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Transesterification of waste cooking oil using clinoptilolite/ industrial phosphoric waste as green and environmental catalysts

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  • Aghel, Babak
  • Gouran, Ashkan
  • Nasirmanesh, Farzad

Abstract

This paper focuses on creating a new, environmentally sustainable catalyst made of industrial phosphoric waste and clinoptilolite for transesterification of waste cooking oil. A state-of-the-art CaO-based catalyst supported on the industrial phosphoric waste was obtained from a clinoptilolite zeolite-like material and alkali-activated CaO. So after ordinary purification, the clinoptilolite, and the weighed calcium oxide were stirred for 24 h at room temperature and then kept at 800 °C for 2 h for the formation of the catalyst. For assessment of the catalyst, the study used XRF, FT-IR, SEM, XRD, and BET. Under optimized conditions, the highest purity of biodiesel for waste cooking oil was 84.76%, the oil to methanol volume ratio was 1.47, the catalyst dosage was 8.08 wt%, the temperature was 54.72 °C, and the duration was 119 min. Results indicated that using waste cooking oil as raw materials and clinoptilolite/CaO as a catalyst for biodiesel development is a cost-effective and eco-friendly oil-recycling method and minimizes the production costs of biodiesel to improve biodiesel's competitiveness vis petroleum diesel.

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  • Aghel, Babak & Gouran, Ashkan & Nasirmanesh, Farzad, 2022. "Transesterification of waste cooking oil using clinoptilolite/ industrial phosphoric waste as green and environmental catalysts," Energy, Elsevier, vol. 244(PB).
    • Handle: RePEc:eee:energy:v:244:y:2022:i:pb:s036054422200041x
    DOI: 10.1016/j.energy.2022.123138
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    4. Aghel, Babak & Biabani, Arash, 2024. "Using solar microreactors and photocatalysts to synthesize biodiesel," Renewable Energy, Elsevier, vol. 220(C).
    5. Wang, Zhijuan & Zhou, Huajing & Liu, Zilian & Miao, Rongrong & He, Liang & Guan, Qingqing, 2023. "Walnut-shaped calcium oxide-cancrinite spheres for transesterification of waste frying oil," Renewable Energy, Elsevier, vol. 208(C), pages 229-239.
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