IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v138y2019icp805-819.html
   My bibliography  Save this article

Effect of torrefaction on the physicochemical properties of pigeon pea stalk (Cajanus cajan) and estimation of kinetic parameters

Author

Listed:
  • Singh, Rishikesh kumar
  • Sarkar, Arnab
  • Chakraborty, Jyoti Prasad

Abstract

Torrefaction of biomass is an important preprocessing step which increases energy density and higher heating value. Torrefaction of pigeon pea stalk has been carried out in a tubular quartz reactor at different temperatures under nitrogen atmosphere. DT-TGA data have been used to predict the pyrolysis behavior and in estimating kinetic parameters using Arrhenius method. The effect of temperature was more pronounced as compared to residence time on the yield of solid product during torrefaction. Both O/C ratio and H/C ratios have decreased with increase in temperature. There was 28.6% increase in HHV of torrefied biomass at 275 °C and 45 min residence time as compared to raw biomass. There has been increase in energy density for torrefied biomass as compared to raw biomass. Moisture reabsorption, loose and tapped bulk density decreased for torrefied biomass as compared to raw biomass. For pigeon pea stalk Carr Compressibility index has decreased and Hausner Ratio has increased, resulting in lesser compactability and improved flowability respectively for torrefied biomass. Torrefied pigeon pea stalk exhibited better combustible properties. The activation energies of hemicellulose and cellulose have been decreased by 32.5% and 28.2% due to severe torrefaction. The contribution factor for hemicellulose decreased with increasing severity of torrefaction.

