Helen
  • Oliveira, Débora
  • Mazutti, Marcio A.
  • Silva, Edson A.
  • Oliveira, J. Vladimir

Abstract

This work investigates the production of fatty acid methyl esters (FAME) from Jatropha curcas oil using a variety of heterogeneous catalysts: resins, zeolites, clays, hydrotalcites, aluminas and niobium oxide. For this purpose, a catalyst screening was first conducted in a batch reactor at the following operating conditions: oil to methanol molar ratio of 1:9, 6h of reaction, 5 wt% catalyst, at 333 and 393K. From the screening step, KSF clay and Amberlyst 15 catalysts were selected to carry out a 23 full factorial central composite rotatable design so as to elucidate the effects of process variables on FAME yield. The optimum reaction conditions for both catalysts were found to be oil to methanol molar ratio of 1:12, 5 wt% of catalyst, 433K and 6h of reaction with a FAME yield of about 70 wt%. A kinetic study was then experimentally performed and a semi-empirical model was built to represent the experimental data. Finally, catalyst re-utilization in five successive batch experiments was evaluated at the optimized conditions.

Suggested Citation

  • Zanette, Andréia F. & Barella, Rodrigo A. & Pergher, Sibele B.C. & Treichel, Helen & Oliveira, Débora & Mazutti, Marcio A. & Silva, Edson A. & Oliveira, J. Vladimir, 2011. "Screening, optimization and kinetics of Jatropha curcas oil transesterification with heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(2), pages 726-731.
    • Handle: RePEc:eee:renene:v:36:y:2011:i:2:p:726-731
    DOI: 10.1016/j.renene.2010.08.028
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    3. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    4. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat Teong & Khayoon, Muataz Sh., 2012. "Intensification of biodiesel production via ultrasonic-assisted process: A critical review on fundamentals and recent development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4574-4587.
    5. Amani, H. & Ahmad, Z. & Hameed, B.H., 2014. "Synthesis of fatty acid methyl esters via the methanolysis of palm oil over Ca3.5xZr0.5yAlxO3 mixed oxide catalyst," Renewable Energy, Elsevier, vol. 66(C), pages 680-685.
    6. Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2012. "Biodiesel production from non-edible plant oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3621-3647.
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    8. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    9. Kalam, M.A. & Ahamed, J.U. & Masjuki, H.H., 2012. "Land availability of Jatropha production in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3999-4007.
    10. Laskar, Ikbal Bahar & Changmai, Bishwajit & Gupta, Rajat & Shi, Da & Jenkinson, Kellie J. & Wheatley, Andrew E.H. & Rokhum, Lalthazuala, 2021. "A mesoporous polysulfonic acid-formaldehyde polymeric catalyst for biodiesel production from Jatropha curcas oil," Renewable Energy, Elsevier, vol. 173(C), pages 415-421.
    11. Navarro-Pineda, Freddy S. & Baz-Rodríguez, Sergio A. & Handler, Robert & Sacramento-Rivero, Julio C., 2016. "Advances on the processing of Jatropha curcas towards a whole-crop biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 247-269.
    12. de Aguiar, Viviane Marques & de Souza, Andrea Luzia F. & Galdino, Fernanda S. & da Silva, Michelle Martha C. & Teixeira, Viviane Gomes & Lachter, Elizabeth R., 2017. "Sulfonated poly(divinylbenzene) and poly(styrene-divinylbenzene) as catalysts for esterification of fatty acids," Renewable Energy, Elsevier, vol. 114(PB), pages 725-732.

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