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Minimizing tar formation whilst enhancing syngas production by integrating biomass torrefaction pretreatment with chemical looping gasification

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  • Fan, Yuyang
  • Tippayawong, Nakorn
  • Wei, Guoqiang
  • Huang, Zhen
  • Zhao, Kun
  • Jiang, Liqun
  • Zheng, Anqing
  • Zhao, Zengli
  • Li, Haibin

Abstract

The objective of this study is to investigate the effect of torrefaction pretreatment on the syngas production and tar formation from chemical looping gasification (CLG) of biomass over different oxygen carriers. The torrefaction of eucalyptus wood and subsequent CLG were systematically studied by using the fixed bed reactors coupling with various analytical methods. The experimental results demonstrate that torrefaction played significant impacts on CLG of eucalyptus wood using iron ore as an oxygen carrier. The gas yield and carbon conversion efficiency from CLG of eucalyptus wood were lowered by torrefaction, while the tar content was evidently reduced from 43.6 to 17.6 g/Nm3. These results could be due to the devolatilization, polycondensation, and carbonization of eucalyptus wood during torrefaction, resulting in the formation of fewer tar precursors and more char with lower reactivity during subsequent CLG. The negative impacts of torrefaction on the gas yield and carbon conversion efficiency of CLG can be effectively overcome by the selection of suitable oxygen carriers. Five metallic ferrites were successfully synthesized and used to replace iron ore for CLG of torrefied eucalyptus wood obtained at 280 °C. It is found that NiFe2O4 reduced the tar content by 88.8% and improved the gas yield by 27.5% compared to CLG of untreated eucalyptus wood over iron ore. These results suggest that integrating biomass torrefaction pretreatment with CLG is an efficient strategy for enhancing syngas production whilst minimizing tar formation.

Suggested Citation

  • Fan, Yuyang & Tippayawong, Nakorn & Wei, Guoqiang & Huang, Zhen & Zhao, Kun & Jiang, Liqun & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2020. "Minimizing tar formation whilst enhancing syngas production by integrating biomass torrefaction pretreatment with chemical looping gasification," Applied Energy, Elsevier, vol. 260(C).
    • Handle: RePEc:eee:appene:v:260:y:2020:i:c:s0306261919320021
    DOI: 10.1016/j.apenergy.2019.114315
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    2. Zeng, Kuo & Wang, Biao & Xia, Shengpeng & Cui, Chaoxian & Wang, Chenyang & Zheng, Anqing & Zhao, Kun & Zhao, Zengli & Li, Haibin & Isobaev, M.D., 2022. "Towards directional pyrolysis of xylan: Understanding the roles of alkali/alkaline earth metals and pyrolysis temperature," Energy, Elsevier, vol. 254(PA).
    3. Onsree, Thossaporn & Tippayawong, Nakorn, 2021. "Machine learning application to predict yields of solid products from biomass torrefaction," Renewable Energy, Elsevier, vol. 167(C), pages 425-432.
    4. Wang, Kun & An, Zewen & Wang, Fengyin & Liang, Wenzheng & Wang, Cuiping & Guo, Qingjie & Liu, Yongzhuo & Yue, Guangxi, 2021. "Effect of ash on the performance of iron-based oxygen carrier in the chemical looping gasification of municipal sludge," Energy, Elsevier, vol. 231(C).
    5. Ma, Jiao & Feng, Shuo & Zhang, Zhikun & Wang, Zhuozhi & Kong, Wenwen & Yuan, Peng & Shen, Boxiong & Mu, Lan, 2022. "Effect of torrefaction pretreatment on the combustion characteristics of the biodried products derived from municipal organic wastes," Energy, Elsevier, vol. 239(PD).
    6. Abdul Waheed & Salman Raza Naqvi & Imtiaz Ali, 2022. "Co-Torrefaction Progress of Biomass Residue/Waste Obtained for High-Value Bio-Solid Products," Energies, MDPI, vol. 15(21), pages 1-20, November.
    7. Yan, Beibei & Li, Songjiang & Cao, Xingsijin & Zhu, Xiaochao & Li, Jian & Zhou, Shengquan & Zhao, Juan & Sun, Yunan & Chen, Guanyi, 2023. "Flue gas torrefaction integrated with gasification based on the circulation of Mg-additive," Applied Energy, Elsevier, vol. 333(C).
    8. Jinlong Xie & Kang Zhu & Zhen Zhang & Xinfei Chen & Yan Lin & Jianjun Hu & Ya Xiong & Yongqi Zhang & Zhen Huang & Hongyu Huang, 2023. "Chemical Looping Gasification of Wood Waste Using NiO-Modified Hematite as an Oxygen Carrier," Energies, MDPI, vol. 16(4), pages 1-16, February.
    9. Arnob Das & Susmita Datta Peu, 2022. "A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector," Sustainability, MDPI, vol. 14(18), pages 1-42, September.
    10. Ren, Yi & Wang, Zhiyong & Chen, Jianbiao & Gao, Haojie & Guo, Kai & Wang, Xu & Wang, Xiaoyuan & Wang, Yinfeng & Chen, Haijun & Zhu, Jinjiao & Zhu, Yuezhao, 2023. "Effect of water/acetic acid washing pretreatment on biomass chemical looping gasification (BCLG) using cost-effective oxygen carrier from iron-rich sludge ash," Energy, Elsevier, vol. 272(C).
    11. Kargbo, Hannah O. & Zhang, Jie & Phan, Anh N., 2021. "Optimisation of two-stage biomass gasification for hydrogen production via artificial neural network," Applied Energy, Elsevier, vol. 302(C).
    12. Duan, Hanqi & Zhang, Zhiqing & Rahman, Md Maksudur & Guo, Xiaojuan & Zhang, Xingguang & Cai, Junmeng, 2020. "Insight into torrefaction of woody biomass: Kinetic modeling using pattern search method," Energy, Elsevier, vol. 201(C).

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