Suggested Citation

  • Singh, Rishikesh kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2019. "Effect of torrefaction on the physicochemical properties of pigeon pea stalk (Cajanus cajan) and estimation of kinetic parameters," Renewable Energy, Elsevier, vol. 138(C), pages 805-819.
    • Handle: RePEc:eee:renene:v:138:y:2019:i:c:p:805-819
    DOI: 10.1016/j.renene.2019.02.022
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119301661
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.02.022?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Congyu & Ho, Shih-Hsin & Chen, Wei-Hsin & Xie, Youping & Liu, Zhenquan & Chang, Jo-Shu, 2018. "Torrefaction performance and energy usage of biomass wastes and their correlations with torrefaction severity index," Applied Energy, Elsevier, vol. 220(C), pages 598-604.
    2. Soponpongpipat, N. & Sae-Ueng, U., 2015. "The effect of biomass bulk arrangements on the decomposition pathways in the torrefaction process," Renewable Energy, Elsevier, vol. 81(C), pages 679-684.
    3. Chew, J.J. & Doshi, V., 2011. "Recent advances in biomass pretreatment – Torrefaction fundamentals and technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4212-4222.
    4. Christoforou, Elias A. & Fokaides, Paris A., 2016. "Life cycle assessment (LCA) of olive husk torrefaction," Renewable Energy, Elsevier, vol. 90(C), pages 257-266.
    5. Karkania, V. & Fanara, E. & Zabaniotou, A., 2012. "Review of sustainable biomass pellets production – A study for agricultural residues pellets’ market in Greece," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(3), pages 1426-1436.
    6. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2006. "More efficient biomass gasification via torrefaction," Energy, Elsevier, vol. 31(15), pages 3458-3470.
    7. Proskurina, Svetlana & Heinimö, Jussi & Schipfer, Fabian & Vakkilainen, Esa, 2017. "Biomass for industrial applications: The role of torrefaction," Renewable Energy, Elsevier, vol. 111(C), pages 265-274.
    8. Do, Truong Xuan & Lim, Young-il & Cho, Hyodeuk & Shim, Jaehui & Yoo, Jeongkeun & Rho, Kyutai & Choi, Seong-Geun & Park, Chanwoo & Park, Byeong-Yun, 2018. "Techno-economic analysis of fry-drying and torrefaction plant for bio-solid fuel production," Renewable Energy, Elsevier, vol. 119(C), pages 45-53.
    9. Chen, Wei-Hsin & Cheng, Wen-Yi & Lu, Ke-Miao & Huang, Ying-Pin, 2011. "An evaluation on improvement of pulverized biomass property for solid fuel through torrefaction," Applied Energy, Elsevier, vol. 88(11), pages 3636-3644.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Marcin Bajcar & Miłosz Zardzewiały & Bogdan Saletnik & Grzegorz Zaguła & Czesław Puchalski & Józef Gorzelany, 2023. "Torrefaction as a Way to Remove Chlorine and Improve the Energy Properties of Plant Biomass," Energies, MDPI, vol. 16(21), pages 1-10, October.
    2. Kongto, Pumin & Palamanit, Arkom & Chaiprapat, Sumate & Tippayawong, Nakorn & Khempila, Jarunee & Lam, Su Shiung & Hayat, Asif & Yuh Yek, Peter Nai, 2023. "Physicochemical changes and energy properties of torrefied rubberwood biomass produced by different scale moving bed reactors," Renewable Energy, Elsevier, vol. 219(P2).
    3. Kumar, R. & Strezov, V. & Weldekidan, H. & He, J. & Singh, S. & Kan, T. & Dastjerdi, B., 2020. "Lignocellulose biomass pyrolysis for bio-oil production: A review of biomass pre-treatment methods for production of drop-in fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    4. Singh, Rishikesh Kumar & Chakraborty, Jyoti Prasad & Sarkar, Arnab, 2020. "Optimizing the torrefaction of pigeon pea stalk (cajanus cajan) using response surface methodology (RSM) and characterization of solid, liquid and gaseous products," Renewable Energy, Elsevier, vol. 155(C), pages 677-690.
    5. Hasan, Mohd Faizal & Omar, Muhammad Syaraffi & Sukiran, Mohamad Azri & Nyakuma, Bemgba Bevan & Muhamad Said, Mohd Farid, 2022. "Torrefaction of fibrous empty fruit bunch under mild pressurization technique," Renewable Energy, Elsevier, vol. 194(C), pages 349-358.
    6. Sahu, Parmanand & Gangil, Sandip & Bhargav, Vinod Kumar, 2023. "Biopolymeric transitions under pyrolytic thermal degradation of Pigeon pea stalk," Renewable Energy, Elsevier, vol. 206(C), pages 157-167.
    7. Sahu, Parmanand & Gangil, Sandip, 2023. "Stepped pyrolysis: A novel approach for enhanced adsorbency and carbon in Pigeon pea stalk char," Renewable Energy, Elsevier, vol. 219(P2).
    8. Oleg Milovanov & Dmitry Klimov & Sergey Kuzmin & Sergey Grigoriev & Alexander Mikhalev & Rafail Isemin & Mathieu Brulé, 2024. "Application of Torrefaction for Improved Fuel Properties of Sunflower Husks," Energies, MDPI, vol. 17(18), pages 1-13, September.
    9. Singh, Satyansh & Chakraborty, Jyoti Prasad & Mondal, Monoj Kumar, 2020. "Torrefaction of woody biomass (Acacia nilotica): Investigation of fuel and flow properties to study its suitability as a good quality solid fuel," Renewable Energy, Elsevier, vol. 153(C), pages 711-724.
    10. Zhao, Zhong & Feng, Shuo & Zhao, Yaying & Wang, Zhuozhi & Ma, Jiao & Xu, Lianfei & Yang, Jiancheng & Shen, Boxiong, 2022. "Investigation on the fuel quality and hydrophobicity of upgraded rice husk derived from various inert and oxidative torrefaction conditions," Renewable Energy, Elsevier, vol. 189(C), pages 1234-1248.
    11. Lin, Yi-Li & Zheng, Nai-Yun & Lin, Ching-Shi, 2021. "Repurposing Washingtonia filifera petiole and Sterculia foetida follicle waste biomass for renewable energy through torrefaction," Energy, Elsevier, vol. 223(C).
    12. Adeleke, Adekunle A. & Ikubanni, Peter P. & Emmanuel, Stephen S. & Fajobi, Moses O. & Nwachukwu, Praise & Adesibikan, Ademidun A. & Odusote, Jamiu K. & Adeyemi, Emmanuel O. & Abioye, Oluwaseyi M. & Ok, 2024. "A comprehensive review on the similarity and disparity of torrefied biomass and coal properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 199(C).
