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Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat

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  • Shkatulov, Alexandr
  • Ryu, Junichi
  • Kato, Yukitaka
  • Aristov, Yury

Abstract

New composite material for storage and transformation of heat of a temperature range of 250–350 °C has been synthesized by precipitation of magnesium hydroxide Mg(OH)2 in the pores of expanded vermiculite. The hydroxide is stabilized inside the pores as irregular sticks of 1–3 μm in size across flats of the base and about 30 μm in length. The temperature of decomposition of the confined hydroxide is found to be by some 50 °C lower than that of the bulk one as revealed by both TG and DSC techniques. One possible reason of this finding is a significant acceleration of the decomposition reaction of the confined hydroxide as revealed from comparative kinetic tests in the temperature range of 260–300 °C. The maximal heat storage capacity is 540 kJ per kg of the composite with the hydroxide content of 67.4 mass. % that is larger than the heat of melting for promising phase change materials. Further study of the new composite material for storage of middle temperature heat could be of high interest to find out reasons of the decomposition temperature reduction in order to use this effect for harmonizing the reaction temperature with the temperature level of heat to be stored.

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  • Shkatulov, Alexandr & Ryu, Junichi & Kato, Yukitaka & Aristov, Yury, 2012. "Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat," Energy, Elsevier, vol. 44(1), pages 1028-1034.
    • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:1028-1034
    DOI: 10.1016/j.energy.2012.04.045
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    1. Stylianos Flegkas & Felix Birkelbach & Franz Winter & Hans Groenewold & Andreas Werner, 2019. "Profitability Analysis and Capital Cost Estimation of a Thermochemical Energy Storage System Utilizing Fluidized Bed Reactors and the Reaction System MgO/Mg(OH) 2," Energies, MDPI, vol. 12(24), pages 1-16, December.
    2. Pan, Z.H. & Zhao, C.Y., 2017. "Gas–solid thermochemical heat storage reactors for high-temperature applications," Energy, Elsevier, vol. 130(C), pages 155-173.
    3. Shkatulov, A.I. & Houben, J. & Fischer, H. & Huinink, H.P., 2020. "Stabilization of K2CO3 in vermiculite for thermochemical energy storage," Renewable Energy, Elsevier, vol. 150(C), pages 990-1000.
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    6. Flegkas, S. & Birkelbach, F. & Winter, F. & Freiberger, N. & Werner, A., 2018. "Fluidized bed reactors for solid-gas thermochemical energy storage concepts - Modelling and process limitations," Energy, Elsevier, vol. 143(C), pages 615-623.
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    9. Miliozzi, Adio & Chieruzzi, Manila & Torre, Luigi, 2019. "Experimental investigation of a cementitious heat storage medium incorporating a solar salt/diatomite composite phase change material," Applied Energy, Elsevier, vol. 250(C), pages 1023-1035.
    10. Jae Yong Lee & Taesu Yim & Hyouck Ju Kim & Sungkook Hong & Doo Won Seo & Hong Soo Kim, 2019. "Investigation on Long Term Operation of Thermochemical Heat Storage with MgO-Based Composite Honeycombs," Energies, MDPI, vol. 12(7), pages 1-18, April.
    11. Taesu Yim & Hong Soo Kim & Jae Yong Lee, 2018. "Cyclic Assessment of Magnesium Oxide with Additives as a Thermochemical Material to Improve the Mechanical Strength and Chemical Reaction," Energies, MDPI, vol. 11(9), pages 1-15, September.
    12. Emanuela Mastronardo & Yukitaka Kato & Lucio Bonaccorsi & Elpida Piperopoulos & Candida Milone, 2017. "Thermochemical Storage of Middle Temperature Wasted Heat by Functionalized C/Mg(OH) 2 Hybrid Materials," Energies, MDPI, vol. 10(1), pages 1-16, January.
    13. Yan, T. & Wang, R.Z. & Li, T.X., 2018. "Experimental investigation on thermochemical heat storage using manganese chloride/ammonia," Energy, Elsevier, vol. 143(C), pages 562-574.
    14. Pan, Zhihao & Zhao, C.Y., 2015. "Dehydration/hydration of MgO/H2O chemical thermal storage system," Energy, Elsevier, vol. 82(C), pages 611-618.
    15. Yan, T. & Wang, R.Z. & Li, T.X. & Wang, L.W. & Fred, Ishugah T., 2015. "A review of promising candidate reactions for chemical heat storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 13-31.
    16. Yannan Zhang & Ruzhu Wang & Tingxian Li & Yanjie Zhao, 2016. "Thermochemical Characterizations of Novel Vermiculite-LiCl Composite Sorbents for Low-Temperature Heat Storage," Energies, MDPI, vol. 9(10), pages 1-15, October.
    17. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    18. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    19. Aydin, Devrim & Casey, Sean P. & Riffat, Saffa, 2015. "The latest advancements on thermochemical heat storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 356-367.
    20. Shkatulov, Alexandr & Aristov, Yuri, 2015. "Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat," Energy, Elsevier, vol. 85(C), pages 667-676.
    21. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Lanza, M. & Milone, C., 2016. "Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 181(C), pages 232-243.
    22. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).
    23. N'Tsoukpoe, Kokouvi Edem & Restuccia, Giovanni & Schmidt, Thomas & Py, Xavier, 2014. "The size of sorbents in low pressure sorption or thermochemical energy storage processes," Energy, Elsevier, vol. 77(C), pages 983-998.

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