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Biodiesel production over copper vanadium phosphate

Author

Listed:
  • Chen, Lei
  • Yin, Ping
  • Liu, Xiguang
  • Yang, Lixia
  • Yu, Zhongxi
  • Guo, Xin
  • Xin, Xinquan

Abstract

In the present study, copper vanadium phosphate (CuVOP) with three-dimensional network structure was synthesized by hydrothermal method, and was characterized by Infrared spectrum (IR), elemental analysis (EA), EDXRF (energy dispersive X ray fluorescence) etc. Moreover, soybean oil was used as feedstock for producing biodiesel, and biodiesel was produced by CuVOP-catalyzed transesterification process. Response surface methodology was employed to statistically evaluate and optimize the conditions for the maximum conversion to biodiesel, and the effects of amount of catalyst, ratio of methanol to oil, reaction time and reaction temperature were investigated by the 24 full-factorial central composite design. The maximum conversion is obtained at amount of catalyst of 1.5%, methanol/oil molar ratio of 6.75, reaction temperature of 65 °C and reaction time of 5 h. Copper vanadium phosphate CuVOP resulted very active in the transesterification reaction for biodiesel production.

Suggested Citation

  • Chen, Lei & Yin, Ping & Liu, Xiguang & Yang, Lixia & Yu, Zhongxi & Guo, Xin & Xin, Xinquan, 2011. "Biodiesel production over copper vanadium phosphate," Energy, Elsevier, vol. 36(1), pages 175-180.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:1:p:175-180
    DOI: 10.1016/j.energy.2010.10.056
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    References listed on IDEAS

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    1. Yuan, Xingzhong & Liu, Jia & Zeng, Guangming & Shi, Jingang & Tong, Jingyi & Huang, Guohe, 2008. "Optimization of conversion of waste rapeseed oil with high FFA to biodiesel using response surface methodology," Renewable Energy, Elsevier, vol. 33(7), pages 1678-1684.
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    2. Bessa, Larissa C.B.A. & Ferreira, M.C. & Batista, Eduardo A.C. & Meirelles, Antonio J.A., 2013. "Performance and cost evaluation of a new double-effect integration of multicomponent bioethanol distillation," Energy, Elsevier, vol. 63(C), pages 1-9.
    3. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
    4. Borah, Manash Jyoti & Devi, Anuchaya & Saikia, Raktim Abha & Deka, Dhanapati, 2018. "Biodiesel production from waste cooking oil catalyzed by in-situ decorated TiO2 on reduced graphene oxide nanocomposite," Energy, Elsevier, vol. 158(C), pages 881-889.

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