    13. Abdulyekeen, Kabir Abogunde & Umar, Ahmad Abulfathi & Patah, Muhamad Fazly Abdul & Daud, Wan Mohd Ashri Wan, 2021. "Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    14. Kartal, Furkan & Özveren, Uğur, 2022. "Prediction of torrefied biomass properties from raw biomass," Renewable Energy, Elsevier, vol. 182(C), pages 578-591.
    15. A. Silveira, Edgar & Santanna Chaves, Bruno & Macedo, Lucélia & Ghesti, Grace F. & Evaristo, Rafael B.W. & Cruz Lamas, Giulia & Luz, Sandra M. & Protásio, Thiago de Paula & Rousset, Patrick, 2023. "A hybrid optimization approach towards energy recovery from torrefied waste blends," Renewable Energy, Elsevier, vol. 212(C), pages 151-165.
    16. Lasek, Janusz A. & Głód, Krzysztof & Słowik, Krzysztof, 2021. "The co-combustion of torrefied municipal solid waste and coal in bubbling fluidised bed combustor under atmospheric and elevated pressure," Renewable Energy, Elsevier, vol. 179(C), pages 828-841.
    17. Singh, Rishikesh Kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2020. "Effect of torrefaction on the physicochemical properties of eucalyptus derived biofuels: estimation of kinetic parameters and optimizing torrefaction using response surface methodology (RSM)," Energy, Elsevier, vol. 198(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Gan, Yong Yang & Ong, Hwai Chyuan & Ling, Tau Chuan & Chen, Wei-Hsin & Chong, Cheng Tung, 2019. "Torrefaction of de-oiled Jatropha seed kernel biomass for solid fuel production," Energy, Elsevier, vol. 170(C), pages 367-374.
    2. Ping Wang & Bret H. Howard, 2017. "Impact of Thermal Pretreatment Temperatures on Woody Biomass Chemical Composition, Physical Properties and Microstructure," Energies, MDPI, vol. 11(1), pages 1-20, December.
    3. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    4. Sabil, Khalik M. & Aziz, Muafah A. & Lal, Bhajan & Uemura, Yoshimitsu, 2013. "Synthetic indicator on the severity of torrefaction of oil palm biomass residues through mass loss measurement," Applied Energy, Elsevier, vol. 111(C), pages 821-826.
    5. Fan, Yuyang & Li, Luwei & Tippayawong, Nakorn & Xia, Shengpeng & Cao, Fengzhu & Yang, Xingwei & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2019. "Quantitative structure-reactivity relationships for pyrolysis and gasification of torrefied xylan," Energy, Elsevier, vol. 188(C).
    6. Ong, Hwai Chyuan & Yu, Kai Ling & Chen, Wei-Hsin & Pillejera, Ma Katreena & Bi, Xiaotao & Tran, Khanh-Quang & Pétrissans, Anelie & Pétrissans, Mathieu, 2021. "Variation of lignocellulosic biomass structure from torrefaction: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    7. Singh, Rishikesh Kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2020. "Effect of torrefaction on the physicochemical properties of eucalyptus derived biofuels: estimation of kinetic parameters and optimizing torrefaction using response surface methodology (RSM)," Energy, Elsevier, vol. 198(C).
    8. Singh, Rishikesh Kumar & Chakraborty, Jyoti Prasad & Sarkar, Arnab, 2020. "Optimizing the torrefaction of pigeon pea stalk (cajanus cajan) using response surface methodology (RSM) and characterization of solid, liquid and gaseous products," Renewable Energy, Elsevier, vol. 155(C), pages 677-690.
    9. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba, Izabela, 2015. "Characterisation of renewable fuels' torrefaction process with different instrumental techniques," Energy, Elsevier, vol. 87(C), pages 259-269.
    10. Chai, Meiyun & Xie, Li & Yu, Xi & Zhang, Xingguang & Yang, Yang & Rahman, Md. Maksudur & Blanco, Paula H. & Liu, Ronghou & Bridgwater, Anthony V. & Cai, Junmeng, 2021. "Poplar wood torrefaction: Kinetics, thermochemistry and implications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    11. Volpe, Roberto & Messineo, Antonio & Millan, Marcos & Volpe, Maurizio & Kandiyoti, Rafael, 2015. "Assessment of olive wastes as energy source: pyrolysis, torrefaction and the key role of H loss in thermal breakdown," Energy, Elsevier, vol. 82(C), pages 119-127.
    12. Abdulyekeen, Kabir Abogunde & Umar, Ahmad Abulfathi & Patah, Muhamad Fazly Abdul & Daud, Wan Mohd Ashri Wan, 2021. "Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    13. Chai, Li & Saffron, Christopher M., 2016. "Comparing pelletization and torrefaction depots: Optimization of depot capacity and biomass moisture to determine the minimum production cost," Applied Energy, Elsevier, vol. 163(C), pages 387-395.
    14. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    15. Tran, Khanh-Quang & Luo, Xun & Seisenbaeva, Gulaim & Jirjis, Raida, 2013. "Stump torrefaction for bioenergy application," Applied Energy, Elsevier, vol. 112(C), pages 539-546.
    16. Fan, Yuyang & Tippayawong, Nakorn & Wei, Guoqiang & Huang, Zhen & Zhao, Kun & Jiang, Liqun & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2020. "Minimizing tar formation whilst enhancing syngas production by integrating biomass torrefaction pretreatment with chemical looping gasification," Applied Energy, Elsevier, vol. 260(C).
    17. Rousset, P. & Fernandes, K. & Vale, A. & Macedo, L. & Benoist, A., 2013. "Change in particle size distribution of Torrefied biomass during cold fluidization," Energy, Elsevier, vol. 51(C), pages 71-77.
    18. Chen, Wei-Hsin & Chen, Chih-Jung & Hung, Chen-I & Shen, Cheng-Hsien & Hsu, Heng-Wen, 2013. "A comparison of gasification phenomena among raw biomass, torrefied biomass and coal in an entrained-flow reactor," Applied Energy, Elsevier, vol. 112(C), pages 421-430.
    19. Suopajärvi, Hannu & Pongrácz, Eva & Fabritius, Timo, 2013. "The potential of using biomass-based reducing agents in the blast furnace: A review of thermochemical conversion technologies and assessments related to sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 511-528.
    20. Jorge Miguel Carneiro Ribeiro & Radu Godina & João Carlos de Oliveira Matias & Leonel Jorge Ribeiro Nunes, 2018. "Future Perspectives of Biomass Torrefaction: Review of the Current State-Of-The-Art and Research Development," Sustainability, MDPI, vol. 10(7), pages 1-17, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:138:y:2019:i:c:p:805-819. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.