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Investigation on the fuel quality and hydrophobicity of upgraded rice husk derived from various inert and oxidative torrefaction conditions

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  • Zhao, Zhong
  • Feng, Shuo
  • Zhao, Yaying
  • Wang, Zhuozhi
  • Ma, Jiao
  • Xu, Lianfei
  • Yang, Jiancheng
  • Shen, Boxiong

Abstract

Torrefaction is a promising approach which could optimize the behavior of biomass effectively. In this research, a typical and abundant agricultural by-product rice husk was employed for clarifying the correlation between upgradation condition and the fuel quality of upgraded sample. Rice husk were torrefied in inert and oxidative atmospheres (O2: 0, 6, 10 and 21 vol%) at three temperatures (493, 543 and 573 K). After undergoing various torrefaction processes, the torrefied samples were analyzed by elemental analysis, componential determination, fiber component identification, Fourier Transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), pore structure identification, contact angle characterization and moisture re-absorption test. The results illustrated that the additional oxidizing atoms could participate in the optimization of surface physiochemical property of rice husk particles during torrefaction process. Oxygen deficient torrefaction expressed a tendency to increase the heating value and the fixed carbon content in torrefied samples significantly. The minimum hydrophilic groups remained on the surface of rice husk sample pretreated in 6 vol% O2, and the specific surface area of upgraded sample torrefied in 6 vol% O2 at 573 K was the maximum. The contact angle results were consistent with that of moisture re-absorption tests, implying that increasing torrefaction severity appropriately was beneficial to optimizing the surface behavior and hydrophobicity of upgraded rice husk. Torrefaction of rice husk performed in 6 vol% O2 at 573 K was the optimum condition in this study.

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  • Zhao, Zhong & Feng, Shuo & Zhao, Yaying & Wang, Zhuozhi & Ma, Jiao & Xu, Lianfei & Yang, Jiancheng & Shen, Boxiong, 2022. "Investigation on the fuel quality and hydrophobicity of upgraded rice husk derived from various inert and oxidative torrefaction conditions," Renewable Energy, Elsevier, vol. 189(C), pages 1234-1248.
    • Handle: RePEc:eee:renene:v:189:y:2022:i:c:p:1234-1248
    DOI: 10.1016/j.renene.2022.03.087
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    2. Hasan, Mohammad Maruf & Du, Fang, 2023. "The role of foreign trade and technology innovation on economic recovery in China: The mediating role of natural resources development," Resources Policy, Elsevier, vol. 80(C).
    3. Antonios Nazos & Dorothea Politi & Georgios Giakoumakis & Dimitrios Sidiras, 2022. "Simulation and Optimization of Lignocellulosic Biomass Wet- and Dry-Torrefaction Process for Energy, Fuels and Materials Production: A Review," Energies, MDPI, vol. 15(23), pages 1-35, November.
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    5. Sui, Haiqing & Chen, Jianfeng & Cheng, Wei & Zhu, Youjian & Zhang, Wennan & Hu, Junhao & Jiang, Hao & Shao, Jing'ai & Chen, Hanping, 2024. "Effect of oxidative torrefaction on fuel and pelletizing properties of agricultural biomass in comparison with non-oxidative torrefaction," Renewable Energy, Elsevier, vol. 226(C).

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